5-(2-chloroethyl)-2-norbornene | 39852-71-6

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 有机氯化物
• 英文名称: 5-(2-chloroethyl)-2-norbornene
• 英文别名: 5-(2-Chloroethyl)bicyclo[2.2.1]hept-2-ene
• CAS: 39852-71-6
• 化学式: C₉H₁₃Cl
• mdl: MFCD19234695
• 分子量: 156.655
• InChiKey: JCHDZHTVBMCNRM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3
• 重原子数：
  10
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.777
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  5-(2-chloroethyl)-2-norbornene 、 甲基二苯基氯硅烷 在 magnesium 作用下， 以 四氢呋喃 为溶剂， 反应 14.0h， 以38 g的产率得到5-(2-diphenylmethylsilylethyl)-2-norbornene
  参考文献：
  名称：

  JP6207287

  摘要：

  公开号：

文献信息

• MASS POLYMERIZABLE POLYCYCLOOLEFIN COMPOSITIONS CONTAINING SOLUBLE PHOTOACID GENERATORS
  申请人：PROMERUS, LLC

  公开号：US20210380733A1

  公开（公告）日：2021-12-09

  Embodiments in accordance with the present invention encompass compositions comprising a soluble photoacid generator, a organopalladium compound, a photosensitizer and one or more olefinic monomers which undergo vinyl addition polymerization when said composition is exposed to a suitable actinic radiation to form a substantially transparent film. The monomers employed therein have a range of optical and mechanical properties, and thus these compositions can be tailored to form films having various opto-electronic properties. Accordingly, compositions of this invention are useful in various applications, including as coatings, encapsulants, fillers, leveling agents, among others.

  根据本发明的实施例，包括可溶性光酸发生剂、有机钯化合物、光敏剂和一种或多种烯烃单体的组合物被涵盖在内，当该组合物暴露于适当的光辐射下时，这些单体会经历乙烯基加成聚合反应，形成一个基本透明的薄膜。其中使用的单体具有不同的光学和机械性能，因此这些组合物可以定制成具有各种光电性能的薄膜。因此，本发明的组合物在各种应用中都是有用的，包括作为涂料、封装材料、填充剂、平整剂等。
• Novel tertiary alcohol compounds having an alicyclic structure
  申请人：——

  公开号：US20020087033A1

  公开（公告）日：2002-07-04

  The present invention provides novel tertiary alcohol compounds which are useful as monomers for the preparation of photoresist materials having high transparency and a great affinity for the substrate and hence suitable for use in photolithography using a light source comprising preferably light having a wavelength of 300 nm or less and more preferably light emitted from an ArF excimer laser. Specifically, the present invention provides tertiary alcohols compounds represented by the following general formula (1): 1 wherein R 1 and R 2 each independently represents a straight-chain, branched or cyclic alkyl group having 1 to 10 carbon atoms, in which some or all of the hydrogen atoms on the constituent carbon atoms may be replaced by a halogen atom or halogen atoms, or R 1 and R 2 may be joined together to form an aliphatic hydrocarbon ring; Z represents a straight-chain, branched or cyclic divalent organic group having 2 to 10 carbon atoms; and k is 0 or 1.

  本发明提供了一种新型的三级醇化合物，它们可用作单体，用于制备具有高透明度和对基底具有很强亲和力的光阻材料，因此适用于使用光源的光刻。该光源最好具有300纳米或更短波长的光，更好的是从ArF准分子激光发射的光。具体而言，本发明提供了由下式（1）表示的三级醇化合物： 其中，R1和R2各自独立地表示具有1到10个碳原子的直链、支链或环烷基，其中构成碳原子上的一些或所有氢原子可以被卤素原子或卤素原子替代，或者R1和R2可以结合形成脂肪族碳氢化合物环；Z表示具有2到10个碳原子的直链、支链或环状双价有机基团；k为0或1。
• Functional norbornenes and polymeric derivatives and fabrication thereof
  申请人：Liaw Der-Jang

  公开号：US20070173609A1

  公开（公告）日：2007-07-26

  The present invention relates to novel functional norbornenes as initiators for radical polymerization, its polymer and a process for producing the same. More particularly, the novel functional norbornenes can be selectively polymerized by ring-opening metathesis polymerization or radical polymerization to obtain various polynorbornene derivatives or grafted copolymer materials. The polynorbornene derivatives and grafted copolymer materials not only exhibit excellent functional properties but also enhanced physical and chemical properties after modification. The polynorbornene derivatives and grafted copolymer materials disclosed in the present invention exhibit excellent heat resistance, transparency and water resistance. The present invention also deals with a process for producing such derivatives and materials having controllable molecular weight with narrow molecular weight distribution.

  本发明涉及一种新型的功能性诺伯烯作为自由基聚合引发剂，以及其聚合物和制备方法。更具体地说，这些新型的功能性诺伯烯可以通过开环重排聚合或自由基聚合选择性地聚合，以获得各种聚诺伯烯衍生物或接枝共聚物材料。这些聚诺伯烯衍生物和接枝共聚物材料不仅具有优异的功能性能，而且在改性后还具有增强的物理和化学性能。本发明所披露的聚诺伯烯衍生物和接枝共聚物材料具有优异的耐热性、透明度和耐水性。本发明还涉及一种制备具有可控分子量和窄分子量分布的这些衍生物和材料的方法。
• Modified monoolefin copolymer elastomer with improved heat and oil resistance
  申请人：UNIROYAL, INC.

  公开号：EP0015627A1

  公开（公告）日：1980-09-17

  An EPM or EPDM type of elastomer is modified by graft copolymerization with acrylic ester type of monomeric material whose homopolymer has a glass transition temperature of not greater than 6° C, in an amount sufficient to provide an ester group (-COO-) content of from 25 to 40% by weight, to yield a mixed copolymerizate vulcanizable to a heat and oil resistant elastomeric state.

  通过与丙烯酸酯类单体材料接枝共聚改性 EPM 或 EPDM 弹性体，其均聚物的玻璃化转变温度不高于 6 摄氏度，其用量足以使酯基（-COO-）含量达到 25% 至 40% （按重量计），从而得到可硫化成耐热耐油弹性体状态的混合共聚物。
• Vulcanizable acrylic rubber composition
  申请人：ENICHEM S.p.A.

  公开号：EP0796890A1

  公开（公告）日：1997-09-24

  The present invention relates to a method and composition for vulcanizing acrylic gum containing active halogen groups, wherein a mixture of 2,5-dimercapto-1,3,4-thiadiazole and a metal dialkyldithiocarbamate is added thereto, and the mixture is heated. The method advantageously requires no post cure.

  本发明涉及一种硫化含有活性卤素基团的丙烯酸树胶的方法和组合物，其中加入 2,5-二巯基-1,3,4-噻二唑和金属二烷基二硫代氨基甲酸酯的混合物，并加热该混合物。该方法的优点是无需后固化。