申请人:Lu Ning
公开号:US10131794B2
公开(公告)日:2018-11-20
The present invention provides for a household, agricultural, coating or personal care product composition containing the crosslinked reaction product of a network composition the reaction product of: (i) at least one anionic polymerizable ethylenically unsaturated monomer (I) selected from the group consisting of
[CH2═C(R3)C(O)OXa(C2H4O)b(C3H6O)c(C4H8O)d]pP(O)(OY)q(OZ)r
and
CH2═C(R3)C(O)OXa′(C2H4O)b′(C3H6O)c′(C4H8O)d′—SO3—Y)
where R3=H or alkyl of 1 to about 6 carbon atoms; X=alkyl, aryl, or alkaryl diradical connecting group of 0 to about 9 carbon atoms; a, a′, b, b′, c, c′, d and d′ are 0 to about 100; q is 0 to about 2; r is 0 to about 2; p is 1 to about 3 subject to the limitation that p+q+r=3; and Y and Z is H, or metal ion; and
(ii) one or more additional monomers (II) selected from the group consisting of acrylic acid/acrylate, methacrylic acid/methacrylate, acrylamides, vinyl acetate and styrene, which are copolymerizable with (I); and
(iii) a cross-linking agent (III), capable of copolymerizing with (I) and (II).
本发明提供了一种家用、农用、涂料或个人护理产品组合物,该组合物含有一种网络组合物的交联反应产物,该网络组合物的反应产物为(i) 至少一种阴离子可聚合乙烯基不饱和单体 (I),选自以下组别
[CH2═C(R3)C(O)OXa(C2H4O)b(C3H6O)c(C4H8O)d]pP(O)(OY)q(OZ)r
和
CH2═C(R3)C(O)OXa′(C2H4O)b′(C3H6O)c′(C4H8O)d′-SO3-Y)
其中 R3=H 或 1 至约 6 个碳原子的烷基;X=0 至约 9 个碳原子的烷基、芳基或烷芳基二元连接基团;a、a′、b、b′、c、c′、d 和 d′ 为 0 至约 100;q 为 0 至约 2;r 为 0 至约 2;p 为 1 至约 3,但以 p+q+r=3 为限;Y 和 Z 为 H 或金属离子;以及
(ii) 选自丙烯酸/丙烯酸酯、甲基丙烯酸/甲基丙烯酸酯、丙烯酰胺、乙酸乙烯酯和苯乙烯 组的一种或多种可与(I)共聚的附加单体(II);以及
(iii) 可与(I)和(II)共聚的交联剂(III)。