1,4-bis(dimethoxymethylsilyl)benzene | 135778-06-2

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: 1,4-bis(dimethoxymethylsilyl)benzene
• 英文别名: 1,4-Bis(methyldimethoxysilyl)benzene；[4-[dimethoxy(methyl)silyl]phenyl]-dimethoxy-methylsilane
• CAS: 135778-06-2
• 化学式: C₁₂H₂₂O₄Si₂
• 分子量: 286.475
• InChiKey: AYHMBXGPNZPJIS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.83
• 重原子数：
  18
• 可旋转键数：
  6
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  36.9
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  1,4-bis(dimethoxymethylsilyl)benzene 在 氢氟酸 作用下， 以 水 为溶剂， 以10.1 g的产率得到1,4-bis[difluoro(methyl)silyl]benzene
  参考文献：
  名称：

  Highly Unsaturated Macrocyclic Silahydrocarbons Containing Exocyclic Phenyl Groups

  摘要：

  A series of 12- and 18-membered macrocycloethynes and macrocyclosilethenesilethynes, containing peripheral methyl and phenyl groups was prepared by organomagnesium sysnthesis under conditions of high dilution. One of these compounds contains an endocyclic 1,4-phenylene bridge.

  DOI：

  10.1023/b:rugc.0000016020.37433.f6
• 作为产物：
  描述：

  甲基三甲氧基硅烷 、 1,4-二溴苯 在 magnesium 作用下， 以 四氢呋喃 为溶剂， 反应 24.0h， 以25%的产率得到1,4-bis(dimethoxymethylsilyl)benzene
  参考文献：
  名称：

  Rigid rod molecules containing two Si(OMe)3 or SiMe(OMe)2 groups for hybrid materials synthesis

  摘要：

  The synthesis of new bis(trimethoxysilyl) and bis(dimethoxymethylsilyl)arene compounds containing rigid organic groups such as stilbenyl, diphenylacetylene or diphenylbut-1,3-diyne is reported. The Heck type reaction constituted a convenient route to these compounds. since this coupling reaction appeared compatible with the presence of Si(OR)(3) groups. (C) 2001 Elsevier Science B.V. All nights reserved.

  DOI：

  10.1016/s0022-328x(01)00668-4

文献信息

• Rigid rod molecules containing two Si(OMe)3 or SiMe(OMe)2 groups for hybrid materials synthesis
  作者：Geneviève Cerveau、Sabrina Chappellet、Robert J.P. Corriu*、Bertrand Dabiens

  DOI：10.1016/s0022-328x(01)00668-4

  日期：2001.4

  The synthesis of new bis(trimethoxysilyl) and bis(dimethoxymethylsilyl)arene compounds containing rigid organic groups such as stilbenyl, diphenylacetylene or diphenylbut-1,3-diyne is reported. The Heck type reaction constituted a convenient route to these compounds. since this coupling reaction appeared compatible with the presence of Si(OR)(3) groups. (C) 2001 Elsevier Science B.V. All nights reserved.
• Self-organization of a rigid α,ω-bis-silanediol determined by X-ray crystal structure
  作者：Francis Carré、Geneviève Cerveau、Robert J.P. Corriu、Bertrand Dabiens

  DOI：10.1016/s0022-328x(00)00841-x

  日期：2001.4

  The X-ray crystal structure of the 1,4-bis(dihydroxymethylsilyl)benzene exhibits an unusual crystal packing with a hydrogen bonded network locking the orientation of the molecules to an approximate head-to-tail arrangement. (C) 2001 Elsevier Science B.V. All rights reserved.
• Highly Unsaturated Macrocyclic Silahydrocarbons Containing Exocyclic Phenyl Groups
  作者：O. G. Yarosh、L. V. Zhilitskaya、N. K. Yarosh、A. I. Albanov、M. G. Voronkov

  DOI：10.1023/b:rugc.0000016020.37433.f6

  日期：2003.10

  A series of 12- and 18-membered macrocycloethynes and macrocyclosilethenesilethynes, containing peripheral methyl and phenyl groups was prepared by organomagnesium sysnthesis under conditions of high dilution. One of these compounds contains an endocyclic 1,4-phenylene bridge.