1-Allyl-1-methyl-3-butenylamin | 19243-49-3

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 1-Allyl-1-methyl-3-butenylamin
• 英文别名: 4-Methylhepta-1,6-dien-4-amine
• CAS: 19243-49-3
• 化学式: C₈H₁₅N
• mdl: MFCD01202919
• 分子量: 125.214
• InChiKey: LISDOJRNQJDFDI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.7
• 重原子数：
  9
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  26
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  1-Allyl-1-methyl-3-butenylamin 在 RuCl2(1,3-dimesityl-imidazolidin-2-yl)(PCy3)(=CHPh) sodium hydride 、 三乙胺 作用下， 以 二氯甲烷 、 N,N-二甲基甲酰胺 为溶剂， 反应 3.5h， 生成
  参考文献：
  名称：

  含氮四烯的双环复分解反应：双环生物碱骨架的有效构建以及对羽扇豆碱及其衍生物的四种立体异构体的合成应用。

  摘要：

  研究了含氮四烯的双环复分解反应。稠合/哑铃型产物的选择性可以通过连接于C [双键] C键的取代基的电子/立体效应和底物的s-顺式/ s-反式构象比来控制。该方法也已成功地应用于羽扇豆碱及其衍生物的四种立体异构体的对映选择性合成。

  DOI：

  10.1002/chem.200305581
• 作为产物：
  描述：

  2,4-Diallyl-1,3-bis-(1-allyl-1-methyl-but-3-enyl)-[1,3,2,4]diazadiboretidine 在 sodium hydroxide 作用下， 生成 1-Allyl-1-methyl-3-butenylamin
  参考文献：
  名称：

  Bubnov,Yu.N. et al., Journal of general chemistry of the USSR, 1968, vol. 38, p. 263 - 269

  摘要：

  DOI：

文献信息

• AMPHOLYTIC TER-POLYMERS FOR USE IN PERSONAL CARE COMPOSITIONS
  申请人：Gamez-Garcia Manuel

  公开号：US20100226868A1

  公开（公告）日：2010-09-09

  Novel ampholytic ter-polymers comprising at least an ethylenically unsaturated cationic monomer, a monomer containing a carboxylic acid or sulfonic acid group and diallyamine or derivative are claimed. Further, the ter-polymers may be used in personal care or personal washing compositions optionally in the presence of conditioning agents such as silicone, fatty amines, fatty amine oxides and fatty quaternaries and/or various benefit agents. The ter-polymer compositions are especially useful in the treatment of keratin-containing substrates. Keratin substrates include, but are not limited to, animal and human hair, skin and nails.

  本发明涉及一种新型两性离子聚合物，其中包含至少一种乙烯基不饱和阳离子单体、一种含有羧酸或磺酸基团的单体以及二烯基胺或其衍生物。此外，该聚合物可以用于个人护理或个人清洁组合物中，可选地与调理剂（如硅油、脂肪胺、脂肪胺氧化物和脂肪季铵盐）和/或各种功效剂一起使用。该聚合物组合物在处理含角蛋白底物方面特别有用。角蛋白底物包括但不限于动物和人类的头发、皮肤和指甲。
• Antiviral alpha, alpha-dialkyl adamantylethylamines
  申请人：PENNWALT CORPORATION

  公开号：EP0068365A1

  公开（公告）日：1983-01-05

  Warm-blooded animals are treated by administering to the animal a dosage, effective to prevent or to alleviate the symptoms of herpes virus, type II, of a compound of the Formula (I) or its acid salt: wherein R, and R2 are selected from the class consisting of H and -CH3; and at least one pharmaceutically acceptable carrier, wherein the compound is 0.01 to 95% by weight of the composition.

  温血动物的治疗方法是给动物施用有效预防或减轻 II 型疱疹病毒症状的式 (I) 化合物或其酸盐： 其中R和R2选自H和-CH3组成的类别；以及至少一种药学上可接受的载体，其中化合物占组合物重量的0.01%至95%。
• A process for preparing an aqueous copolymer solution
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：EP0688800A1

  公开（公告）日：1995-12-27

  A process for preparing an aqueous solution of an ionic copolumer having a copolymer concentration of 20 % by weight or less and a viscosity of 20 ps or more at 25 °C, which comprises conducting copolymerization of an acrylamide compound(B) with a diallylamine compound(A) by continuously adding an aqueous solution of (B) having a concentration of 30% by weight or less to an aqueous solution of the diallylamine compound(A) having a concentration of 5 % by weight or more and less than 10 % by weight, and this process exhibit high conversion of diallylamine compounds, of which reactivity is low, and a copolymer having a high molecular weight can be obtained.

  一种制备离子共聚物水溶液的工艺，其共聚物浓度为 20%（重量比）或更低，在 25 °C 时的粘度为 20 ps 或更高、该工艺包括将丙烯酰胺化合物(B)与二烯丙基胺化合物(A)进行共聚，方法是向二烯丙基胺化合物(A)的水溶液中连续加入浓度为 30% (重量)或以下的丙烯酰胺化合物(B)，二烯丙基胺化合物(A)的浓度为 5% (重量)或以上且小于 10% (重量)，该工艺显示出二烯丙基胺化合物的高转化率，而二烯丙基胺化合物的反应活性较低，可获得高分子量的共聚物。
• Inkjet recording method
  申请人：FUJI PHOTO FILM CO., LTD.

  公开号：EP1352754A2

  公开（公告）日：2003-10-15

  An inkjet recording method of forming an image on an inkjet recording sheet that has, on a support, a colorant-receiving layer which contains at least one inorganic mordant, by using an inkjet recording ink set that comprises, as minimum constituent elements thereof, a yellow ink which contains at least one yellow dye, a magenta ink which contains at least one magenta dye and a cyan ink which contains at least one cyan dye, wherein an oxidation potential of the magenta dye and an oxidation potential of the cyan dye are each nobler than 0.8 V (vs SCE).

  一种喷墨记录方法，通过使用喷墨记录墨水组在喷墨记录薄片上形成图像，该喷墨记录薄片在支撑物上具有着色剂接收层，该着色剂接收层含有至少一种无机媒染剂，作为其最小组成元素，该墨水组包括含有至少一种黄色染料的黄色墨水、含有至少一种品红色染料的品红色墨水和含有至少一种青色染料的青色墨水，其中品红色染料的氧化电位和青色染料的氧化电位均高于 0.8 V (vs SCE)。
• Fine particle dispersion
  申请人：Fuji Photo Film Co., Ltd.

  公开号：EP1350805A2

  公开（公告）日：2003-10-08

  The present invention provides an ink-jet recording sheet having a coloring agent accepting layer which contains a dispersion containing a cationic polymer with an average molecular weight of 60,000 or lower and having a sulfate ion concentration of 1.5% by mass or lower to the cationic polymer together with a water-soluble resin; an particle dispersion obtained by further granulating a pre-dispersion obtained by pre-dispersing a solution containing at least fine particles and a cationic polymer and the pre-dispersion and/or the particle dispersion is heated at room temperature for 5 hours or longer after pre-dispersion and/or after granulating; and a coating solution for coloring agent accepting layer obtained by adding a water-soluble resin to the particle dispersion.

  本发明提供了一种喷墨记录纸，该记录纸具有着色剂接受层，其中包含一种分散体，该分散体含有平均分子量为 60,000 或更低的阳离子聚合物，其硫酸根离子浓度为阳离子聚合物的 1.本发明提供了一种具有着色剂接受层的喷墨记录纸，它包含：含有平均分子量为 60,000 或更低且硫酸根离子浓度为 1.5%（质量分数）或更低的阳离子聚合物的分散液，以及水溶性树脂；通过进一步粒化通过预分散含有至少细颗粒和阳离子聚合物的溶液而得到的预分散液而得到的颗粒分散液，预分散液和/或颗粒分散液在预分散后和/或粒化后在室温下加热 5 小时或更长时间；以及通过向颗粒分散液中添加水溶性树脂而得到的着色剂接受层的涂层溶液。