N-丁基-1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-十七氟代-1-辛烷磺酰胺 | 31506-34-0

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 卤代烷
• 中文名称: N-丁基-1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-十七氟代-1-辛烷磺酰胺
• 英文名称: N-Butyl-perfluoroctansulfonamid
• 英文别名: n-C8F17SO2NHC4H9；N-butyl perfluorooctanesulfonamide；N-butyl-1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-heptadecafluorooctane-1-sulfonamide
• CAS: 31506-34-0
• 化学式: C₁₂H₁₀F₁₇NO₂S
• 分子量: 555.256
• InChiKey: UUZCNLZINSJLSR-UHFFFAOYSA-N

物化性质

• 沸点：
  283.0±50.0 °C(Predicted)
• 密度：
  1.588±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6.5
• 重原子数：
  33
• 可旋转键数：
  11
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  54.6
• 氢给体数：
  1
• 氢受体数：
  20

安全信息

• 海关编码：
  2935009090

反应信息

• 作为产物：
  描述：

  全氟辛基磺酰氟 、 正丁胺 在 三乙胺 作用下， 以 异丙醚 为溶剂， 反应 4.0h， 生成 N-丁基-1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-十七氟代-1-辛烷磺酰胺
  参考文献：
  名称：

  Synthesis and surface activities of organic solvent-soluble fluorinated surfactants

  摘要：

  A variety of fluorinated surfactants soluble in organic solvent were prepared, including C8F17SO2NHCnH2n+1 (n = 2, 4, 6, 8, 10), C8F17SO2NHR (R = C6H11, C6H5), C8F17SO2N(C(n)H(2)n(+1))(2) (n = 1, 2, 3, 4) and C8F17SO2NH(CH2)(n)NHO2SC8F17 (n = 6, 10). Their surface activities in various organic solvents were determined by surface tension measurement. The results showed that these fluorinated surfactants can reduce the surface tension of both polar and non-polar organic solvents. In general, organic solvents with strong polarity or long alkyl chain are beneficial to increase the surface activity of these polar fluorinated surfactants. By comparing fluorinated surfactants with the same fluorocarbon segment and connecting group, C8F17SO2N(CnH2n+1)(2) (n = 1, 2, 3, 4) showed lower surface activity in organic solvents than C8F17SO2NHCnH2n+1 (n = 2, 4, 6, 8) with an equal carbon number of the solvophilic group. Through surface tension vs. concentration curves given for N-octyl perfluorooctanesulfonamide in various organic solvents, a break point like the critical micelle concentration of ordinary surfactants in aqueous solutions was observed, and the effect of the different types of organic solvents on adsorption and aggregation behavior was also studied. (C) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jfluchem.2009.05.006

文献信息

• Polymerizable composition and compound therefor
  申请人：Kunita Kazuto

  公开号：US20050008967A1

  公开（公告）日：2005-01-13

  To provide a polymerizable composition suitable for a lithographic printing plate precursor which can satisfy the requirements of high sensitivity, excellent storage stability and long press life and enables direct plate making from digital data from computer, etc. when recording is conducted a solid laser or semiconductor laser emitting ultraviolet ray, visible light or infrared ray and a compound therefore, the present invention relates to a photoradical polymerizable composition comprising a polyfunctional crosslinking agent having a specific structure represented by formula (I) or (II) defined in the specification.

  为了提供一种适用于平版印刷版前体的可聚合组合物，该组合物能够满足高灵敏度、优异的储存稳定性和长印刷寿命的要求，并且在使用固体激光器或半导体激光器发射紫外线、可见光或红外线进行记录时，能够根据来自计算机等的数字数据直接制版，本发明涉及一种光阳极可聚合组合物，该组合物包含具有本说明书中定义的式(I)或式(II)所代表的特定结构的多官能团交联剂。
• Polymer having polymerizable group, polymerizable composition, planographic printing plate precursor, and planographic printing method using the same
  申请人：Kunita Kazuto

  公开号：US20060057492A1

  公开（公告）日：2006-03-16

  A polymer having a polymerizable group and an alkyleneoxy groups on side chains thereof, and a polymerizable composition containing the polymer. The polymerizable composition preferably contains a polymerizable compound and a polymerization initiator. Also provided is a planographic printing plate precursor having a polymerizable layer on a hydrophilic support, the polymerizable layer containing a polymer having a polymerizable on a side chain thereof. The planographic printing plate precursor can form an image without being subjected to an alkali development. An undercoat layer containing a specific copolymer may be provided between the support and the photopolymerizable layer.

  一种聚合物，其侧链上具有可聚合基团和烷氧基，以及一种含有该聚合物的可聚合组合物。可聚合组合物最好含有可聚合化合物和聚合引发剂。此外，还提供了一种在亲水性支撑物上具有可聚合层的平版印刷板前体，该可聚合层含有在其侧链上具有可聚合基团的聚合物。这种平版印刷板前体无需经过碱显影即可形成图像。在支承层和可光聚合层之间可设置一个含有特定共聚物的底涂层。
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: F: PerFHalOrg.2, 1.3.4, page 137 - 166
  作者：

  DOI：——

  日期：——
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: F: PerFHalOrg.SVol.3, 6.2.3.4, page 152 - 186
  作者：

  DOI：——

  日期：——
• Perfluoroalkylsulfonamido - alkyl esters of fumaric acid and other ethylenically unsaturated polybasic acids and polymers thereof
  申请人：CIBA?GEIGY CORPORATION

  公开号：US03636085A1

  公开（公告）日：1972-01-18