Trioctylthiophosphat | 103188-23-4

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机硫代磷酸及其衍生物
• 英文名称: Trioctylthiophosphat
• 英文别名: thiophosphoric acid O,O',O''-trioctyl ester；Thiophosphorsaeure-O,O',O''-trioctylester；O,O',O''-Trioctyl-thiophosphat；Trioctylphosphorothioate；trioctoxy(sulfanylidene)-λ5-phosphane
• CAS: 103188-23-4
• 化学式: C₂₄H₅₁O₃PS
• 分子量: 450.707
• InChiKey: YVFHKLYMBACKFA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  11.5
• 重原子数：
  29
• 可旋转键数：
  24
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  59.8
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  Thiophosphoric acid O,O',O''-tripentyl ester 、 Triheptylphosphorothioate 、 Trioctylthiophosphat 、 Tridecylphosphorothioate 、 Tridodecylphosphorothioate 、 Tripentadecylphosphorothioate 、 Trioctadecylphosphorothioate 、 Trieicosylphosphorothioate 生成 O,O,O-三丁基硫代磷酸酯
  参考文献：
  名称：

  Lubricant composition containing an alkali-metal borate and a mixture of

  摘要：

  本发明涉及一种含有磷酸盐、单硫代磷酸盐和双硫代磷酸盐的且具有临界比例的碱金属硼酸盐润滑剂。

  公开号：

  US04431552A1
• 作为产物：
  描述：

  亚磷酸三辛酯 在 sulfur 作用下， 生成 Trioctylthiophosphat
  参考文献：
  名称：

  Arbusow; Winogradowa, Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1951, p. 733,738

  摘要：

  DOI：

文献信息

• Refrigerating Machine Oil, and Working Fluid Composition for Refrigerating Machine Which is Produced Using Same
  申请人：KH NEOCHEM CO., LTD.

  公开号：US20160168500A1

  公开（公告）日：2016-06-16

  Provided is a refrigerating machine oil which comprises an ester between a polyol consisting of at least one of pentaerythritol and dipentaerythritol represented by formula (I) and 2-propylheptanoic acid, and is characterized in that the refrigerating machine oil can be used in combination with a refrigerant consisting of 1,3,3,3-tetrafluoropropene (HFO-1234ze). When the refrigerating machine oil is used in combination with a refrigerant consisting of HFO-1234ze, excellent miscibility with the refrigerant, lubricity, thermal and chemical stability and the like can be achieved.

  提供的是一种制冷机油，其包括一种酯，该酯由式（I）表示的至少含有一种戊四醇和重聚戊四醇的多元醇和2-丙基庚酸之间的酯化反应形成，其特征在于该制冷机油可以与由1,3,3,3-四氟丙烯（HFO-1234ze）组成的制冷剂结合使用。当该制冷机油与由HFO-1234ze组成的制冷剂结合使用时，可以实现与制冷剂的良好相容性、润滑性、热和化学稳定性等。
• Fluid composition for use in viscous coupling
  申请人：COSMO OIL COMPANY, LTD

  公开号：EP0599251A1

  公开（公告）日：1994-06-01

  The present invention provides a stable working fluid for use in a viscous coupling which is insusceptible to viscosity decreases due to thermal decomposition as well as viscosity increases or gelation, which comprises a specific polyorganosiloxane as a base oil having one or more selected from the group consisting of sulfonate, phenate and salicylate incorporated therein, and which may further comprises sulfur, phosphorus and chlorine compounds incorporated therein.

  本发明提供了一种用于粘性偶联剂的稳定工作液，它不易受热分解导致的粘度下降以及粘度增加或凝胶化的影响，它由特定的聚有机硅氧烷作为基础油，其中掺入了一种或多种从磺酸盐、苯酸盐和水杨酸盐组成的组中选出的物质，还可进一步掺入硫、磷和氯化合物。
• Metal free hydraulic fluid with amine salt
  申请人：THE LUBRIZOL CORPORATION

  公开号：EP0667389A2

  公开（公告）日：1995-08-16

  Functional fluids comprising an oil of lubricating viscosity, the reaction product of an amine and a sulfonic acid, and at least one sulfur-containing compound of the structure         (RX)3P=X where X is sulfur or oxygen exhibit good anti-rust and antiwear performance.

  功能性流体，包括具有润滑粘度的油、胺和磺酸的反应产物以及至少一种结构的含硫化合物 (RX)3P=X 其中 X 为硫或氧，具有良好的防锈和抗磨损性能。
• Combination of a sulfer compound and specific phosphorus compounds and their use in lubricating compositions, concentrates and greases
  申请人：THE LUBRIZOL CORPORATION

  公开号：EP0695799A2

  公开（公告）日：1996-02-07

  This invention relates to a lubricating composition comprising a major amount of an oil of lubricating viscosity and (a) a extreme pressure improving amount of at least one sulfur compound, and an antiwear or an extreme pressure improving amount of the combination of (b) at least one ammonium salt of a phosphoric acid ester, (c) at least one phosphite, and (d) at least one thiophosphate or at least one reaction product of a phosphite and sulfur or a source of sulfur. The invention also relates to concentrates and greases containing the combination of the sulfur compound and the specific phosphorus compounds.

  本发明涉及一种润滑组合物，其中包含主要量的润滑粘度油和(a)至少一种硫化合物的极压改进量，以及(b)至少一种磷酸酯铵盐、(c)至少一种亚磷酸酯和(d)至少一种硫代磷酸盐或至少一种亚磷酸酯与硫或硫源的反应产物的抗磨或极压改进量的组合。本发明还涉及含有硫化合物和特定磷化合物组合的浓缩物和润滑脂。
• Base oil for carbon dioxide refrigerant and refrigerating machine oil composition
  申请人：Nippon Mitsubishi Oil Corporation

  公开号：EP1211302A1

  公开（公告）日：2002-06-05

  A refrigerating machine oil for a carbon dioxide refrigerant according to the present invention contains polyalkylene glycol represented by the following general formula (1):         R1-(OR3)n-OR2}m     (1) [where R1 represents a residue obtained by removing m hydroxyl groups from an organic compound having three to ten hydroxyl groups, R2 hydrogen, an alkylene group of one to five carbons, or an acyl group of one to five carbons, R3 an alkylene group of two to four carbons, m an integer of 3 to 10, and n such an integer that a number average molecular weight of the polyalkylene glycol (1) becomes 500 to 3000],    wherein a kinematic viscosity at 100°C of the polyalkylene glycol is 5-20 mm2/s.

  根据本发明，一种用于二氧化碳制冷剂的冷冻机油含有由以下通式（1）表示的聚亚烷基二醇： R1-(OR3)n-OR2}m (1) [其中 R1 代表从具有三至十个羟基的有机化合物中除去 m 个羟基而得到的残余物，R2 代表氢、一至五个碳原子的亚烷基或一至五个碳原子的酰基，R3 代表二至四个碳原子的亚烷基，m 代表 3 至 10 的整数，n 代表使聚亚烷基二醇（1）的平均分子量变为 500 至 3000 的整数]、 其中聚亚烷基二醇在 100°C 时的运动粘度为 5-20 mm2/s。