6-chloro-2-methylhex-1-ene | 68012-01-1

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 有机氯化物
• 英文名称: 6-chloro-2-methylhex-1-ene
• 英文别名: 6-Chlor-2-methyl-1-hexen
• CAS: 68012-01-1
• 化学式: C₇H₁₃Cl
• 分子量: 132.633
• InChiKey: BTDYONIARBEIAO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.3
• 重原子数：
  8
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.71
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  (E)-3-methylbut-3-en-2-one O-pivaloyl oxime 、 6-chloro-2-methylhex-1-ene 在 六氟异丙醇 、 [Cp*^CF3Rh(MeCN)₃](SbF₆)₂ 、 cesium acetate 作用下， 反应 12.0h， 以81%的产率得到
  参考文献：
  名称：

  Expedient Access to 2,3-Dihydropyridines from Unsaturated Oximes by Rh(III)-Catalyzed C–H Activation

  摘要：

  alpha,beta-Unsaturated - oxime pivalates are proposed to undergo reversible C(sp(2))-H insertion with cationic Rh (III) complexes to furnish five-membered metallacycles. In the presence of 1,1-disubstituted olefins, these species participate in irreversible migratory insertion to give, after reductive elimination, 2,3-dihydropyridine products in good yields. Catalytic hydrogenation can then be used to. convert these molecules into piperidines, which are important structural components of numerous pharmaceuticals.

  DOI：

  10.1021/jacs.5b04946
• 作为产物：
  描述：

  2-甲基-1,5-环己二烯 生成 6-chloro-2-methylhex-1-ene
  参考文献：
  名称：

  有机铝与铜（II）卤化物的反应。通过氢铝化制备烷基卤化物的便捷途径

  摘要：

  四烷基铝锂与氯化铜或溴化铜(II)的反应以良好的产率得到相应的烷基卤化物。简便的反应为分别从 1-烯烃或非共轭二烯烃制备 1-卤代烷烃或 1-卤代烯烃提供了方便的方法。

  DOI：

  10.1246/cl.1978.833

文献信息

• REACTIONS OF ORGANOALUMINUMS WITH COPPER(II) HALIDES. A CONVENIENT ROUTE TO ALKYL HALIDES PROM OLEFINS VIA HYDROALUMINATION
  作者：Fumie Sato、Yoshikuni Mori、Masao Sato

  DOI：10.1246/cl.1978.833

  日期：1978.8.5

  The reaction of lithium tetraalkylaluminums with copper(ll) chloride or bromide gives the corresponding alkyl halides in good yield. The facile reaction offers a convenient method for the preparation of 1-haloalkanes or 1-haloalkenes from 1-alkenes or nonconjugated diolefins, respectively.

  四烷基铝锂与氯化铜或溴化铜(II)的反应以良好的产率得到相应的烷基卤化物。简便的反应为分别从 1-烯烃或非共轭二烯烃制备 1-卤代烷烃或 1-卤代烯烃提供了方便的方法。
• SATO F.; MORI G.; SATO M., CHEM. LETT., 1978, NO 8, 833-834
  作者：SATO F.、 MORI G.、 SATO M.

  DOI：——

  日期：——
• COMPOSITION FOR FORMING PATTERN, KIT, PATTERN PRODUCING METHOD, PATTERN, AND METHOD FOR MANUFACTURING SEMICONDUCTOR ELEMENT
  申请人：FUJIFILM Corporation

  公开号：US20220002450A1

  公开（公告）日：2022-01-06

  Provided are: a composition for forming a pattern for imprinting, which contains a polymerizable compound, a photopolymerization initiator, and an organic halogen compound containing at least one atom selected from the group consisting of a chlorine atom, a bromine atom, and an iodine atom, in which the organic halogen compound is a compound which is stable to light of a mercury lamp, and a content of the organic halogen compound is 0.001% to 1.0% by mass with respect to a total solid content in the composition for forming a pattern; a kit including the composition for forming a pattern; a pattern producing method; a pattern; and a method for manufacturing a semiconductor element.
• Expedient Access to 2,3-Dihydropyridines from Unsaturated Oximes by Rh(III)-Catalyzed C–H Activation
  作者：Fedor Romanov-Michailidis、Kassandra F. Sedillo、Jamie M. Neely、Tomislav Rovis

  DOI：10.1021/jacs.5b04946

  日期：2015.7.22

  alpha,beta-Unsaturated - oxime pivalates are proposed to undergo reversible C(sp(2))-H insertion with cationic Rh (III) complexes to furnish five-membered metallacycles. In the presence of 1,1-disubstituted olefins, these species participate in irreversible migratory insertion to give, after reductive elimination, 2,3-dihydropyridine products in good yields. Catalytic hydrogenation can then be used to. convert these molecules into piperidines, which are important structural components of numerous pharmaceuticals.