[Mn(((C10H6)(O)CHN)2CH2CHMe)(water)]ClO4 | 1342898-18-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: [Mn(((C10H6)(O)CHN)2CH2CHMe)(water)]ClO4
• 英文别名: [Mn(((C10H6)(O)CHN)2CH2CHMe)(H2O)]ClO4
• CAS: 1342898-18-3
• 化学式: C₂₅H₂₂MnN₂O₃*ClO₄
• 分子量: 552.85
• InChiKey: LKCXMNDPBUOVMO-HXNPZEQSSA-K

反应信息

• 作为反应物：
  描述：

  caesium octacyanotungstate*2H2O 、 [Mn(((C10H6)(O)CHN)2CH2CHMe)(water)]ClO4 以 甲醇 、 水 、 乙腈 为溶剂， 生成 [Mn(((C10H6)(O)CHN)2CH2CHMe)W(cyanide)8][Mn(((C10H6)(O)CHN)2CH2CHMe)(water)2]2*(acetonitrile)*(water)
  参考文献：
  名称：

  Cyanide-Bridged W^VMn^III Single-Chain Magnet with Isolated Mn^III Moieties Exhibiting Two Types of Relaxation Dynamics

  摘要：

  A 5d-3d bimetallic compound was prepared by self-assembling [W(CN)(8)](3-) and the Mn-III Schiff bases. This neutral complex consists of cyanide-linked anionic chains and isolated Mn-III Schiff base cations. We demonstrate that two types of relaxation processes are involved in the system; the low-T dynamics may come from magnetic domain dynamics and the high-T relaxation stems from the anionic chain, revealing single-chain magnet character.

  DOI：

  10.1021/ic202100y