1-((2-hydroxy-5-chlorophenyl)diazenyl)naphthalen-2-ol | 1099088-09-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 1-((2-hydroxy-5-chlorophenyl)diazenyl)naphthalen-2-ol
• 英文别名: 1-(5-chloro-2-hydroxyphenyl)azo-2-hydroxynaphthalene；1-[(5-chloro-2-hydroxyphenyl)azo]-2-naphthalenol
• CAS: 1099088-09-1
• 化学式: C₁₆H₁₁ClN₂O₂
• 分子量: 298.729
• InChiKey: HQKOBNMULFASAN-VHEBQXMUSA-N

物化性质

• 沸点：
  532.1±50.0 °C(Predicted)
• 密度：
  1.37±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.32
• 重原子数：
  21.0
• 可旋转键数：
  2.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  65.18
• 氢给体数：
  2.0
• 氢受体数：
  4.0

反应信息

• 作为反应物：
  描述：

  1-((2-hydroxy-5-chlorophenyl)diazenyl)naphthalen-2-ol 在 sodium hydroxide 作用下， 以 水 为溶剂， 生成
  参考文献：
  名称：

  WO2007/9966

  摘要：

  公开号：

文献信息

• Polymerizable metal-azo and metal-azomethine dyes
  申请人：MINNESOTA MINING AND MANUFACTURING COMPANY

  公开号：EP0503780A1

  公开（公告）日：1992-09-16

  Disclosed are metal-azo and metal-azomethine materials which are useful as monomeric dyes which may be mordanted by polymerization. The inventive dyes contain a central metal ; an azo containing ligand ; and a ligand having a free-radically polymerizable group (not directly attached to the azo or azomethine containing ligand) bound to the metal, and optionally, a monodentate or bidentate ligand which satisfy the coordination requirements of the central metal. Also disclosed are homopolymers and copolymers of the metal-azo or metal azomethine dyes.

  本发明公开了可用作单体染料的金属偶氮和金属偶氮亚甲基材料，这些单体染料可通过聚合作用进行媒染。本发明的染料含有中心金属、含偶氮配体、与金属结合的可自由基聚合的配体（不直接连接到含偶氮或偶氮亚甲基的配体上），以及满足中心金属配位要求的单齿或双齿配体。此外，还公开了金属偶氮或金属偶氮亚甲基染料的均聚物和共聚物。
• Transfer imaging using metal-azo and metal-azomethine dyes
  申请人：MINNESOTA MINING AND MANUFACTURING COMPANY

  公开号：EP0508573A1

  公开（公告）日：1992-10-14

  Dye donor sheets comprising a substrate having a coating comprising a binder and at least one neutral 1 :1 metal-azo or neutral 1 :1 metal-azomethine dye having the general structure : wherein Z1 and Z2 each independently represent an arene nucleus, having from 5 to 14 ring atoms ; G1 and G2 each independently represent a metal ligating group, and further wherein G1 and G2 may be contained within or pendant from at least one of Z1 and Z2 ; R represents a hydrogen atom, a halogen atom, an alkyl group, an acylamino group, an alkoxy group, a sulfonarmido group, an aryl group, a thiol group, an alkylthio group, an arylthio group, an alkylamino group, an arylamino group, an amino group, an alkoxycarbonyl group, an acyloxy group, a nitro group, a cyano group, a sulfonyl group, a sulfoxyl group, an aryloxy group, a hydroxy group, a thioanido group, a carbamoyl group, a sulfamoyl group, a carboxyl group, a sulfo group, a formyl group, an acyl group, a ureido group, or aryloxycarbonyl group, a silyl group, a carbonato group ; or a sulfoalkoxy group ; L is any combination of monodentate, bidentate, or tridentate ligands which satisfy the coordination requirements of the metal ; X represents nitrogen or a methine (CH) group ; M is a divalent or polyvalent transition metal where the coordination number is at least four, and k, m, and n are whole members less than or equal to 3. Use of the above constructions in thermal dye transfer imaging is also disclosed.

  染料给体薄片，包括具有涂层的基底，涂层包括粘合剂和至少一种中性 1:1 金属偶氮染料或中性 1:1 金属偶氮甲胺染料，染料的一般结构为......： 其中 Z1 和 Z2 各自独立地代表一个具有 5 至 14 个环原子的炔核； G1 和 G2 各自独立地代表一个金属连接基团，其中 G1 和 G2 可包含在 Z1 和 Z2 中的至少一个内或悬垂于其中； R 代表氢原子、卤素原子、烷基、酰氨基、烷氧基、磺酰氨基、芳基、硫醇基、烷硫基、芳硫基、烷基氨基、芳基氨基、氨基、烷氧基羰基、酰氧基、硝基、氰基、烷基羰基、烷氧基羰基、烷氧基羰基、烷氧基羰基、酰氧基硝基、氰基、磺酰基、磺酰胺基、芳氧基、羟基、硫酰胺基、氨基甲酰基、氨基磺酰基、羧基、磺酰基、甲酰基、酰基、脲酰基或芳氧羰基、硅烷基、碳酸基；或磺烷氧基； L 是满足金属配位要求的单齿、双齿或三齿配体的任意组合； X 代表氮或甲烷（CH）基团； M 是配位数至少为四的二价或多价过渡金属，且 k、m 和 n 是小于或等于 3 的整数。 上述结构在热染料转移成像中的应用也已公开。
• Monoazo metal complex compound containing composition and production method thereof
  申请人：ORIENT CHEMICAL INDUSTRIES, LTD.

  公开号：EP1160293A2

  公开（公告）日：2001-12-05

  Monoazo metal complex compound containing composition, the incidence of skin sensitization in a skin sensitization potential test based on the maximization method of said composition being not more than 20% and method for producing said composition which comprises a step for removing impurity substances using an alcoholic organic solvent; charge control agent comprising said composition and toner containing said charge control agent; coloring agent containing said composition and colored thermoplastic resin composition containing said coloring agent.

  含有单偶氮金属络合物的组合物，在基于最大化方法的皮肤致敏可能性测试中，所述组合物的皮肤致敏发生率不超过 20%，以及生产所述组合物的方法，其中包括使用醇类有机溶剂去除杂质物质的步骤；电荷控制剂，包括所述组合物和含有所述电荷控制剂的调色剂；着色剂，包括所述组合物和含有所述着色剂的有色热塑性树脂组合物。
• ENVIRONMENTALLY RESPONSIVE CHROMATIC LUMINESCENT COMPOSITIONS WITH IMPROVED HAND
  申请人：Bambu Vault LLC

  公开号：EP3174953B1

  公开（公告）日：2020-09-02
• Chromium Complex Dyes
  申请人：Nusser Rainer

  公开号：US20090263630A1

  公开（公告）日：2009-10-22

  The present invention relates to novel 1:2 chromium complex dyes, processes for their preparation and their use for dyeing or printing fibre materials containing hydroxyl groups or containing nitrogen. The present invention relates to a 1:2 chromium complex dye of formula (I) wherein all substituents are as defined in the claims, a process for their preparation and their use for dyeing or printing fiber materials containing hydroxyl groups or containing nitrogen.