5,6-dioctylnaphtho[2,1-b:3,4-b']dithiophene | 1040858-81-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 5,6-dioctylnaphtho[2,1-b:3,4-b']dithiophene
• 英文别名: 14,15-dioctyl-5,8-dithiatetracyclo[10.4.0.02,6.07,11]hexadeca-1,3,6,9,11,13,15-heptaene
• CAS: 1040858-81-8
• 化学式: C₃₀H₄₀S₂
• 分子量: 464.78
• InChiKey: PKMPKOCWOBMTEN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  13.3
• 重原子数：
  32
• 可旋转键数：
  14
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.53
• 拓扑面积：
  56.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  1,2-dioctylbenzene 在 碘 、 sodium thiosulfate 作用下， 以 乙醇 、 水 、 溶剂黄146 、 甲苯 为溶剂， 生成 5,6-dioctylnaphtho[2,1-b:3,4-b']dithiophene
  参考文献：
  名称：

  POLYMERS WITH TUNABLE BAND GAPS FOR PHOTONIC AND ELECTRONIC APPLICATIONS

  摘要：

  本发明提供了一种共聚物，包括至少一个给体单体和至少一个受体单体。该聚合物可以选择性地进一步包括至少一个额外的共聚单体。这些聚合物可用作电荷传输、半导体、电化学导电、光导电或发光材料。还描述了包括这些聚合物的微电子器件（例如，作为异质结的一部分）。

  公开号：

  US20130092912A1

文献信息

• Polymers with tunable band gaps for photonic and electronic applications
  申请人：You Wei

  公开号：US09184390B2

  公开（公告）日：2015-11-10

  The present invention provides, among other things, a copolymer comprising at least one donor monomer and at least one acceptor monomer. The polymer may optionally further comprise at least one additional comonomer. The polymers are useful as a charge-transport, semiconducting, electrochemical conducting, photoconducting, or light emitting material. Microelectronic devices comprising such polymers (e.g., as a heterojunction therein) are also described.

  本发明提供了一种共聚物，其中包括至少一种给体单体和至少一种受体单体。该聚合物还可以选择性地包含至少一种额外的共聚单体。这些聚合物可用作电荷传输、半导体、电化学导电、光电导或发光材料。还描述了包括这种聚合物的微电子器件（例如，作为异质结）。
• NOVEL COMPOSITIONS, METHODS AND POLYMERS
  申请人：Brown Christopher T.

  公开号：US20110028644A1

  公开（公告）日：2011-02-03

  A composition comprising a homopolymer or a copolymer comprising bithiophene units for use in, for example, low band gap materials including uses in organic photovoltaic active layers. The band gap and other properties can be engineered by polymerization methods including selection of monomer structure and ratio of monomer components. In addition, a dimer adapted for making alternating copolymers further comprising one first monomer moiety comprising at least one bithiophene moiety compound covalently linked to one second monomer moiety comprising a different bithiophene moiety or at least one moiety that is not a bithiophene. The composition can be copolymerized to form an alternating copolymer that can be further processed to form a polymeric film used in a printed organic electronic device. A series of novel copolymers are designed that would allow fabrication of materials with tailor made electronic and/or mechanical properties that can be easily manipulated through molecules chemical structure and potentially result in long term stability under ambient conditions that can be advantageous for use in organic electronics (e.g., OPVs, OLEDs, OFETs). Improved methods are disclosed for making monomers comprising a benzo[2,1-b:3,4-b′]dithiophene moiety that are useful as electronics materials.

  该组成物包括一种由噻吩单元组成的同聚物或共聚物，例如，用于低带隙材料，包括在有机光伏活性层中使用。可以通过聚合方法，包括选择单体结构和单体组分的比例来设计带隙和其他性质。此外，还提供了一种二聚体，适用于制备交替共聚物，该二聚体进一步包括一个第一单体基团，包括至少一个噻吩基团化合物与一个第二单体基团共价连接，第二单体基团包括不同的噻吩基团或至少一个不是噻吩的基团。该组成物可以共聚合形成交替共聚物，进一步加工成用于印刷有机电子器件的聚合膜。设计了一系列新型共聚物，可允许制备具有定制电子和/或机械性能的材料，这些性能可以通过分子化学结构轻松操纵，并且在环境条件下具有长期稳定性，这对于有机电子学（例如，OPV、OLED、OFET）的使用非常有优势。还公开了用于制备含苯并[2,1-b:3,4-b′]噻吩基团的单体的改进方法，这些单体在电子材料中很有用。
• US8440785B2
  申请人：——

  公开号：US8440785B2

  公开（公告）日：2013-05-14
• US9184390B2
  申请人：——

  公开号：US9184390B2

  公开（公告）日：2015-11-10
• POLYMERS WITH TUNABLE BAND GAPS FOR PHOTONIC AND ELECTRONIC APPLICATIONS
  申请人：You Wei

  公开号：US20130092912A1

  公开（公告）日：2013-04-18

  The present invention provides, among other things, a copolymer comprising at least one donor monomer and at least one acceptor monomer. The polymer may optionally further comprise at least one additional comonomer. The polymers are useful as a charge-transport, semiconducting, electrochemical conducting, photoconducting, or light emitting material. Microelectronic devices comprising such polymers (e.g., as a heterojunction therein) are also described.

  本发明提供了一种共聚物，包括至少一个给体单体和至少一个受体单体。该聚合物可以选择性地进一步包括至少一个额外的共聚单体。这些聚合物可用作电荷传输、半导体、电化学导电、光导电或发光材料。还描述了包括这些聚合物的微电子器件（例如，作为异质结的一部分）。