2,6-dimethyl-4-(prop-1-en-1-yl)phenol | 49583-11-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: 2,6-dimethyl-4-(prop-1-en-1-yl)phenol
• 英文别名: (E)-2,6-Dimethyl-4-propenyl-phenol；2,6-Dimethyl-4t-propenylphenol；2,6-dimethyl-4-[(E)-prop-1-enyl]phenol
• CAS: 49583-11-1
• 化学式: C₁₁H₁₄O
• 分子量: 162.232
• InChiKey: XTKIDYLXKJSJQU-SNAWJCMRSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.3
• 重原子数：
  12
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.27
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  5-烯丙基-2-甲氧基-1,3-二甲基苯 在 sodium hydroxide 、 甲基碘化镁 、 五羰基铁 作用下， 以 乙醚 为溶剂， 生成 2,6-dimethyl-4-(prop-1-en-1-yl)phenol
  参考文献：
  名称：

  2-乙烯基和2-烯丙基苯酚中芳香族氢的转移

  摘要：

  2-乙烯基和2-烯丙基苯酚的芳香性向氢转移

  DOI：

  10.1002/hlca.19770600624

文献信息

• Controllable synthesis of 2- and 3-aryl-benzomorpholines from 2-aminophenols and 4-vinylphenols
  作者：Kui Dong、Xiao-Ling Jin、Shihao Chen、Li-Zhu Wu、Qiang Liu

  DOI：10.1039/d0cc02662j

  日期：——

  We present herein a method for the controllable synthesis of 3-aryl-benzomorpholine and 2-aryl-benzomorpholine cycloadducts via cross-coupling/annulation between electron-rich 2-aminophenols and 4-vinylphenols.

  我们在此提出一种方法，通过电子丰富的2-氨基酚和4-乙烯基酚之间的交叉偶联/环合反应，可控合成3-芳基-苯并吗啉和2-芳基-苯并吗啉环加成物。
• SOLUBLE BRANCHED POLYMERS
  申请人：Grigoras Cristian

  公开号：US20140303313A1

  公开（公告）日：2014-10-09

  Branched polymers are prepared from at least (A) at least one monomer having an electron donor moiety, (B) at least one monomer having an electron acceptor moiety, and (C) at least one multifunctional branching agent comprising a urea moiety and at least two N-vinyl groups. The branched polymers are least 20% (by weight) soluble in a solvent for which the corresponding polymer of equal molecular weight made without said multifunctional branching agent is at least 20% (by weight) soluble. Due in part to the wide range of chemistries and solubility and rheological properties, the branched polymers find application in personal care, pharmaceutical/nutritional, and performance chemicals compositions.

  分支聚合物由至少（A）至少一种具有电子给体基团的单体，（B）至少一种具有电子受体基团的单体和（C）至少一种多功能分支剂组成，该分支剂包含尿素基团和至少两个N-乙烯基团。这些分支聚合物在相应的等分子量聚合物不含多功能分支剂的溶剂中至少有20％（重量）的溶解度，由于其广泛的化学性质、溶解度和流变性质，这些分支聚合物在个人护理、制药/营养和性能化学成分中应用广泛。
• Stereochemie und Mechanismus derPrins-Reaktion bei ausgepr�gter Ladungsdelokalisierung im intermedi�ren Carbeniumion
  作者：H. Griengl、W. Sieber

  DOI：10.1007/bf00903917

  日期：——
• US9163102B2
  申请人：——

  公开号：US9163102B2

  公开（公告）日：2015-10-20
• [EN] SOLUBLE BRANCHED POLYMERS<br/>[FR] POLYMÈRES RAMIFIÉS SOLUBLES
  申请人：ISP INVESTMENTS INC

  公开号：WO2013082359A1

  公开（公告）日：2013-06-06

  Branched polymers are prepared from at least (A) at least one monomer having an electron donor moiety, (B) at least one monomer having an electron acceptor moiety, and (C) at least one multifunctional branching agent comprising a urea moiety and at least two N-vinyl groups. The branched polymers are least 20% (by weight) soluble in a solvent for which the corresponding polymer of equal molecular weight made without said multifunctional branching agent is at least 20% (by weight) soluble. Due in part to the wide range of chemistries and solubility and rheological properties, the branched polymers find application in personal care, pharmaceutical/nutritional, and performance chemicals compositions.