5-[4-(3,4-ethylenedioxy-5-formylthiophen-2-yl)phenyl]-10,15,20-tris(4-methylphenyl)porphyrin zinc | 1253521-64-0

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二苯乙烯类
• 英文名称: 5-[4-(3,4-ethylenedioxy-5-formylthiophen-2-yl)phenyl]-10,15,20-tris(4-methylphenyl)porphyrin zinc
• CAS: 1253521-64-0
• 化学式: C₅₄H₃₈N₄O₃SZn
• 分子量: 888.377
• InChiKey: LBTZOVYRTBXWLZ-NJLIRLSYSA-M

反应信息

• 作为反应物：
  描述：

  5-[4-(3,4-ethylenedioxy-5-formylthiophen-2-yl)phenyl]-10,15,20-tris(4-methylphenyl)porphyrin zinc 、 氰乙酸 在 哌啶 作用下， 以 乙腈 为溶剂， 以58%的产率得到2-cyano-3-{3,4-ethylenedioxy-5-[4-(10,15,20-tris(4-methylphenyl)porphyrinatozinc(II)-5-yl)phenyl]thiophen-2-yl}acrylic acid
  参考文献：
  名称：

  The structural modification of thiophene-linked porphyrin sensitizers for dye-sensitized solar cells

  摘要：

  Three donor (pi-spacer) acceptor porphyrin dyes were synthesized for use in dye-sensitized solar cells The dyes comprised the same donor (porphyrin derivative) and acceptor/anchoring group (2-cyanoacrylic acid) but varying pi-spacer consisting of a combination of 4-methylthiophene, 4-hexylthiophene or 3,4-ethylenedioxythiophene groups The dyes displayed different adsorption behavior and coverage of the TiO2 surface (C) 2010 Elsevier Ltd. All rights reserved

  DOI：

  10.1016/j.dyepig.2010.05.003
• 作为产物：
  描述：

  5-[4-(3,4-ethylenedioxy-5-formylthiophen-2-yl)phenyl]-10,15,20-tris(4-methylphenyl)porphyrin 在 zinc diacetate 作用下， 以 甲醇 、 氯仿 为溶剂， 以97%的产率得到5-[4-(3,4-ethylenedioxy-5-formylthiophen-2-yl)phenyl]-10,15,20-tris(4-methylphenyl)porphyrin zinc
  参考文献：
  名称：

  The structural modification of thiophene-linked porphyrin sensitizers for dye-sensitized solar cells

  摘要：

  Three donor (pi-spacer) acceptor porphyrin dyes were synthesized for use in dye-sensitized solar cells The dyes comprised the same donor (porphyrin derivative) and acceptor/anchoring group (2-cyanoacrylic acid) but varying pi-spacer consisting of a combination of 4-methylthiophene, 4-hexylthiophene or 3,4-ethylenedioxythiophene groups The dyes displayed different adsorption behavior and coverage of the TiO2 surface (C) 2010 Elsevier Ltd. All rights reserved

  DOI：

  10.1016/j.dyepig.2010.05.003