2,5-di(2-thiazolyl)-3,4-di(2-thienyl)thiophene | 1443952-95-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 双噻吩和低聚噻吩
• 英文名称: 2,5-di(2-thiazolyl)-3,4-di(2-thienyl)thiophene
• 英文别名: 2,5-Di(2-thiazolyl)-3,4-di(2-thienyl)thiophene；2-[5-(1,3-thiazol-2-yl)-3,4-dithiophen-2-ylthiophen-2-yl]-1,3-thiazole
• CAS: 1443952-95-1
• 化学式: C₁₈H₁₀N₂S₅
• 分子量: 414.621
• InChiKey: YFFKEYKXYBWKBY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.7
• 重原子数：
  25
• 可旋转键数：
  4
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  167
• 氢给体数：
  0
• 氢受体数：
  7

反应信息

• 作为产物：
  描述：

  3,4-dibromo-2,5-di(2-thiazolyl)thiophene 、 2-三丁基甲锡烷基噻吩 在 tris(dibenzylideneacetone)dipalladium(0) chloroform complex 、 三(2-呋喃基)膦 作用下， 以 间二甲苯 为溶剂， 反应 20.0h， 以99%的产率得到2,5-di(2-thiazolyl)-3,4-di(2-thienyl)thiophene
  参考文献：
  名称：

  Distinct Responses to Mechanical Grinding and Hydrostatic Pressure in Luminescent Chromism of Tetrathiazolylthiophene

  摘要：

  Luminescent mechanochromism has been intensively studied in the past few years. However, the difference in the anisotropic grinding and the isotropic compression is not clearly distinguished in many cases, in spite of the importance of this discrimination for the application of such mechanochromic materials. We now report the distinct luminescent responses of a new organic fluorophore, tetrathiazolylthiophene, to these stresses. The multichromism is achieved over the entire visible region using the single fluorophore. The different mechanisms of a blue shift by grinding crystals and of a red shift under hydrostatic pressure are fully investigated, which includes a high-pressure single-crystal X-ray diffraction analysis. The anisotropic and isotropic modes of mechanical loading suppress and enhance the excimer formation, respectively, in the 3D hydrogen-bond network.

  DOI：

  10.1021/ja4055228

文献信息

• Distinct Responses to Mechanical Grinding and Hydrostatic Pressure in Luminescent Chromism of Tetrathiazolylthiophene
  作者：Kazuhiko Nagura、Shohei Saito、Hitoshi Yusa、Hiroshi Yamawaki、Hiroshi Fujihisa、Hiroyasu Sato、Yuichi Shimoikeda、Shigehiro Yamaguchi

  DOI：10.1021/ja4055228

  日期：2013.7.17

  Luminescent mechanochromism has been intensively studied in the past few years. However, the difference in the anisotropic grinding and the isotropic compression is not clearly distinguished in many cases, in spite of the importance of this discrimination for the application of such mechanochromic materials. We now report the distinct luminescent responses of a new organic fluorophore, tetrathiazolylthiophene, to these stresses. The multichromism is achieved over the entire visible region using the single fluorophore. The different mechanisms of a blue shift by grinding crystals and of a red shift under hydrostatic pressure are fully investigated, which includes a high-pressure single-crystal X-ray diffraction analysis. The anisotropic and isotropic modes of mechanical loading suppress and enhance the excimer formation, respectively, in the 3D hydrogen-bond network.