N-Methyl-N-vinyl-anilin | 7025-99-2

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N-Methyl-N-vinyl-anilin
• 英文别名: N-methyl-N-vinyl-aniline；N-vinylmethylphenylamine；N-ethenyl-N-methylaniline
• CAS: 7025-99-2
• 化学式: C₉H₁₁N
• 分子量: 133.193
• InChiKey: RNFYPKLPQMWIKW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.8
• 重原子数：
  10
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.11
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  N-Methyl-N-vinyl-anilin 、 alkaline earth salt of/the/ methylsulfuric acid 生成 N-甲基苯胺
  参考文献：
  名称：

  v. Braun; Kirschbaum, Chemische Berichte, 1919, vol. 52, p. 2263

  摘要：

  DOI：
• 作为产物：
  描述：

  N-甲基-N-羟乙基苯胺 生成 N-Methyl-N-vinyl-anilin
  参考文献：
  名称：

  Lattes,A.; Riviere,M., Comptes Rendus des Seances de l'Academie des Sciences, Serie C: Sciences Chimiques, 1966, vol. 262, p. 1797 - 1800

  摘要：

  DOI：

文献信息

• PURIFICATION OF ALKENYL COMPOUNDS
  申请人：——

  公开号：US20020038059A1

  公开（公告）日：2002-03-28

  A process for purifying alkenyl compounds having a divalent or trivalent heteroatom in the &agr;-position relative to the double bond by distillation comprises carrying out at least two distillations in which the purified alkenyl compounds are obtained from the gas phase by condensation, where the time between the first distillation after the synthesis of the alkenyl compounds and at least one further distillation is at least one day and the purified alkenyl compounds have an APHA color number of <30.

  一种用蒸馏法纯化α-位于双键旁的含二价或三价杂原子的烯基化合物的方法，包括进行至少两次蒸馏，其中通过冷凝从气相中获得纯化的烯基化合物，第一次蒸馏后至少一次进一步蒸馏的时间至少为一天，纯化的烯基化合物的APHA色数小于30。
• Adsorbent and Analysis Method Using Same
  申请人：HITACHI HIGH-TECHNOLOGIES CORPORATION

  公开号：US20160109417A1

  公开（公告）日：2016-04-21

  An adsorbent which enables solid phase extraction of water-soluble molecules with high efficiency and excellent selectivity and an analysis system using the adsorbent, the adsorbent containing a structure represented by the formula I wherein R is a carrier component, the moiety other than R is a side-chain functional group, R and the benzene ring in the side-chain functional group are bonded directly or bonded through one or more atoms, R′ is selected from the group consisting of hydroxy group, alkoxy group, amino group, alkylamino group, thiol group and alkyl sulfide group, R″ is independently selected from the group consisting of hydroxy group, alkoxy group, alkyl group, amino group, alkylamino group, dialkylamino group, trialkylamino group, thiol group, alkyl sulfide group and hydrogen atom, x is an integer of zero or more and three or less, and n is the number of the side-chain functional groups contained in the carrier component.

  一种吸附剂，能够高效、选择性地固相萃取水溶性分子，并使用该吸附剂的分析系统，该吸附剂包含由式I表示的结构，其中R是载体组分，除R外的部分是侧链功能基，R和侧链功能基中的苯环直接键合或通过一个或多个原子键合，R′选自羟基、烷氧基、氨基、烷基氨基、硫醇基和烷基硫醚基的群组，R″独立地选自羟基、烷氧基、烷基、氨基、烷基氨基、二烷基氨基、三烷基氨基、硫醇基、烷基硫醚基和氢原子的群组，x为零或更多且不超过三的整数，n为载体组分中含有的侧链功能基数。
• Synthesis of 2‐Methylindoles through Ruthenium(II)‐Catalyzed Reaction of Aniline Derivatives with Allylamines
  作者：Xue‐Yi He、Zhong‐Xia Wang

  DOI：10.1002/adsc.202201181

  日期：2023.2.7

  The ruthenium(II)-catalyzed reaction of aniline derivatives with allylamines was carried out, affording 2-methylindoles via C−H/C−N bond activation. 4,5-Dimethyl pyrimidin-2-yl group attached on the nitrogen atom of anilines is the most effective directing group and N-allyl-4-fluoro-N-methylaniline is the optimal allylamine. The cyclization products were obtained in 16% to 96% yields. The method does

  进行了钌 (II) 催化的苯胺衍生物与烯丙胺的反应，通过 C-H/C-N 键活化提供 2-甲基吲哚。连接在苯胺氮原子上的 4,5-二甲基嘧啶-2-基是最有效的导向基团，N-烯丙基-4-氟-N-甲基苯胺是最佳的烯丙胺。环化产物的收率为 16% 至 96%。该方法不需要外部氧化剂。提出了一种可能的机制。
• Anti-fouling agent
  申请人：Nitto Kasei Co., Ltd.

  公开号：EP0091039A2

  公开（公告）日：1983-10-12

  An antifouling agent comprising as an antifouling component a substantially linear triorganotin-containing copolymer containing (a) at least one kind of N-coordinated triorganotin-containing recurring units of the formula (la) or (Ib) represented in the specification and (b) comonomer recurring units derived from at least one ethylenic vinyl compound as a comonomer. The antifouling agent is applied to a structure which is needed to be protected from fouling organisms to form a film of the copolymer on the structure.

  一种防污剂，其防污成分包括基本上线性的含三聚有机锡共聚物，该共聚物含有(a)至少一种如说明书中所示的式(la)或(Ib)的N-配位三聚有机锡循环单元和(b)作为共聚单体的至少一种乙烯基乙烯基化合物衍生的共聚单体循环单元。 将防污剂涂在需要防止污损生物的结构上，在该结构上形成一层共聚物薄膜。
• Verfahren zur Stabilisierung und/oder Senkung der Farbzahl von Alkenylverbindungen
  申请人：BASF AKTIENGESELLSCHAFT

  公开号：EP1223161A2

  公开（公告）日：2002-07-17

  Verfahren zur Stabilisierung und/oder Senkung der Farbzahl von Alkenylverbindungen mit einem zwei- oder dreibindigen Heteroatom in α-Stellung zur Doppelbindung, bei dem man die Alkenylverbindungen mit einem Oxidationsmittel versetzt.

  稳定和/或降低二价或三价杂原子位于双键 α 位的烯基化合物色数的工艺，其中在烯基化合物中加入氧化剂。