N-[4-(叔丁基氨基)-6-氯-1,3,5-三嗪-2-基]乙酰胺 | 153233-52-4

• 分子结构分类: 有机化合物 - 有机氮化合物
• 中文名称: N-[4-(叔丁基氨基)-6-氯-1,3,5-三嗪-2-基]乙酰胺
• 英文名称: 2-chloro-4-acetamido-6-tert-butylamino-1,3,5-triazine
• 英文别名: 2-Chloro-4-tert-butylamino-6-acetamido-s-triazine；N-(4-(tert-Butylamino)-6-chloro-1,3,5-triazin-2-yl)acetamide；N-[4-(tert-butylamino)-6-chloro-1,3,5-triazin-2-yl]acetamide
• CAS: 153233-52-4
• 化学式: C₉H₁₄ClN₅O
• 分子量: 243.696
• InChiKey: DYRSLXURNMQEOR-UHFFFAOYSA-N

物化性质

• 密度：
  1.330±0.06 g/cm3(Predicted)
• 保留指数：
  1898

计算性质

• 辛醇/水分配系数(LogP)：
  1.7
• 重原子数：
  16
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.56
• 拓扑面积：
  79.8
• 氢给体数：
  2
• 氢受体数：
  5

上下游信息

• 上游原料

  中文名称	英文名称	CAS号	化学式	分子量
  特丁津	terbuthylazine	5915-41-3	C9H16ClN5	229.713

反应信息

• 作为产物：
  描述：

  特丁津 在 双氧水 作用下， 以 水 为溶剂， 生成 2-氯-4,6-二氨基-1,3,5-三嗪 、 去乙基特丁津 、 N-[4-(叔丁基氨基)-6-氯-1,3,5-三嗪-2-基]乙酰胺 、 氟氯氢菊脂(去异丙基莠去津)
  参考文献：
  名称：

  Photosensitized degradation of terbuthylazine in water

  摘要：

  We investigated the photodegradation of terbuthylazine, an s-triazine herbicide, in the presence of hydrogen peroxide (H2O2), titanium dioxide (TiO2), acetone or humic substances. In the presence of H2O2 and UV light, the degradation of terbuthylazine quickly leads td the formation of ammeline. The degradation pathway consists of dealkylation reactions giving 2-chloro-4,6-diamino-1,3,5-triazine, and then ammeline through hydroxylation. Irradiation of terbuthylazine with simulated solar light in the presence of titanium dioxide gives also dealkylation products in the first stage of degradation; Acetone at 1% (v/v) produces a 7-fold enhancement of the degradation rate. In the presence of humic substances, different results were obtained, depending on the origin of the substances tested. The humic acids isolated from a soil accelerate the degradation speed, whereas the fulvic acids from a small stream reduce it. Copyright (C) 1996 Elsevier Science Ltd

  DOI：

  10.1016/0045-6535(96)00176-2

文献信息

• Photosensitized degradation of terbuthylazine in water
  作者：Y. Sanlaville、S. Guittonneau、M. Mansour、E.A. Feicht、P. Meallier、A. Kettrup

  DOI：10.1016/0045-6535(96)00176-2

  日期：1996.7

  We investigated the photodegradation of terbuthylazine, an s-triazine herbicide, in the presence of hydrogen peroxide (H2O2), titanium dioxide (TiO2), acetone or humic substances. In the presence of H2O2 and UV light, the degradation of terbuthylazine quickly leads td the formation of ammeline. The degradation pathway consists of dealkylation reactions giving 2-chloro-4,6-diamino-1,3,5-triazine, and then ammeline through hydroxylation. Irradiation of terbuthylazine with simulated solar light in the presence of titanium dioxide gives also dealkylation products in the first stage of degradation; Acetone at 1% (v/v) produces a 7-fold enhancement of the degradation rate. In the presence of humic substances, different results were obtained, depending on the origin of the substances tested. The humic acids isolated from a soil accelerate the degradation speed, whereas the fulvic acids from a small stream reduce it. Copyright (C) 1996 Elsevier Science Ltd