trans-[(SO4)Ru(III)(NH3)4(NCS)] | 93833-38-6

• 分子结构分类: 无机化合物
• 英文名称: trans-[(SO4)Ru(III)(NH3)4(NCS)]
• CAS: 93833-38-6
• 化学式: CH₁₂N₅O₄RuS₂
• 分子量: 323.339
• InChiKey: CINZGFMPRHBGDW-UHFFFAOYSA-L

反应信息

• 作为反应物：
  描述：

  氟硼酸钠 、 trans-[(SO4)Ru(III)(NH3)4(NCS)] 、 trans-[(SO3)Co(III)(cyclam)(CNS)]*4H2O 在 Zn/Hg 作用下， 以 水 为溶剂， 以60%的产率得到trans-[(SO3)Co(III)(NCS)(1,4,78,11-tetraazacyclotetradecane)Ru(II)(NH3)4(NCS)](BF4)*2H2O
  参考文献：
  名称：

  Asymmetric heterobimetallic mixed-valence complex trans-[(SO3)Co(cyclam)(NCS)Ru(NH3)4(NCS)](BF4): Synthesis and characterization

  摘要：

  [(SO3)Co(cyclam)(NCS)] and [(SO3)Co(cyclam)-NCS-Ru(NH3)(4)(NCS)](BF4) complexes were synthesized and characterized by means nix-ray diffraction, electrochemistry, elemental analysis, and spectroscopic techniques. Crystallographic and FTIR data indicated NCS- ligand is coordinated to Co through the nitrogen atom in the monomer species. Electrochemistry and FTIR data of the material isolated after reductive electrolysis of [(SO3)Co(cyclam)(NCS)] hint that NCS- and SO32- are released thus forming [Co(cyclam)(L)(2)](2+), where L is solvent molecules. The formation of the heterobimetallic mixed-valence complex induced a thermodynamic stabilization of Co and Ru metal atoms in the oxidized and reduced states, respectively. According to the Robin and Day classification, a Class II system with a comproportionation constant of 5.78 x 10(6) is suggested for the mixed-valence complex based on the electrochemical and UV-Vis-NIR results. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2011.05.019