5-(4-Dimethoxymethyl-phenyl)-10-phenyl-5,10-dihydro-phenazine | 500556-05-8

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 5-(4-Dimethoxymethyl-phenyl)-10-phenyl-5,10-dihydro-phenazine
• 英文别名: 5-[4-(Dimethoxymethyl)phenyl]-10-phenyl-5,10-dihydrophenazine；5-[4-(dimethoxymethyl)phenyl]-10-phenylphenazine
• CAS: 500556-05-8
• 化学式: C₂₇H₂₄N₂O₂
• 分子量: 408.5
• InChiKey: JMUOHKOJEOGXSX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.8
• 重原子数：
  31
• 可旋转键数：
  5
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.11
• 拓扑面积：
  24.9
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  5-(4-Dimethoxymethyl-phenyl)-10-phenyl-5,10-dihydro-phenazine 以95%的产率得到5-p-formylphenyl-10-phenyl-5,10-dihydrophenazine
  参考文献：
  名称：

  Facile Synthesis of 5,10-Diaryl-5,10-dihydrophenazines and Application to EL Devices

  摘要：

  An efficient method for the synthesis of 5,10-diaryldihydrophenazine was developed using a recently developed Pd(0)-mediated cross-coupling reaction. The products 1k and 3c showed excellent properties as hole injection materials in electroluminescent (EL) devices.

  DOI：

  10.1021/ol0274458
• 作为产物：
  描述：

  酚嗪 在 三叔丁基膦 、 palladium diacetate 、 sodium t-butanolate 作用下， 以 乙醚 、 邻二甲苯 为溶剂， 反应 3.0h， 生成 5-(4-Dimethoxymethyl-phenyl)-10-phenyl-5,10-dihydro-phenazine
  参考文献：
  名称：

  Facile Synthesis of 5,10-Diaryl-5,10-dihydrophenazines and Application to EL Devices

  摘要：

  An efficient method for the synthesis of 5,10-diaryldihydrophenazine was developed using a recently developed Pd(0)-mediated cross-coupling reaction. The products 1k and 3c showed excellent properties as hole injection materials in electroluminescent (EL) devices.

  DOI：

  10.1021/ol0274458

文献信息

• Facile Synthesis of 5,10-Diaryl-5,10-dihydrophenazines and Application to EL Devices
  作者：Toshihiro Okamoto、Eriko Terada、Masatoshi Kozaki、Manabu Uchida、Shingo Kikukawa、Keiji Okada

  DOI：10.1021/ol0274458

  日期：2003.2.1

  An efficient method for the synthesis of 5,10-diaryldihydrophenazine was developed using a recently developed Pd(0)-mediated cross-coupling reaction. The products 1k and 3c showed excellent properties as hole injection materials in electroluminescent (EL) devices.