10,10a-dihydro-4aH-phenothiazine

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并噻嗪类
• 英文名称: 10,10a-dihydro-4aH-phenothiazine
• 化学式: C₁₂H₁₁NS
• 分子量: 201.29
• InChiKey: XYBUNINDJPDVKM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.3
• 重原子数：
  14
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.17
• 拓扑面积：
  37.3
• 氢给体数：
  1
• 氢受体数：
  2

文献信息

• DIAMINOPHENOTHIAZINIUM DERIVATIVES FOR LABELLING BIOMOLECULES, METHOD AND SUBSTRATE FOR LABELLING OLIGONUCLEOTIDES, AND OLIGONUCLEOTIDES OBTAINED
  申请人：UNIVERSITY CLAUDE BERNARD LYON I

  公开号：US20150011712A1

  公开（公告）日：2015-01-08

  The present invention relates to diaminophenothiazinium derivatives of formula (I); in which R 1 , R 2 , R 3 , R 4 , R 5 , R 6 and X − are as defined in Claim 1, and also the methods for labelling oligonucleotides using such a derivative, labeling substrates and the oligonucleotides which can be obtained by means of such methods or from such labelling substrates.

  本发明涉及式（I）的二氨基苯噻嗪衍生物；其中R1、R2、R3、R4、R5、R6和X−如权利要求1中定义的那样，以及使用这种衍生物标记寡核苷酸的方法，标记底物和可以通过这些方法或从这些标记底物获得的寡核苷酸。
• Method for forming a carbon-carbon or carbon-heteroatom bond
  申请人：Spindler Jean-Francis

  公开号：US20090240061A1

  公开（公告）日：2009-09-24

  The invention relates to a method for forming a carbon-carbon or carbon-heteroatom bond by reacting an unsaturated compound carrying a leaving group and a nucleophilic compound, in the absence of a ligand. The aim of the invention is especially to form carbon-nitrogen bonds according to a method for the arylation of nitrogenated organic derivatives. According to the inventive method, a carbon-carbon or carbon-heteroatom bond is formed by reacting an unsaturated compound carrying a leaving group with a nucleophilic compound donating a carbon atom or a heteroatom (HE) that can substitute the leaving group, thus forming a C—C or C—HE bond, in the presence of a copper-based catalyst and a base. Said metal is characterised in that the reaction takes place in the absence of a ligand and in a nitrile-type solvent.

  该发明涉及一种通过在缺乏配体的情况下，使携带一个离去基团的不饱和化合物与一个亲核化合物发生反应，形成碳-碳或碳-杂原子键的方法。该发明的目的特别是根据一种对氮杂有机衍生物进行芳基化的方法形成碳-氮键。根据该创新方法，通过使携带一个离去基团的不饱和化合物与提供一个可替代离去基团的碳原子或杂原子（HE）的亲核化合物发生反应，在铜基催化剂和碱的存在下形成碳-碳或碳-杂原子键。所述金属的特征在于反应在缺乏配体和硝基型溶剂的情况下进行。
• POLYCYCLIC AROMATIC COMPOUND
  申请人：Kwansei Gakuin Educational Foundation

  公开号：US20200190115A1

  公开（公告）日：2020-06-18

  The present invention provides a novel polycyclic aromatic compound having a plurality of aromatic rings linked by a boron atom, a nitrogen atom, and the like, and thus increases the number of alternatives of a material for an organic electroluminescent (EL) device. Furthermore, the present invention provides an excellent organic EL device by using a novel polycyclic aromatic compound as a material for an organic EL device.

  本发明提供了一种新型多环芳香化合物，其中多个芳香环由硼原子、氮原子等连接，从而增加了有机电致发光（EL）器件材料的选择。此外，本发明通过使用新型多环芳香化合物作为有机EL器件的材料，提供了优秀的有机EL器件。
• [EN] NOVEL ORGANIC ELECTROLUMINESCENT COMPOUNDS AND ORGANIC ELECTROLUMINESCENT DEVICE USING THE SAME<br/>[FR] NOUVEAUX COMPOSÉS ORGANIQUES ÉLECTROLUMINESCENTS ET DISPOSITIF ORGANIQUE ÉLECTROLUMINESCENT LES UTILISANT
  申请人：GRACEL DISPLAY INC

  公开号：WO2010050781A1

  公开（公告）日：2010-05-06

  Disclosed Provided are a novel organic electroluminescent compound and an organic electroluminescent device using the same as an electroluminescent material. The disclosed organic electroluminescent compound is represented by Chemical Formula 1: (Formula I should be inserted here) wherein Ar1 represents (C6-C60)arylene, (C3~C60)heteroarylene containing one or more heteroatom(s) selected from N, O and S, 5- or 6-membered heterocycloalkylene containing one or more heteroatom(s) selected from N, O and S, (C3-C60)cycloalkylene, adamantylene, (C7-C60)bicycloalkylene, (C2-C60)alkenylene, (C2-C60)alkynylene, (Cl-C60)alkylenethio, (Cl-C60)alkyleneoxy, (C6-C60)aryleneoxy, (C6-C60)arylenethio or; (Formula II should be inserted here) and ring A and ring B independently represent a 5- to 7-membered heterocyclic amino group or a ring selected from the following structures: (Formula III should be inserted here) wherein the 5- to 7-membered heterocyclic amino group may further contain NR2I or one or more heteroatom(s) selected from O and S. The organic electroluminescent compound provides superior luminous efficiency and excellent life property. Therefore, it may be used to manufacture OLED devices having very good operation life.

  公开了一种新颖的有机电致发光化合物及使用该化合物作为电致发光材料的有机电致发光器件。所公开的有机电致发光化合物由化学式1表示：其中Ar1代表(C6-C60)芳基、(C3~C60)含有来自N、O和S的一个或多个杂原子的杂芳基、含有来自N、O和S的一个或多个杂原子的5-或6-成员杂环烷基、(C3-C60)环烷基、金刚烷基、(C7-C60)双环烷基、(C2-C60)烯烃基、(C2-C60)炔基、(Cl-C60)硫代烷基、(Cl-C60)氧代烷基、(C6-C60)氧代芳基、(C6-C60)硫代芳基或；环A和环B分别表示5-至7-成员杂环氨基或从以下结构中选择的环：其中5-至7-成员杂环氨基可能进一步包含NR2I或来自O和S的一个或多个杂原子。该有机电致发光化合物提供优越的发光效率和出色的寿命特性。因此，它可用于制造具有非常良好运行寿命的OLED器件。
• Sulfonium salt, curable composition, ink composition, inkjet recording method, printed material, process for producing lithographic printing plate, and lithographic printing plate
  申请人：Tsuchimura Tomotaka

  公开号：US20070197677A1

  公开（公告）日：2007-08-23

  A sulfonium salt is provided that has a cation represented by Formula (II) (R 1′ to R 13′ in Formula (II) independently denote a hydrogen atom or a substituent, and may be bonded to each other to form a ring, provided that at least one of R 1′ to R 8′ denotes a halogen atom or a haloalkyl group). There are also provided a curable composition that includes the sulfonium salt, and an ink composition that includes the curabie composition. Furthermore, there are also provided an inkjet recording method employing the ink composition, and a process for producing a lithographic printing plate, the process including discharging the ink composition onto a hydrophilic support. A printed material and a lithographic printing plate thus obtained are also included in the present invention.

  提供一种具有由化学式（II）表示的阳离子的硫铵盐（其中，化学式（II）中的R1'到R13'独立地表示氢原子或取代基，并且它们可以结合在一起形成环，前提是R1'到R8'中至少有一个表示卤素原子或卤代烷基）。还提供了包括该硫铵盐的可固化组合物，以及包括该可固化组合物的油墨组合物。此外，还提供了一种采用该油墨组合物的喷墨记录方法，以及生产平版印刷版的工艺，其中该工艺包括将油墨组合物排放到亲水性支撑体上。本发明还包括由此获得的印刷材料和平版印刷版。