TC'T | 1014976-71-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 双噻吩和低聚噻吩
• 英文名称: TC'T
• 英文别名: 1,3-Dithiophen-2-ylcyclopenta[c]thiophene-4,6-dione
• CAS: 1014976-71-6
• 化学式: C₁₅H₈O₂S₃
• 分子量: 316.425
• InChiKey: JQGCPFTZMBVDKS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.8
• 重原子数：
  20
• 可旋转键数：
  2
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  119
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  2-三丁基甲锡烷基噻吩 、 1,3-dibromo-cyclopenta[c]thiophene-4,6-dione 在 四(三苯基膦)钯 作用下， 以 甲苯 为溶剂， 反应 12.0h， 以20%的产率得到TC'T
  参考文献：
  名称：

  Electronegative Oligothiophenes Based on Difluorodioxocyclopentene-Annelated Thiophenes:  Synthesis, Properties, and n-Type FET Performances

  摘要：

  A series of oligothiophenes containing difluorodioxocyclopentene-annelated thiophene units was synthesized, and their electronic properties and structures were investigated by spectroscopic and electrochemical measurements and X-ray analyses. The oligothiophenes having the terminal difluorodioxocyclopentene annelations showed n-type semiconducting behavior on FET devices, and the quaterthiophene revealed field-effect electron mobility as high as 1.3 x 10(-2) cm(2) V-1 s(-1).

  DOI：

  10.1021/ol7029678

文献信息

• POLYMER HAVING UNIT OBTAINED BY CONDENSATION OF DIFLUOROCYCLOPENTANEDIONE RING AND AROMATIC RING, ORGANIC THIN FILM USING THE SAME, AND ORGANIC THIN FILM DEVICE
  申请人：Sumitomo Chemical Company, Limited

  公开号：EP2123690A1

  公开（公告）日：2009-11-25

  A polymer having a repeating unit represented by the following general formula (I) and a ferrocene-based reduction potential of -1.5 to - 0.5 V as measured by a cyclic voltammetry method wherein Ar1 represents a divalent aromatic hydrocarbon group or a divalent heterocyclic group, and these groups may be substituted by a substituent.

  一种聚合物，其重复单元由以下通式(I)表示，二茂铁的还原电位用循环伏安法测定为-1.5 至-0.5 V 其中 Ar1 代表二价芳香烃基团或二价杂环基团，这些基团可被取代基取代。
• US8114956B2
  申请人：——

  公开号：US8114956B2

  公开（公告）日：2012-02-14
• Electronegative Oligothiophenes Based on Difluorodioxocyclopentene-Annelated Thiophenes:  Synthesis, Properties, and n-Type FET Performances
  作者：Yutaka Ie、Yoshikazu Umemoto、Makoto Okabe、Takahiro Kusunoki、Ken-ichi Nakayama、Yong-Jin Pu、Junji Kido、Hirokazu Tada、Yoshio Aso

  DOI：10.1021/ol7029678

  日期：2008.3.1

  A series of oligothiophenes containing difluorodioxocyclopentene-annelated thiophene units was synthesized, and their electronic properties and structures were investigated by spectroscopic and electrochemical measurements and X-ray analyses. The oligothiophenes having the terminal difluorodioxocyclopentene annelations showed n-type semiconducting behavior on FET devices, and the quaterthiophene revealed field-effect electron mobility as high as 1.3 x 10(-2) cm(2) V-1 s(-1).