sulfinic acid

• 分子结构分类: 无机化合物 - 均质非金属化合物 - 其他非金属有机物
• 英文名称: sulfinic acid
• 英文别名: Hydroxy(oxo)-lambda4-sulfane；hydroxy(oxo)-λ4-sulfane
• 化学式: H₂O₂S
• 分子量: 66.0807
• InChiKey: BUUPQKDIAURBJP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.5
• 重原子数：
  3
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  38.3
• 氢给体数：
  2
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  硫化氢 、 二氧化硫 以 solid matrix 为溶剂， 生成 sulfinic acid
  参考文献：
  名称：

  固体氩中亚硫酸（HSO2H）的红外光谱

  摘要：

  Mercury-xenon arc lamp photolysis of argon matrix samples at 12 K containing hydrogen sulfide and sulfur dioxide produced eight new infrared absorptions at 2591, 1209, 1093, 762, 476, 450, 340, and 270 cm-1. Extensive deuterium and oxygen-18 isotopic substitution studies, and normal-coordinate calculations on all isotopomers, allow the assignment of these absorptions to eight vibrational modes of sulfinic acid. The HSO2H molecule is formed by in situ hydrogen atom addition to matrix-isolated sulfur dioxide molecules. This is the first infrared spectroscopic observation of this reactive molecule.

  DOI：

  10.1021/j100160a033

文献信息

• Infrared spectrum of sulfinic acid (HSO2H) in solid argon
  作者：Matthew A. Fender、Yasmin M. Sayed、Frank T. Prochaska

  DOI：10.1021/j100160a033

  日期：1991.4

  Mercury-xenon arc lamp photolysis of argon matrix samples at 12 K containing hydrogen sulfide and sulfur dioxide produced eight new infrared absorptions at 2591, 1209, 1093, 762, 476, 450, 340, and 270 cm-1. Extensive deuterium and oxygen-18 isotopic substitution studies, and normal-coordinate calculations on all isotopomers, allow the assignment of these absorptions to eight vibrational modes of sulfinic acid. The HSO2H molecule is formed by in situ hydrogen atom addition to matrix-isolated sulfur dioxide molecules. This is the first infrared spectroscopic observation of this reactive molecule.