Dicyclohexyl-oxiranylmethyl-amine | 27110-25-4

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: Dicyclohexyl-oxiranylmethyl-amine
• 英文别名: N-cyclohexyl-N-(oxiran-2-ylmethyl)cyclohexanamine
• CAS: 27110-25-4
• 化学式: C₁₅H₂₇NO
• mdl: MFCD11126998
• 分子量: 237.385
• InChiKey: RNNCMOKRBXICBN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.6
• 重原子数：
  17
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  15.8
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  Dicyclohexyl-oxiranylmethyl-amine 以 乙醚 为溶剂， 反应 16.0h， 生成
  参考文献：
  名称：

  Synthèse de 3-[2F-alkyléthylamino]-1,2-époxypropanes et obtention de nouveaux tensioactifs mono ou bicaténaires à tête β-hydroxylée

  摘要：

  In this paper we report the synthesis of new intermediates of the type 3-[2-F-alkyl-ethylamino]-1,2-epoxypropanes which lead simply and with good yields to a large range of fluorinated monotailed, bitailed and hydrogenated/fluorinated bitailed surfactants having a secondary amino group and at least one hydroxy group. Evaluation of their surface properties has allowed the contribution of each hydrophobic tail contained in the hydrogenated and fluorinated bitailed molecules to be demonstrated.

  DOI：

  10.1016/s0022-1139(00)81248-8

文献信息

• [EN] AMPHIPHILIC BLOCK COPOLYMER<br/>[FR] COPOLYMÈRE SÉQUENCÉ AMPHIPHILE
  申请人：BYK CHEMIE GMBH

  公开号：WO2021175972A1

  公开（公告）日：2021-09-10

  The invention relates to block copolymer comprising i) A first block wherein at least 65 mol-% of the repeating units of the first block are repeating units of the formula (I) -[CH2-CH2-O]-, ii) A second block wherein at least 90 mol-% of the repeating units of the second block are repeating units of at least one of formulae (II) or (III), wherein the groups R1, R2, and R3 independent of each occurrence are selected from hydrocarbyl groups having 1 to 40 carbon atoms, which are optionally substituted by ether or hydroxyl groups, and wherein the groups R1 and R2 are optionally linked to each other such that a nitrogen heterocyclic structure is present, iii) A third block which is different from the first block and the second block and which is more hydrophobic than the first block.
• Synthèse de 3-[2F-alkyléthylamino]-1,2-époxypropanes et obtention de nouveaux tensioactifs mono ou bicaténaires à tête β-hydroxylée
  作者：P.S. Abenin、F. Szönyi、A. Cambon

  DOI：10.1016/s0022-1139(00)81248-8

  日期：1991.11

  In this paper we report the synthesis of new intermediates of the type 3-[2-F-alkyl-ethylamino]-1,2-epoxypropanes which lead simply and with good yields to a large range of fluorinated monotailed, bitailed and hydrogenated/fluorinated bitailed surfactants having a secondary amino group and at least one hydroxy group. Evaluation of their surface properties has allowed the contribution of each hydrophobic tail contained in the hydrogenated and fluorinated bitailed molecules to be demonstrated.