| 1161882-54-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• CAS: 1161882-54-7
• 化学式: C₃₂H₃₅N₂OP
• 分子量: 494.616
• InChiKey: BVGCVLDYMQCGDO-FRGOEROOSA-N

反应信息

• 作为产物：
  描述：

  萘酚 、 (3aS,7aS)-2-Chloro-1,3-bis-((S)-1-phenyl-ethyl)-octahydro-benzo[1,3,2]diazaphosphole 以 氘代氯仿 、 二氯甲烷 为溶剂， 反应 0.17h， 生成
  参考文献：
  名称：

  rac-9-Ethyl-12a-hydroxytetradecahydrotriphenylene-1,5(2H,4bH)-dione: stabilization of a new isomer of a functionalized perhydrotriphenylene through a tandem Michael addition–aldol reaction

  摘要：

  The title compound, C20H30O3, is a new functionalized perhydrotriphenylene derivative formed via a tandem Michael addition-aldol reaction. The structural study reveals that the system of fused rings approximates a C-2 point symmetry, with trans-cis-cis ring junctions, while highly symmetric all-trans perhydrotriphenylene, previously characterized, approximates a D-3 symmetry. The perhydrotriphenylene nucleus of the title compound corresponds to the third stable stereoisomer isolated for this polycyclic system. Considering that the C-S isomer was obtained recently through a similar tandem reaction, a general strategy is proposed which may help to obtain other stable stereoisomers of perhydrotriphenylene.

  DOI：

  10.1107/s0108270108011876