2,6-Dimethyl-1,5-dihydro-s-indacene | 260061-08-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 茚和异茚
• 英文名称: 2,6-Dimethyl-1,5-dihydro-s-indacene
• CAS: 260061-08-3
• 化学式: C₁₄H₁₄
• 分子量: 182.265
• InChiKey: ZIYWZFIEWGTJOR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.3
• 重原子数：
  14
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.29
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  di-μ-chloro-bis(1,5-cyclooctadiene)dirhodium 、 2,6-Dimethyl-1,5-dihydro-s-indacene 在 KH 作用下， 以 四氢呋喃 为溶剂， 生成 2,6-dimethyl-5-hydro-s-indacenide-Rh(I)(cyclooctadiene)
  参考文献：
  名称：

  Synthesis, properties and reactivity of mononuclear Rh(I) and Ir(I) complexes of s- and as-hydroindacenide ligands

  摘要：

  The monometallic complexes with Rh(COD) and Ir(COD) of 1,5- and 1,7-dihydro-s-indacene, 2,6-dimethyl-1,5-dihydro-s-indacene and 2,7-dimethyl-1,6-dihydro-as-indacene have been synthesized and characterized spectroscopically and structurally. Deprotonation and further complexation of these compounds afforded mixtures of syn and anti homobimetallic isomers. The syn/anti ratio depends on the structure of the ion pairs of the salt and on the s or as geometry of the bridging ligand. (C) 2000 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(99)00522-7
• 作为产物：
  描述：

  2,6-Bis(chloromethyl)-1,5-dihydro-s-indacene 在 三乙基硼氢化锂 作用下， 生成 2,6-Dimethyl-1,5-dihydro-s-indacene
  参考文献：
  名称：

  Pentamethylcyclopentadienyl rhodium complexes of 1,5- and 1,7-dihydro-s-indacenes and their derivatives

  摘要：

  DOI：

  10.1016/s0040-4039(00)87328-1

文献信息

• Synthesis, properties and reactivity of mononuclear Rh(I) and Ir(I) complexes of s- and as-hydroindacenide ligands
  作者：Annalisa Bisello、Alberto Ceccon、Alessandro Gambaro、Paolo Ganis、Francesco Manoli、Saverio Santi、Alfonso Venzo

  DOI：10.1016/s0022-328x(99)00522-7

  日期：2000.1

  The monometallic complexes with Rh(COD) and Ir(COD) of 1,5- and 1,7-dihydro-s-indacene, 2,6-dimethyl-1,5-dihydro-s-indacene and 2,7-dimethyl-1,6-dihydro-as-indacene have been synthesized and characterized spectroscopically and structurally. Deprotonation and further complexation of these compounds afforded mixtures of syn and anti homobimetallic isomers. The syn/anti ratio depends on the structure of the ion pairs of the salt and on the s or as geometry of the bridging ligand. (C) 2000 Elsevier Science S.A. All rights reserved.
• Pentamethylcyclopentadienyl rhodium complexes of 1,5- and 1,7-dihydro-s-indacenes and their derivatives
  作者：Peter Bickert、Klaus Hafner

  DOI：10.1016/s0040-4039(00)87328-1

  日期：1982.1