tert-butyl-trimethyl-ammonium; hydroxide | 118834-98-3

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: tert-butyl-trimethyl-ammonium; hydroxide
• 英文别名: tert-Butyl-trimethyl-ammonium; Hydroxid；Tert-butyl(trimethyl)azanium;hydroxide
• CAS: 118834-98-3
• 化学式: C₇H₁₈N*HO
• 分子量: 133.234
• InChiKey: UTMMDQSMXNGLSW-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  1.31
• 重原子数：
  9
• 可旋转键数：
  1
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  1
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  tert-butyl-trimethyl-ammonium; hydroxide 生成 甲醇 、 三甲胺
  参考文献：
  名称：

  Hanhart; Ingold, Journal of the Chemical Society, 1927, p. 1014

  摘要：

  DOI：

文献信息

• Silicone coating compositions and coated articles
  申请人：Shin-Etsu Chemical Co., Ltd.

  公开号：EP1591503A1

  公开（公告）日：2005-11-02

  A silicone coating composition comprising (A) a silicone resin resulting from (co)hydrolytic condensation of an alkoxysilane or a partial hydrolytic condensate thereof, (B) an aromatic-free compound for curing the silicone resin, and (C) a solvent remains stable during shelf storage. It is applied and heat cured to a plastic substrate to form a protective coat having a high hardness, mar resistance, adhesion toughness and crack resistance.

  一种硅树脂涂料组合物，包括：(A) 由烷氧基硅烷或其部分水解缩合物（共）水解缩合而成的硅树脂；(B) 用于固化硅树脂的不含芳烃的化合物；(C) 在货架储存期间保持稳定的溶剂。将其涂在塑料基材上并加热固化，可形成一层具有高硬度、抗磨损性、附着韧性和抗裂性的保护层。
• Abrasion-resistant coating composition and coated article
  申请人：Shin-Etsu Chemical Co., Ltd.

  公开号：EP1997853A1

  公开（公告）日：2008-12-03

  A coating composition that is capable of forming a coating film that combines abrasion resistance and crack resistance. The composition comprises: (A) a silicone resin obtained by hydrolysis and condensation of an alkoxysilane that includes an alkoxysilane represented by a general formula (1):          (R1)mSi(OR2)4-m     (1) (wherein, R1 represents a hydrogen atom, or a substituted or unsubstituted monovalent hydrocarbon group, R2 represents an alkyl group of 1 to 3 carbon atoms, and m represents either 0 or 1), (B) hydrophobic silica microparticles, (C) a curing catalyst, and (D) a solvent.

  一种涂料组合物，能够形成兼具耐磨性和抗裂性的涂膜。该组合物包括：(A) 通过水解和缩合烷氧基硅烷获得的硅树脂，烷氧基硅烷包括通式 (1) 所代表的烷氧基硅烷： (R1)mSi(OR2)4-m (1) (其中，R1 代表氢原子或取代或未取代的一价烃基，R2 代表 1 至 3 个碳原子的烷基，m 代表 0 或 1），(B) 疏水性二氧化硅微粒，(C) 固化催化剂，以及 (D) 溶剂。
• UV-shielding silicone coating composition and coated article
  申请人：Shin-Etsu Chemical Co., Ltd.

  公开号：EP2226352A2

  公开（公告）日：2010-09-08

  A UV-shielding silicone coating composition comprises (A) a dispersion in a dispersing medium of composite zinc oxide nanoparticles which are obtained by coating zinc oxide nanoparticles with an oxide or hydroxide of Al, Si, Zr or Sn, the dispersion having a photocatalytic degradability of up to 25%, (B) a silicone resin, (C) a curing catalyst, and (D) a solvent, the solids content of composite zinc oxide nanoparticle dispersion (A) being 1 to 50% by weight based on silicone resin (B). The composition is transparent to visible light, mar resistant, UV-shielding, weatherable, and durable.

  一种紫外线屏蔽硅树脂涂料组合物包括（A）复合氧化锌纳米粒子在分散介质中的分散液，该分散液是通过将氧化锌纳米粒子与 Al、Si、Zr 或 Sn 的氧化物或氢氧化物涂覆在一起而得到的，该分散液的光催化降解性高达 25%；（B）硅树脂；（C）固化催化剂；以及（D）溶剂，复合氧化锌纳米粒子分散液（A）的固体含量为硅树脂（B）重量的 1%至 50%。该组合物对可见光透明、耐污、防紫外线、耐候和耐用。
• UV-shielding coating composition and coated article
  申请人：Shin-Etsu Chemical Co., Ltd.

  公开号：EP2239308A1

  公开（公告）日：2010-10-13

  A UV-shielding coating composition comprises (A) a dispersion in a dispersing medium of composite zinc oxide nanoparticles which are obtained by coating surfaces of zinc oxide nanoparticles with an oxide or hydroxide of Al, Si, Zr and Sn, the dispersion having a photocatalytic degradability of up to 25%, (B) a vinyl copolymer obtained from copolymerization of an alkoxysilyl-containing vinyl monomer, a UV-absorbing vinyl monomer, and another monomer, and (C) a solvent. The composition is transparent to visible light, UV-shielding, mar resistant, weatherable, and durable.

  一种紫外线屏蔽涂料组合物包括：(A)复合氧化锌纳米粒子在分散介质中的分散体，该分散体是通过在氧化锌纳米粒子表面涂覆 Al、Si、Zr 和 Sn 的氧化物或氢氧化物而得到的，该分散体的光催化降解性高达 25%；(B)乙烯基共聚物，该共聚物是由含烷氧基硅基的乙烯基单体、紫外线吸收乙烯基单体和另一种单体共聚而成；以及(C)溶剂。该组合物对可见光透明，具有紫外线屏蔽、防污、耐候性和耐久性。
• Abrasion resistant silicone coating composition, coated article, and making method
  申请人：Shin-Etsu Chemical Co., Ltd.

  公开号：EP2281857A1

  公开（公告）日：2011-02-09

  A silicone coating composition is provided comprising (A) a hydrolytic condensate obtained by (co)hydrolytic condensation of an alkoxysilane, (B) colloidal silica, (C) a urethane-modified vinyl polymer, (D) a curing catalyst, and (E) a solvent, the solid content of component (C) being 1 to 30% by weight based on the total solid content of components (A) and (B). The silicone coating composition can be coated and cured to an organic resin substrate without a need for primer, and the cured coating is abrasion resistant and transparent to visible light.

  本发明提供了一种有机硅涂料组合物，包括（A）由烷氧基硅烷（共）水解缩合得到的水解缩合物；（B）胶体二氧化硅；（C）聚氨酯改性乙烯基聚合物；（D）固化催化剂；以及（E）溶剂，其中组分（C）的固体含量为组分（A）和（B）总固体含量的 1%至 30%（重量百分比）。有机硅涂料组合物无需底漆即可涂覆和固化到有机树脂基材上，固化后的涂层耐磨且对可见光透明。