2-[[2-[2-[(1-Hydroxynaphthalen-2-yl)methylideneamino]phenyl]phenyl]iminomethyl]naphthalen-1-ol | 866723-84-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 2-[[2-[2-[(1-Hydroxynaphthalen-2-yl)methylideneamino]phenyl]phenyl]iminomethyl]naphthalen-1-ol
• CAS: 866723-84-4
• 化学式: C₃₄H₂₄N₂O₂
• 分子量: 492.577
• InChiKey: VQDYWRUAXVNKTF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.9
• 重原子数：
  38
• 可旋转键数：
  5
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  65.2
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  manganese(III) triacetate dihydrate 、 2-[[2-[2-[(1-Hydroxynaphthalen-2-yl)methylideneamino]phenyl]phenyl]iminomethyl]naphthalen-1-ol 以 乙醇 为溶剂， 以70%的产率得到
  参考文献：
  名称：

  Synthetic Study of Symmetrical and Unsymmetrical Schiff Base Complexes of VO(IV) and Mn(III) Derived from 2,2′‐Diaminobiphenyl

  摘要：

  The symmetrical and unsymmetrical Schiff base complexes of VO( IV) and Mn( III) derived from 2,20-diaminobiphenyl and derivatives of salicylaldehyde and 1-hydroxy-2-naphthaldehyde have been synthesized and characterized by elemental analysis, NMR, infrared and electronic absorption spectroscopies, and conductivity measurements. The reaction of the ligands with oxovanadium( IV) was found to be kinetically unfavored, probably due to the small ionic radius of the metal ion, which is not in accordance with the cavity size of the ligands.

  DOI：

  10.1081/sim-200055230