N-异丙基十六胺 | 90207-24-2

• 分子结构分类: 有机化合物 - 有机氮化合物
• 中文名称: N-异丙基十六胺
• 英文名称: N-(propan-2-yl)hexadecan-1-amine
• 英文别名: N-propan-2-ylhexadecan-1-amine
• CAS: 90207-24-2
• 化学式: C₁₉H₄₁N
• 分子量: 283.541
• InChiKey: KRVYVVWZAYMURR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.3
• 重原子数：
  20
• 可旋转键数：
  16
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  12
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  十六胺 、 异丙醇 在 氢气 作用下， 100.0 ℃ 、1.72 MPa 条件下， 反应 72.0h， 以100%的产率得到N-异丙基十六胺
  参考文献：
  名称：

  Alkylation of amines with alcohols catalyzed by palladium nanoparticles

  摘要：

  Palladium nanoparticles (PdNPs) generated in situ from the complex [(dippe)PdMe2] were used as efficient catalyst for the alkylation of amines by aliphatic alcohols using neat conditions, under hydrogen atmosphere. On using short chain alcohols, the reaction resulted in the generation of dialkylated and tri-alkylated amines in high yields (>80%). The use of bulky alcohols allowed the production of mono-alkylated products, also in high yield. (C) 2012 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2012.03.041

文献信息

• Rubber composition containing silica or silicate and salt of an amine
  申请人：BRIDGESTONE CORPORATION

  公开号：EP1081187A2

  公开（公告）日：2001-03-07

  A rubber composition which comprises (A) at least one rubber component selected from the group consisting of natural rubber and diene synthetic rubbers, (B) an inorganic filler comprising at least one filler selected from silica and silicates as the main component and (C) an addition salt of an amine represented by general formula (I): wherein R1 represents a C8 to C24 alkyl group, an aryl group or an aralkyl group, R2 and R3 represent a hydrogen atom, a C1 to C12 alkyl group, an aryl group, an aralkyl group or a hydroxyalkyl group and R4 represents a C6 to C24 alkyl or alkenyl group, an aryl group or an aralkyl group; and a pneumatic tire produced by using the rubber composition. Fuel consumption of a pneumatic tire is decreased and workability and productivity in vulcanization in the production of a pneumatic tire are improved by using the rubber composition.

  一种橡胶组合物，包括(A)至少一种选自天然橡胶和二烯合成橡胶的橡胶组分，(B)至少一种选自二氧化硅和硅酸盐的无机填料作为主要组分，以及(C)通式(I)代表的胺的加成盐： 其中 R1 代表 C8 至 C24 烷基、芳基或芳烷基，R2 和 R3 代表氢原子、C1 至 C12 烷基、芳基、芳烷基或羟烷基，R4 代表 C6 至 C24 烷基或烯基、芳基或芳烷基；以及使用该橡胶组合物生产的充气轮胎。 使用该橡胶组合物可降低充气轮胎的燃料消耗，提高生产充气轮胎时硫化的作业性和生产率。
• RUBBER COMPOSITION AND PNEUMATIC TIRE
  申请人：BRIDGESTONE CORPORATION

  公开号：EP1083199A1

  公开（公告）日：2001-03-14

  There are provided a rubber composition having a high modulus of elasticity and a good workability, and a pneumatic tire. A rubber composition comprising at least one of natural rubber and synthetic diene rubbers as a rubber ingredient, at least one maleimide compound, and at least one nitrogen-containing compound selected from the group consisting of polyaniline, hydrazide, and amine compound is used in a tread.

  提供了一种具有高弹性模量和良好加工性能的橡胶组合物以及一种充气轮胎。 一种橡胶组合物包含天然橡胶和合成二烯橡胶中的至少一种橡胶成分、至少一种马来酰亚胺化合物和至少一种从聚苯胺、酰肼和胺化合物组成的组中选出的含氮化合物，用于胎面。
• Polymaleimide-containing rubber composition and tire
  申请人：BRIDGESTONE CORPORATION

  公开号：EP1199331A1

  公开（公告）日：2002-04-24

  A rubber composition comprises at least one rubber ingredient selected from natural rubber and synthetic rubbers, and a polymaleimide synthesized by reacting at least one of anhydrous maleic acid and anhydrous citraconic acid with methylene polyaniline.

  一种橡胶组合物包含至少一种橡胶成分，选自天然橡胶和合成橡胶，以及一种聚马来酰亚胺，由无水马来酸和无水柠檬酸中的至少一种与亚甲基聚苯胺反应合成。
• US6355710B1
  申请人：——

  公开号：US6355710B1

  公开（公告）日：2002-03-12
• US6506849B1
  申请人：——

  公开号：US6506849B1

  公开（公告）日：2003-01-14