6,6-dimethyl-4,5,6,7-tetrahydro-benzofuran-4-ylamine | 1174315-57-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并呋喃
• 英文名称: 6,6-dimethyl-4,5,6,7-tetrahydro-benzofuran-4-ylamine
• 英文别名: 6,6-dimethyl-5,7-dihydro-4H-1-benzofuran-4-amine
• CAS: 1174315-57-1
• 化学式: C₁₀H₁₅NO
• 分子量: 165.235
• InChiKey: JPMGSYOKPWPNFQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.5
• 重原子数：
  12
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  39.2
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2-cyano-3-difluoromethoxyphenylsulfonyl chloride 、 6,6-dimethyl-4,5,6,7-tetrahydro-benzofuran-4-ylamine 以 乙腈 为溶剂， 反应 16.0h， 生成 2-cyano-3-(difluoromethoxy)-N-(6,6-dimethyl-5,7-dihydro-4H-1-benzofuran-4-yl)benzenesulfonamide
  参考文献：
  名称：

  [EN] 2 -CYANO PHENYL SULFONAMIDE DERIVATIVES USEFUL AS PESTICIDES
  [FR] COMPOSÉS CHIMIQUES

  摘要：

  公开号：

  WO2009092590A3

文献信息

• CHEMICAL COMPOUNDS
  申请人：Pitterna Thomas

  公开号：US20100311582A1

  公开（公告）日：2010-12-09

  A compound of the formula (I) where, for example, W, X and Y are each CH; R 1 and R 6 , independently of each other, are for example, selected from the group consisting of H, C1-C6-alkyl, C2-C6-alkenyl, C2-C6-alkynyl, C1-C6-alkoxy, C3-C8-cycloalkyl, R 7 C(═O), and a ring system; provided that at least one of R 1 and R 6 is a —C2-C6-alkenylthio-C1-C6-alkyl, —C1-C6-alkoxy-C(═O)NRx-C1-C6-alkyl, —partially or fully unsaturated ring system containing in at least one ring in the ring system at least one hetero atom selected from N, O and S, which ring system is bound (i.e. through the N bonded to R 1 and R 6 in formula I) either directly or via a a C1-C6-alkylene group to the remainder of the compound, —partially or fully unsaturated ring system containing a ring that is bound to the remainder of the compound (i.e. through the N bonded to R 1 and R 6 in formula I) via a C1-C6-alkylene group, which group contains at least one hetero atom and/or heteroatom group selected from N, O, S, SO, SO 2 , and C(=0), —a ring system having a 5- to 14-membered bicylic ring which may be unsubstituted or be substituted with 1, 2 or 3, independently of one another, radicals selected from halogen, C1-C6-alkyl, C1-C6-haloalkyl, C1-C6-alkoxy and C1-C6-haloalkoxy, or —(C3-C8-cyloalkyl)thio-C1-C6-alkyl; R 2 is, for example, H, halogen, C1-C6-alkyl, C1-C6-haloalkyl, C1-C6-alkoxy, C1-C6-haloalkoxy or C1-C6-alkoxy-C1-C6-alkoxy, and/or salts thereof; and their use as pesticidal agents.

  化合物的公式（I），其中，例如，W、X和Y都是CH；R1和R6彼此独立，例如，从H、C1-C6-烷基、C2-C6-烯基、C2-C6-炔基、C1-C6-烷氧基、C3-C8-环烷基、R7C（═O）和环系组成的群中选择；前提是R1和R6中至少有一个是-C2-C6-烯基硫基-C1-C6-烷基，-C1-C6-烷氧基-C（═O）NRx-C1-C6-烷基，部分或完全不饱和的环系，其中在环系中至少有一个环中含有N、O和S中选择的至少一个杂原子，该环系通过式I中与R1和R6结合的N直接或通过C1-C6-烷基链与化合物的其余部分结合，部分或完全不饱和的环系，其中有一个环通过C1-C6-烷基链与化合物的其余部分结合，该链含有至少一个N、O、S、SO、SO2和C（=0）中选择的杂原子和/或杂原子基，具有5-至14-成员的双环环系，可以是未取代的或被1、2或3个彼此独立的基团（选择自卤素、C1-C6-烷基、C1-C6-卤代烷基、C1-C6-烷氧基和C1-C6-卤代烷氧基）取代的；R2，例如，是H、卤素、C1-C6-烷基、C1-C6-卤代烷基、C1-C6-烷氧基、C1-C6-卤代烷氧基或C1-C6-烷氧基-C1-C6-烷氧基，和/或其盐；以及它们作为杀虫剂的用途。
• 2-Cyanophenyl Sulfonamide Derivatives Useful as Pesticides
  申请人：Syngenta Participations AG

  公开号：EP2500340A1

  公开（公告）日：2012-09-19

  A compound of the formula I where, for example, W, X and Y are each CH; R1 and R6, independently of each other, are for example, selected from the group consisting of H, C1-C6-alkyl, C2-C6-alkenyl, C2-C6-alkynyl, C1-C6-alkoxy, C3-C8-cycloalkyl, R7C(=O), and a ring system; provided that at least one of R1 and R6 is a - partially or fully unsaturated ring system containing in at least one ring in the ring system at least one hetero atom selected from N, O and S, which ring system is bound (i.e. through the N bonded to R1 and R6 in formula I) either directly or via a a C1-C6-alkylene group to the remainder of the compound, - a ring system having a 5- to 14-membered bicylic ring which may be unsubstituted or be substituted with 1, 2 or 3, independently of one another, radicals selected from halogen, C1-C6-alkyl, C1-C6-haloalkyl, C1-C6-alkoxy and C1-C6-haloalkoxy, or R2 is, for example,H, halogen, C1-C6-alkyl, C1-C6-haloalkyl, C1-C6-alkoxy, C1-C6-haloalkoxy or C1-C6-alkoxy-C1-C6-alkoxy, and/or salts thereof; and their use as as pesticidal agents.

  式 I 的化合物 其中，W、X 和 Y 各为 CH； R1 和 R6 相互独立，例如选自由 H、C1-C6-烷基、C2-C6-烯基、C2-C6-炔基、C1-C6-烷氧基、C3-C8-环烷基、R7C(=O) 和环系统组成的组； 条件是 R1 和 R6 中至少有一个是 - 部分或完全不饱和环系，在环系的至少一个环中含有至少一个选自 N、O 和 S 的杂原子，该环系直接或通过一个 C1-C6- 烷基与化合物的其余部分结合（即通过式 I 中与 R1 和 R6 结合的 N）、 - 具有 5 至 14 元双环的环系，该环系可以未被取代，也可以被 1、2 或 3 个彼此独立的基取代，这些基选自卤素、C1-C6-烷基、C1-C6-卤代烷基、C1-C6-烷氧基和 C1-C6-卤代烷氧基，或 R2 例如是 H、卤素、C1-C6-烷基、C1-C6-卤代烷基、C1-C6-烷氧基、C1-C6-卤代烷氧基或 C1-C6- 烷氧基-C1-C6-烷氧基、 和/或其盐类；以及它们作为杀虫剂的用途。
• 2-CYANOPHENYL SULFONAMIDE DERIVATIVES USEFUL AS PESTICIDES
  申请人：Syngenta Participations AG

  公开号：EP2231632A2

  公开（公告）日：2010-09-29
• [EN] CHEMICAL COMPOUNDS<br/>[FR] COMPOSÉS CHIMIQUES
  申请人：SYNGENTA PARTICIPATIONS AG

  公开号：WO2009092590A2

  公开（公告）日：2009-07-30

  A compound of the formula (I) where, for example, W, X and Y are each CH; R1 and R6, independently of each other, are for example, selected from the group consisting of H, C1-C6-alkyl, C2-C6-alkenyl, C2-C6-alkynyl, C1-C6-alkoxy, C3-C8-cycloalkyl, R7C(=O), and a ring system; provided that at least one of R1 and R6 is a - C2-C6-alkenylthio-C1 -C6-alkyl, - C1 -C6-alkoxy-C(=O)NRx-C1-C6-alkyl, - partially or fully unsaturated ring system containing in at least one ring in the ring system at least one hetero atom selected from N, O and S, which ring system is bound (i.e. through the N bonded to R1 and R6 in formula I) either directly or via a a C1-C6-alkylene group to the remainder of the compound, - partially or fully unsaturated ring system containing a ring that is bound to the remainder of the compound (i.e. through the N bonded to R1 and R6 in formula I) via a C1-C6-alkylene group, which group contains at least one hetero atom and/or heteroatom group selected from N, O, S, SO, SO2, and C(=0), - a ring system having a 5- to 14-membered bicylic ring which may be unsubstituted or be substituted with 1, 2 or 3, independently of one another, radicals selected from halogen, C1-C6-alkyl, C1-C6-haloalkyl, C1-C6-alkoxy and C1-C6-haloalkoxy, or - (C3-C8-cyloalkyl)thio-C1 -C6-alkyl; R2 is, for example, H, halogen, C1 -C6-alkyl, C1-C6-haloalkyl, C1-C6-alkoxy, C1-C6-haloalkoxy or C1-C6-alkoxy-C1 -C6-alkoxy, and/or salts thereof; and their use as as pesticidal agents.
• [EN] 2 -CYANO PHENYL SULFONAMIDE DERIVATIVES USEFUL AS PESTICIDES<br/>[FR] COMPOSÉS CHIMIQUES
  申请人：SYNGENTA PARTICIPATIONS AG

  公开号：WO2009092590A3

  公开（公告）日：2009-12-17