An entry route into non-aqueous plutonyl coordination chemistry
作者:Andrew J. Gaunt、Sean D. Reilly、Trevor W. Hayton、Brian L. Scott、Mary P. Neu
DOI:10.1039/b618577k
日期:——
The Pu(VI) molecular complex, [PuO(2)Cl(2)(thf)(2)]2, is prepared by addition of a HCl/Et(2)O solution to a suspension of PuO(2)CO(3) in thf, yielding the first example of a precursor suitable for investigation of the non-aqueous chemistry of the plutonyl dioxocation under inert atmospheric conditions.