1,2-Naphthochinon-oxim-(2)-sulfonat-(4) | 105165-41-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 1,2-Naphthochinon-oxim-(2)-sulfonat-(4)
• CAS: 105165-41-1
• 化学式: C₁₀H₆NNaO₅S
• 分子量: 275.217
• InChiKey: JSULVGQDNOAOTA-UHFFFAOYSA-M

反应信息

• 作为反应物：
  描述：

  zinc(II) nitrate 、 sodium amminepentacyanoferrate(II) trihydrate 、 1,2-Naphthochinon-oxim-(2)-sulfonat-(4) 以 乙醇 、 水 为溶剂， 生成
  参考文献：
  名称：

  Reactions of the aquapentacyanoferrate(II) ion with 2-nitroso-1-naphthol and 2-nitroso-1-naphthol-4-sulphonic acid

  摘要：

  The aqua ligand of the aquapentacyanoferrate(II) ion was replaced by 2-nitroso-1-naphthol and its sulphonate derivative giving the analogous mononuclear nitrosonaphtholpentacyanoferrate(II) complex in the first stage of the reaction. In the second stage, a cyano-bridged binuclear product was obtained and characterized as pentacyanoferrate(II)-mu-cyano-tricyanonitrosonaphtholferrate(II). The latter reaction was catalysed by mercury(II) ions. The complexes were characterized on the basis of analytical, IR and W-vis spectral data and have in the solid state and in solution a predominately quinone oximic structure. The preparation of the tris(2-nitroso-1-naphthol) ferrate(II) complex is also reported.

  DOI：

  10.1016/0277-5387(94)00280-r