N-丁基-对-氨基二苯胺 | 15464-99-0

• 分子结构分类: 有机化合物 - 有机氮化合物
• 中文名称: N-丁基-对-氨基二苯胺
• 英文名称: N-phenyl-N'-n-butyl-p-phenylenediamine
• 英文别名: N-phenyl-N'-butyl-p-phenylenediamine；N-butyl-N'-phenyl-p-phenylenediamine；N-n-butyl-N'-phenyl-p-phenylenediamine；p-Phenylenediamine (8CI), N-butyl-N'-phenyl-；1-N-butyl-4-N-phenylbenzene-1,4-diamine
• CAS: 15464-99-0
• 化学式: C₁₆H₂₀N₂
• 分子量: 240.348
• InChiKey: PIPXINMICYUFAD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.7
• 重原子数：
  18
• 可旋转键数：
  6
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  24.1
• 氢给体数：
  2
• 氢受体数：
  2

文献信息

• Direct alkylation of N-alkyl-N'-phenyl-p-phenylenediamine
  申请人：Wang Jin-Yun

  公开号：US20070173668A1

  公开（公告）日：2007-07-26

  A single-step process is disclosed for the ring alkylation of at least one N-alkyl-N′-phenyl-phenylenediamine with at least one olefin wherein the process comprises heating a mixture of the N-alkyl-N′-phenyl-phenylenediamine(s) and olefin(s) in the presence of a catalytic amount of at least one alkyl aluminum halide at a temperature of from about 50 to about 350° C. in a sealed vessel for from about one to about 30 hours.

  揭示了一种单步过程，用于将至少一种N-烷基-N'-苯基-苯二胺与至少一种烯烃进行环烷化反应，其中该过程包括在密封容器中，在存在至少一种烷基铝卤化物的催化剂作用下，将N-烷基-N'-苯基-苯二胺(s)和烯烃(s)的混合物加热至约50℃至约350℃的温度，反应时间为约1至约30小时。
• METHOD FOR PRODUCING N-ISOPROPYL(METH)ACRYLAMIDE
  申请人：Knebel Joachim

  公开号：US20110218312A1

  公开（公告）日：2011-09-08

  A novel process is described which allows N-isopropyl(meth)acrylamide to be obtained in high purity and yield in a simple manner, by reacting methacrylic anhydride with isopropylamine, optionally in a solvent.

  本文描述了一种新的工艺，通过将甲基丙烯酸酐与异丙胺反应，可在高纯度和高收率的情况下简单地获得N-异丙基（甲基）丙烯酰胺，可选地在溶剂中进行反应。
• Method and composition for inhibiting acrylate ester polymerization
  申请人：BETZ EUROPE, INC.

  公开号：EP0266906A2

  公开（公告）日：1988-05-11

  Compositions and methods of inhibiting acrylate monomer polymerization at elevated temperatures comprising adding to the acrylate monomer an effective amount for the purpose of (a) hydroxylamine having the formula wherein R and Rʹ are the same or different and are hydrogen, or straight or branched chain alkyl, aryl, alkaryl or aralkyl groups,and (b) a para-phenylenediamine or derivative thereof having at least one N-H group.

  在高温下抑制丙烯酸酯单体聚合的组合物和方法，包括向丙烯酸酯单体中加入有效量的 (a) 羟胺，其式为 其中R和Rʹ相同或不同，并且是氢、或直链或支链烷基、芳基、烷芳基或芳烷基，和 (b) 对苯二胺或其衍生物，至少有一个N-H基团。
• Method and compositions for inhibiting polymerization of acrylic acid monomers
  申请人：BETZ EUROPE, INC.

  公开号：EP0398633A1

  公开（公告）日：1990-11-22

  A method of inhibiting acid monomer (as hereinbefore defined) polymerization comprising adding to the monomer (a) a manganese source compound and (b) a phenylenediamine compound having at least one N-H bond therein. Acrylic acid (as hereinbefore defined) anti-polymerization composition comprising a liquid carrier and dissolved or dispersed therein (a) a manganese source compound and (b) a phenylenediamine compound having at least one N-H bond therein.

  一种抑制酸性单体(如前定义)聚合的方法，包括向单体中加入(a)锰源化合物和(b)其中至少有一个N-H键的苯二胺化合物。 丙烯酸（如前所述）防聚合组合物，包括液体载体和溶解或分散于其中的(a)锰源化合物和(b)至少有一个N-H键的苯二胺化合物。
• Stabilization of gasoline mixtures
  申请人：BETZ EUROPE, INC.

  公开号：EP0534668A1

  公开（公告）日：1993-03-31

  Oxidative stability of gasoline mixtures is improved by adding to the gasoline a phenylenediamine compound (I) in combination with a strongly basic organo-amine compound (II). The compound (II) may comprise hydroxylamines, alkylphenol-polyamine-formaldehyde Mannich reaction products, polyethylene-polyamines, and members of the group of piperazine, aminoalkyl substituted piperazine and amino substituted alicyclic alkanes.

  在汽油中加入苯二胺化合物（I）和强碱性有机胺化合物（II）可提高汽油混合物的氧化稳定性。化合物（II）可包括羟胺、烷基酚-多胺-甲醛曼尼希反应产物、聚乙烯-多胺以及哌嗪、氨基烷基取代的哌嗪和氨基取代的脂环烷烃。