1,3-dibutyl-2,3-dihydro-1H-imidazo[4,5-f][1,10]-phenanthroline-2-yl iodide | 1397690-63-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 菲咯啉
• 英文名称: 1,3-dibutyl-2,3-dihydro-1H-imidazo[4,5-f][1,10]-phenanthroline-2-yl iodide
• CAS: 1397690-63-9
• 化学式: C₂₁H₂₅N₄*I
• 分子量: 460.361
• InChiKey: TURWOONNEFKHBD-UHFFFAOYSA-M

反应信息

• 作为反应物：
  描述：

  六氟磷酸钾 、 cis-dichlorobis(1,10-phenanthroline)ruthenium(II) dihydrate 、 1,3-dibutyl-2,3-dihydro-1H-imidazo[4,5-f][1,10]-phenanthroline-2-yl iodide 以 甲醇 、 水 为溶剂， 以63%的产率得到[Ru(1,10-phenanthroline)2(1,3-dibutyl-2,3-dihydro-1H-imidazo[4,5-f][1,10]-phenanthroline-2-yl)][PF6]3
  参考文献：
  名称：

  Ru(II)–M(I) (M = Rh and Ir) bimetallic complexes based on a bridging ligand composed of 1,10-phenanthroline and N-heterocyclic carbene: Coordination chemistry and detection property of carbon monoxide

  摘要：

  A series of mono-Ru-II and di-nuclear complexes, [Ru-II-M-I(COD)Cl and Ru-II-M-I(CO)(2)Cl] (M = Ir, Rh), have been prepared by using a bridging ligand, 1,3-dibutyl-2,3-dihydro-1H-imidazo[4,5-f][1,10] phenanthroline-2-yl (IL). This bridging ligand consists of 1,10-phenanthroline and N-heterocyclic carbene (NHC) and has two coordinating sites which can bind two different metals. The complexes synthesized have been fully characterized by H-1 NMR, C-13 NMR, high resolution mass spectrometry (HRMS), elemental analysis, and X-ray crystallography in one case. These complexes exhibited typical pi-pi* and metal-to-ligand charge transfer (MLCT) bands in the UV and visible regions, respectively. Compounds Ru-II-Ir-I (CO)(2)Cl and Ru-II-Rh-I(CO)(2)Cl have the stronger emission intensities and the longer luminescence lifetimes (tau) than those of RuII-IrI(COD) Cl and Ru-II-Rh-I(COD)Cl, respectively. Complex Ru-II-Ir-I(COD)Cl was applied to detect carbon monoxide. (C) 2012 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2012.04.038