N'-(3-methylbenzyl)-N-TsDPEN | 1256080-59-7

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二苯乙烯类
• 英文名称: N'-(3-methylbenzyl)-N-TsDPEN
• CAS: 1256080-59-7
• 化学式: C₂₉H₃₀N₂O₂S
• 分子量: 470.635
• InChiKey: GKFWSZOEIRFAQG-FQLXRVMXSA-N

反应信息

• 作为产物：
  描述：

  在 sodium cyanoborohydride 作用下， 以 甲醇 为溶剂， 生成 N'-(3-methylbenzyl)-N-TsDPEN
  参考文献：
  名称：

  Applications of N′-alkylated derivatives of TsDPEN in the asymmetric transfer hydrogenation of CO and CN bonds

  摘要：

  Arene/Ru(II) complexes of (R,R)-N-alkyl-TsDPEN ligands are effective in the asymmetric transfer hydrogenation of ketones and imines in formic acid/triethylamine solution. The complex derived from the N'-Bn derivative of TsDPEN reduces monocyclic imines in up to 60% ee, whilst the N'-Me derivative of TsDPEN forms a more active catalyst than the non-alkylated analogue and reduces ketones in up to 97% ee. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetasy.2010.07.013