| 478800-82-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• CAS: 478800-82-7
• 化学式: C₄₂H₂₈N₂NiO₂
• 分子量: 651.387
• InChiKey: LHLJIFRQQSOJFK-VMERTWADSA-L

反应信息

• 作为产物：
  描述：

  N-<(3-hydroxy-2-naphthyl)methylene>-1-naphthylamine 、 nickel dichloride 以 乙醇 为溶剂， 生成
  参考文献：
  名称：

  摘要：

  Seven new cobalt(II) and nickel(II) complexes with Schiff's bases were synthesized. The Schiff's bases were prepared by the condensation of 1-aminonaphthalene with carbinols, alpha-hydroxy-alpha-phenylacetophenone (L-1), salicylaldehyde (L-2), and 2-hydroxy-1-naphthaldehyde (L-3), and of 2-aminonaphthalenesulfonic-5 acid with 2-hydroxy-1-naphthaldehyde (L-4). The compounds were studied by X-ray powder diffraction, thermogravimetry, measurements of magnetic susceptibility, and spectroscopy (IR and diffuse reflectance). The coordination sites of the ligand and their dentate members were determined. A coordination number of four was realized in the Ni(II) and Co(II) complexes with L-1-L-3, and the complexes with L-4 were characterized by a coordination number of six (a dimer with an octahedral environment of each central ion).

  DOI：

  10.1023/a:1020043116983