1-(Phenylthio)-9-phenyldibenzothiophene | 158637-52-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并噻吩类
• 英文名称: 1-(Phenylthio)-9-phenyldibenzothiophene
• 英文别名: 1-Phenyl-9-phenylsulfanyldibenzothiophene
• CAS: 158637-52-6
• 化学式: C₂₄H₁₆S₂
• 分子量: 368.523
• InChiKey: DJNUIANZZMASAE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8
• 重原子数：
  26
• 可旋转键数：
  3
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  53.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1-(Phenylthio)-9-phenyldibenzothiophene 以 苯 为溶剂， 反应 10.0h， 以80%的产率得到苯并菲并[4,5-bcd]噻吩
  参考文献：
  名称：

  1-（苯硫基）-9-芳基二苯并噻吩的光解过程中硫与芳环之间空间相互作用的证据

  摘要：

  制备立体上拥挤的1-（苯硫基）-9-芳基二苯并硫属苯并噻吩，并用400W高压汞灯在苯中光解，得到三苯并[4,5- bcd ]噻吩。

  DOI：

  10.1016/0040-4039(94)02461-j
• 作为产物：
  描述：

  1,9-bis(phenylthio)dibenzothiophene 在 苯基溴化镁 、 间氯过氧苯甲酸 、 copper dichloride 作用下， 以 二氯甲烷 为溶剂， 反应 29.0h， 生成 1-(Phenylthio)-9-phenyldibenzothiophene
  参考文献：
  名称：

  Effect of Through-Space Interaction on the Photolytic Desulfurization or Deselenization and Intramolecular Cyclization Reactions of 1,9-Disubstituted Dibenzochalcogenophenes

  摘要：

  1,9-Dithia and 1,9-diselena substituents in dibenzochalcogenophenes 1 are in close proximity within the van der Waals S-S and Se-Se contacts and hence have a strong through-space interaction. Photolysis of the compounds 1 with a 400 W high-pressure mercury lamp in benzene produces triphenyleno[4,5-bcd]chalcogenophenes 2 and tribenzo[bc,e,hi][2,7]dichalcogenaazulenes 3 in high yields, except for the dibenzofuran derivative, via photoexcitation, sequential desulfurization or deselenization, and intramolecular cyclization. In the reaction, 1,9-bis(phenylthio)dibenzofuran (1e) exhibits lower reactivity as compared with other dibenzothiophene and dibenzoselenophene derivatives. The X-ray crystallographic analysis of 1,9-bis(phenylseleno)dibenzoselenaphene (1a), 1,9-bis(phenylseleno)dibenzothiophene (1b), and 1,9-bis(phenylthio)dibenzoselenophene (1c) demonstrated that; their structures are distorted as is also that of 1,9-bis(phenylthio)dibenzothiophene (1d),(1) while dibenzofuran derivative 1e was found to be a nearly planar molecule. The structure and reactivity relationship of compounds 1a-e was examined in the photolytic reactions by comparing their interheteroatomic distances at the 1,9 positions and their oxidation potentials. Furthermore, compounds 1a-e afforded the corresponding monosulfoxides and bis-sulfoxides on oxidation with m-chloroperbenzoic acid which were photolyzed readily to give also 2 and 3.

  DOI：

  10.1021/jo00102a043

文献信息

• Effect of Through-Space Interaction on the Photolytic Desulfurization or Deselenization and Intramolecular Cyclization Reactions of 1,9-Disubstituted Dibenzochalcogenophenes
  作者：Takeshi Kimura、Yasuhiro Ishikawa、Kensaku Ueki、Yoji Horie、Naomichi Furukawa

  DOI：10.1021/jo00102a043

  日期：1994.11

  1,9-Dithia and 1,9-diselena substituents in dibenzochalcogenophenes 1 are in close proximity within the van der Waals S-S and Se-Se contacts and hence have a strong through-space interaction. Photolysis of the compounds 1 with a 400 W high-pressure mercury lamp in benzene produces triphenyleno[4,5-bcd]chalcogenophenes 2 and tribenzo[bc,e,hi][2,7]dichalcogenaazulenes 3 in high yields, except for the dibenzofuran derivative, via photoexcitation, sequential desulfurization or deselenization, and intramolecular cyclization. In the reaction, 1,9-bis(phenylthio)dibenzofuran (1e) exhibits lower reactivity as compared with other dibenzothiophene and dibenzoselenophene derivatives. The X-ray crystallographic analysis of 1,9-bis(phenylseleno)dibenzoselenaphene (1a), 1,9-bis(phenylseleno)dibenzothiophene (1b), and 1,9-bis(phenylthio)dibenzoselenophene (1c) demonstrated that; their structures are distorted as is also that of 1,9-bis(phenylthio)dibenzothiophene (1d),(1) while dibenzofuran derivative 1e was found to be a nearly planar molecule. The structure and reactivity relationship of compounds 1a-e was examined in the photolytic reactions by comparing their interheteroatomic distances at the 1,9 positions and their oxidation potentials. Furthermore, compounds 1a-e afforded the corresponding monosulfoxides and bis-sulfoxides on oxidation with m-chloroperbenzoic acid which were photolyzed readily to give also 2 and 3.
• Evidence of through-space interaction between the sulfur and aromatic ring on photolysis of 1-(phenylthio)-9-aryldibenzothiophenes
  作者：Takeshi Kimura、Naomichi Furukawa

  DOI：10.1016/0040-4039(94)02461-j

  日期：1995.2

  Sterically congested 1-(phenylthio)-9-aryldibenzochalcogenophenes were prepared and photolyzed with a 400 W high pressure Hg lamp in benzene to afford triphenyleno[4,5-bcd]thiophenes.

  制备立体上拥挤的1-（苯硫基）-9-芳基二苯并硫属苯并噻吩，并用400W高压汞灯在苯中光解，得到三苯并[4,5- bcd ]噻吩。