申请人:SHIN-ETSU CHEMICAL CO., LTD.
公开号:US10550287B2
公开(公告)日:2020-02-04
A solvent-free silicone-modified polyimide resin composition having fluidity and including no solvent, the composition containing
(A) a silicone-modified polyimide resin of formula (1),
Ee-Ff-Gg (1)
(E is formula (2), F is formula (3), and G is a diamine-derived divalent residue; f+e+g=100 mol %, the molar ratio of f/(e+g) is 0.8-1.2)
(RA is a divalent hydrocarbon group, R1-R4 are monovalent hydrocarbon groups, R5 and R6 are an alkyl group, aryl group, or aralkyl group; m, n, and o are 0-20, n+o≥1, m+n+o=1-60)
-Im-X-Im- (3)
(Im is a cyclic group including a cyclic imide structure, X is a single bond, oxygen, sulfur, sulfide group, sulfone group, carbonyl group, —NRN—, —CRB2—, RArh—, —RArh(ORAr)i—, alkylene group, trivalent group having one H eliminated from said group, or arylene-alkylene group),
(B) a polymerizable compound,
(C) a polymerization initiator, and
(D) hydrophobic fumed silica.
This composition has excellent handleability due to its fluidity and thixotropy.
一种无溶剂
硅改性聚
酰亚胺树脂组合物,具有流动性且不含溶剂,该组合物包含
(A) 式(1)的
硅改性聚
酰亚胺树脂、
Ee-Ff-Gg (1)
(E为式(2),F为式(3),G为二胺衍生的二价残基;f+e+g=100 摩尔%,f/(e+g)的摩尔比为 0.8-1.2)
(RA 为二价烃基,R1-R4 为一价烃基,R5 和 R6 为烷基、芳基或芳烷基;m、n 和 o 为 0-20,n+o≥1,m+n+o=1-60)。
-Im-X-Im- (3)
(Im 是包括环状
亚胺结构的环状基团,X 是单键、氧、
硫、
硫醚基团、砜基团、羰基、-NRN-、-CRB2-、RArh-、-RArh(ORAr)-、亚烷基、从所述基团中去除一个 H 的三价基团或芳基-亚烷基)、
(B) 可聚合化合物、
(C) 聚合
引发剂,以及
(D) 疏
水性气相法
二氧化硅。
由于具有流动性和触变性,这种组合物具有极佳的可操作性。