[(E)-1-Chloro-3-dimethylamino-prop-2-en-(Z)-ylidene]-naphthalen-2-yl-phenyl-ammonium | 290310-56-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: [(E)-1-Chloro-3-dimethylamino-prop-2-en-(Z)-ylidene]-naphthalen-2-yl-phenyl-ammonium
• 英文别名: [3-chloro-3-(N-naphthalen-2-ylanilino)prop-2-enylidene]-dimethylazanium
• CAS: 290310-56-4
• 化学式: C₂₁H₂₀ClN₂
• 分子量: 335.856
• InChiKey: BXWRETWAAIRMSF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.4
• 重原子数：
  24
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.1
• 拓扑面积：
  6.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  [(E)-1-Chloro-3-dimethylamino-prop-2-en-(Z)-ylidene]-naphthalen-2-yl-phenyl-ammonium 在 氢氧化钾 、 三乙胺 作用下， 以 甲醇 、 水 为溶剂， 生成 2-[(naphthalen-2-yl)(phenyl)amino]thiophene
  参考文献：
  名称：

  A Simple Route to N-Arylated 2-Aminothiophenes as a New Class of Amorphous Glass Forming Molecules

  摘要：

  [GRAPHICS]By thermal decarboxylation of N-arylated 2-aminothiophene-5-cacrboxylates, a versatile, heavy-metal free method for preparing the title compounds as new class of highly reactive and easily oxidable, amorphous glass forming molecules has been elaborated.

  DOI：

  10.1021/ol015875c
• 作为产物：
  描述：

  N-(2-naphthyl)-N-phenyl-acetamide 、 N,N-二甲基甲酰胺 在 三氯氧磷 作用下， 生成 [(E)-1-Chloro-3-dimethylamino-prop-2-en-(Z)-ylidene]-naphthalen-2-yl-phenyl-ammonium
  参考文献：
  名称：

  A Simple Route to N-Arylated 2-Aminothiophenes as a New Class of Amorphous Glass Forming Molecules

  摘要：

  [GRAPHICS]By thermal decarboxylation of N-arylated 2-aminothiophene-5-cacrboxylates, a versatile, heavy-metal free method for preparing the title compounds as new class of highly reactive and easily oxidable, amorphous glass forming molecules has been elaborated.

  DOI：

  10.1021/ol015875c

文献信息

• A Simple Route to <i>N-</i>Arylated 2-Aminothiophenes as a New Class of Amorphous Glass Forming Molecules
  作者：Horst Hartmann、Peter Gerstner、Dirk Rohde

  DOI：10.1021/ol015875c

  日期：2001.5.1

  [GRAPHICS]By thermal decarboxylation of N-arylated 2-aminothiophene-5-cacrboxylates, a versatile, heavy-metal free method for preparing the title compounds as new class of highly reactive and easily oxidable, amorphous glass forming molecules has been elaborated.