N,N,N',N',N'',N''-hexapropylphosphorimidic triamide | 78050-95-0

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N,N,N',N',N'',N''-hexapropylphosphorimidic triamide
• 英文别名: hexapropyl-N'''-phosphorimidic triamide；N-bis(dipropylamino)phosphinimyl-N-propylpropan-1-amine
• CAS: 78050-95-0
• 化学式: C₁₈H₄₃N₄P
• 分子量: 346.54
• InChiKey: QHYUDGDYWJXYMN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.7
• 重原子数：
  23
• 可旋转键数：
  15
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  33.6
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  N,N,N',N',N'',N''-hexapropylphosphorimidic triamide 在 氢氧化钾 、 sodium perchlorate 、 氯 作用下， 以 四氯化碳 、 乙醚 、 水 为溶剂， 反应 11.5h， 生成
  参考文献：
  名称：

  Marchenko, A. P.; Koidan, G. N.; Pinchuk, A. M., Journal of general chemistry of the USSR, 1983, vol. 53, # 3, p. 583 - 589

  摘要：

  DOI：
• 作为产物：
  描述：

  N'''-(phenylsulfonyl)-N,N,N',N',N'',N''-hexapropylphosphorimidic triamide 在 sodium 作用下， 以 甲苯 为溶剂， 反应 0.5h， 以88%的产率得到N,N,N',N',N'',N''-hexapropylphosphorimidic triamide
  参考文献：
  名称：

  Zal'tsman, I. S.; Marchenko, A. P.; Koidan, G. N., Journal of general chemistry of the USSR, 1985, vol. 55, # 8, p. 1673 - 1674

  摘要：

  DOI：

文献信息

• BORATE-BASED BASE GENERATOR, AND BASE-REACTIVE COMPOSITION COMPRISING SUCH BASE GENERATOR
  申请人：WAKO PURE CHEMICAL INDUSTRIES, LTD.

  公开号：US20160340374A1

  公开（公告）日：2016-11-24

  An object of the present invention is to provide a compound which is capable of attaining a composition having high storage stability without reacting with a base-reactive compound, even in the case of storage for a long period of time in a mixed state with the base-reactive compound, such as an epoxy-based compound, as well as capable of generating a strong base (guanidines, biguanides, phosphazenes or phosphoniums) by irradiation of light (active energy rays) or heating; a base generator comprising the compound; and a base-reactive composition comprising the base generator and the base-reactive compound. The present invention relates to the compound represented by the general formula (A); the base generator comprising the compound; and the base-reactive composition comprising the base generator and the base-reactive compound. (wherein R 1 represents an alkyl group; an arylalkynyl group which may be substituted with a halogen atom, an alkyl group, an alkoxy group, or an alkylthio group; an alkenyl group; a 2-furylethynyl group; a 2-thiophenylethynyl group; or a 2,6-dithianyl group; R 2 to R 4 each independently represent an alkyl group; an arylalkynyl group which may be substituted with a halogen atom, an alkyl group, an alkoxy group, or an alkylthio group; the aryl group which may be substituted with a halogen atom, an alkyl group, an alkoxy group, or an alkylthio group; a furanyl group; a thienyl group; or an N-alkyl-substituted pyrrolyl group; Z + represents an ammonium cation having a guanidinium group, a biguanidium group or a phosphazenium group, or a phosphonium cation.)

  本发明的目的是提供一种化合物，能够在与碱反应性化合物混合状态长时间存储的情况下，仍能获得具有高储存稳定性的组合物，而不与碱反应性化合物发生反应，同时还能通过光照（活性能量射线）或加热产生强碱（胍胺、双胍胺、磷氮烷或磷銨）；包括该化合物的碱发生器；以及包括该碱发生器和碱反应性化合物的碱反应性组合物。本发明涉及由通式（A）表示的化合物；包括该化合物的碱发生器；以及包括该碱发生器和碱反应性化合物的碱反应性组合物。（其中R1代表烷基；可能被卤素原子、烷基、烷氧基或烷硫基取代的芳基炔基；烯基；2-呋喃基炔基；2-噻吩基炔基；或2,6-二硫基基；R2到R4各自独立地代表烷基；可能被卤素原子、烷基、烷氧基或烷硫基取代的芳基炔基；可能被卤素原子、烷基、烷氧基或烷硫基取代的芳基；呋喃基；噻吩基；或N-烷基取代的吡咯基；Z+代表具有胍胺基团、双胍胺基团或磷氮烷基团的铵阳离子，或磷銨阳离子。）
• Borate-based base generator, and base-reactive composition comprising such base generator
  申请人：FUJIFILM Wako Pure Chemical Corporation

  公开号：US10100070B2

  公开（公告）日：2018-10-16

  A compound capable of providing a composition having high storage stability without reacting with a base-reactive compound, even when stored in a mixed state with the base-reactive compound, as well as capable of generating a strong base by irradiation of light (active energy rays) or heating. A base generator comprises the compound and a base-reactive composition comprises the base generator and the base-reactive compound. The compound is represented by the general formula (A).

  一种化合物，能够提供一种具有高储存稳定性的组合物，即使在与碱反应化合物混合储存的状态下，也不会与碱反应化合物发生反应，并且能够通过光（活性能量射线）照射或加热生成强碱。碱发生器由该化合物组成，碱反应组合物由碱发生器和碱反应化合物组成。该化合物由通式 (A) 表示。
• Koidan, G. N.; Marchenko, A. P.; Kudryavtsev, A. A., Journal of general chemistry of the USSR, 1982, vol. 52, p. 1779 - 1787
  作者：Koidan, G. N.、Marchenko, A. P.、Kudryavtsev, A. A.、Pinchuk, A. M.

  DOI：——

  日期：——
• KOJDAN, G. N.;MARCHENKO, A. P.;KUDRYAVTSEV, A. A.;PINCHUK, A. M., ZH. OBSHCH. XIMII, 1982, 52, N 9, 2001-2011
  作者：KOJDAN, G. N.、MARCHENKO, A. P.、KUDRYAVTSEV, A. A.、PINCHUK, A. M.

  DOI：——

  日期：——
• MARCHENKO, A. P.;KOJDAN, G. N.;PINCHUK, A. M., ZH. OBSHCH. XIMII, 1983, 53, N 3, 670-677
  作者：MARCHENKO, A. P.、KOJDAN, G. N.、PINCHUK, A. M.

  DOI：——

  日期：——