(4-(6,9-diphenyl-9H-carbazol-3-yl)-phenyl)-bis(biphenyl-4-yl)-amine | 1160294-84-7

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: (4-(6,9-diphenyl-9H-carbazol-3-yl)-phenyl)-bis(biphenyl-4-yl)-amine
• 英文别名: N-[4-(6,9-diphenylcarbazol-3-yl)phenyl]-4-phenyl-N-(4-phenylphenyl)aniline
• CAS: 1160294-84-7
• 化学式: C₅₄H₃₈N₂
• 分子量: 714.909
• InChiKey: ZLQDQAGCAFNMHG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  14.7
• 重原子数：
  56
• 可旋转键数：
  8
• 环数：
  10.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  8.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  3-溴-6,9-二苯基-9H-咔唑 、 B-[4-[双(联苯-4-基)氨基]苯基]硼酸 在 palladium diacetate 、 三(邻甲基苯基)磷 potassium carbonate 作用下， 以 乙醇 、 水 、 甲苯 为溶剂， 反应 3.0h， 以87%的产率得到(4-(6,9-diphenyl-9H-carbazol-3-yl)-phenyl)-bis(biphenyl-4-yl)-amine
  参考文献：
  名称：

  [EN] CARBAZOLE DERIVATIVE, AND LIGHT-EMITTING ELEMENT, LIGHT-EMITTING DEVICE, AND ELECTRONIC DEVICE USING CARBAZOLE DERIVATIVE
  [FR] DÉRIVÉ CARBAZOLE, ET ÉLÉMENT ÉMETTANT DE LA LUMIÈRE, DISPOSITIF ÉMETTANT DE LA LUMIÈRE, ET DISPOSITIF ÉLECTRONIQUE UTILISANT LE DÉRIVÉ CARBAZOLE

  摘要：

  为提供具有高发光效率的发光元件，并提供一种低功耗、低电压驱动的发光装置和电子设备，提供了由通式（1）表示的咔唑衍生物。在该式中，α1、α2、α3 和 α4 分别表示具有小于或等于 13 个碳原子的芳基基团；Ar1 和 Ar2 分别表示具有小于或等于 13 个碳原子的芳基基团；R1 表示氢原子、具有 1 到 6 个碳原子的烷基基团、取代或未取代的苯基团，以及取代或未取代的联苯基团中的任意一种；R2 表示具有 1 到 6 个碳原子的烷基基团、取代或未取代的苯基团，以及取代或未取代的联苯基团中的任意一种。此外，l、m 和 n 分别独立地为 0 或 1。

  公开号：

  WO2009072587A1

文献信息

• ORGANIC LIGHT EMITTING DEVICE
  申请人：SAMSUNG DISPLAY CO., LTD.

  公开号：US20170288147A1

  公开（公告）日：2017-10-05

  An organic light emitting device including an anode; a hole transport region on the anode; an emission layer on the hole transport region; an electron transport region on the emission layer; and a cathode on the electron transport region, wherein the hole transport region includes: a first hole transport layer including a first hole transport material represented by the following Formula 1 or a second hole transport material represented by the following Formula 2; and a second hole transport layer on the first hole transport layer, the second hole transport layer including a third hole transport material represented by the following Formula 3 or a fourth hole transport material represented by the following Formula 4:

  一种有机发光器件，包括：阳极；位于阳极上的空穴传输区域；位于空穴传输区域上的发射层；位于发射层上的电子传输区域；以及位于电子传输区域上的阴极，其中空穴传输区域包括：第一空穴传输层，包括由以下化学式1表示的第一空穴传输材料或由以下化学式2表示的第二空穴传输材料；以及位于第一空穴传输层上的第二空穴传输层，第二空穴传输层包括由以下化学式3表示的第三空穴传输材料或由以下化学式4表示的第四空穴传输材料：
• ORGANIC ELECTROLUMINESCENCE ELEMENT AND ELECTRONIC APPARATUS
  申请人：IDEMITSU KOSAN CO., LTD.

  公开号：US20210005826A1

  公开（公告）日：2021-01-07

  An organic electroluminescence device comprising a cathode, an anode and an organic layer disposed between the cathode and the anode, wherein the organic layer comprises a fluorescent emitting layer and the fluorescent emitting layer comprises a first compound, a second compound having a hole mobility larger than that of the first compound, and a dopant material showing a fluorescent spectrum with a half width of 30 nm or less; and an organic electroluminescence device comprising a cathode, an anode and an organic layer disposed between the cathode and the anode, wherein the organic layer comprises a fluorescent emitting layer and the fluorescent emitting layer comprises a first compound, a third compound having an affinity larger than that of the first compound, and a dopant material showing a fluorescent spectrum with a half width of 30 nm or less and the content of the third compound in the fluorescent emitting layer is less than that of the first compound in the fluorescent emitting layer are excellent in their performance.

  一种有机电致发光装置，包括阴极、阳极以及设置在阴极和阳极之间的有机层，其中所述有机层包括荧光发射层，且所述荧光发射层包括第一化合物、第二化合物和掺杂材料，所述第二化合物的空穴迁移率大于所述第一化合物，且所述掺杂材料显示的荧光光谱半宽为30纳米或更小；以及一种有机电致发光装置，包括阴极、阳极以及设置在阴极和阳极之间的有机层，其中所述有机层包括荧光发射层，且所述荧光发射层包括第一化合物、第三化合物和掺杂材料，所述第三化合物与所述第一化合物的亲和力更大，且所述掺杂材料显示的荧光光谱半宽为30纳米或更小，且所述第三化合物在荧光发射层中的含量小于所述第一化合物在荧光发射层中的含量，这些装置的性能都十分出色。
• ORGANIC ELECTROLUMINESCENT ELEMENT AND ELECTRONIC DEVICE
  申请人：IDEMITSU KOSAN CO., LTD.

  公开号：US20210005825A1

  公开（公告）日：2021-01-07

  An organic electroluminescence device comprising a cathode, an anode and an organic layer disposed between the cathode and the anode, wherein the organic layer comprises a fluorescent emitting layer and the fluorescent emitting layer comprises at least one first compound selected from the compounds represented by formulae (19), (21), (22), and (23), a second compound selected from the compounds represented by formula (3a), and a dopant material selected from the compounds represented by formulae (D1) and (D2) is excellent in its performance.

  一个有机电致发光装置，包括阴极、阳极和位于阴极与阳极之间的有机层，其中所述有机层包括荧光发射层，且所述荧光发射层包括至少一种由公式（19）、（21）、（22）和（23）所表示的化合物中选择的第一化合物，一种由公式（3a）所表示的化合物中选择的第二化合物，以及一种由公式（D1）和（D2）所表示的化合物中选择的掺杂材料，其性能卓越。
• Light-Emitting Element, Light-Emitting Device, Electronic Device, and Lighting Device
  申请人：Semiconductor Energy Laboratory Co., Ltd.

  公开号：US20140034929A1

  公开（公告）日：2014-02-06

  A light-emitting element having a long lifetime is provided. A light-emitting element exhibiting high emission efficiency in a high luminance region is provided. A light-emitting element includes a light-emitting layer between a pair of electrodes. The light-emitting layer contains a first organic compound, a second organic compound, and a phosphorescent compound. The first organic compound is represented by a general formula (G0). The molecular weight of the first organic compound is greater than or equal to 500 and less than or equal to 2000. The second organic compound is a compound having an electron-transport property. In the general formula (G0), Ar 1 and Ar 2 each independently represent a fluorenyl group, a spirofluorenyl group, or a biphenyl group, and Ar 3 represents a substituent including a carbazole skeleton.

  提供了一种寿命长的发光元件。提供了一种在高亮度区域表现出高发射效率的发光元件。发光元件包括位于一对电极之间的发光层。发光层含有第一有机化合物、第二有机化合物和磷光化合物。第一有机化合物由通式（G0）表示。第一有机化合物的分子量大于或等于500且小于或等于2000。第二有机化合物是具有电子传输性质的化合物。在通式（G0）中，Ar1和Ar2各自独立地表示芴基团、螺芴基团或联苯基团，而Ar3表示包括咔唑骨架的取代基。
• Carbazole Derivative, and Light-Emitting Element, Light-Emitting Device, and Electronic Device Using Carbazole Derivative
  申请人：Nomura Hiroko

  公开号：US20090160323A1

  公开（公告）日：2009-06-25

  To provide a light-emitting element having high luminous efficiency and to provide a light-emitting device and an electronic device which consumes low power and is driven at low voltage, a carbazole derivative represented by the general formula (1) is provided. In the formula, α 1 , α 2 , α 3 , and α 4 each represent an arylene group having less than or equal to 13 carbon atoms; Ar 1 and Ar 2 each represent an aryl group having less than or equal to 13 carbon atoms; R 1 represents any of a hydrogen atom, an alkyl group having 1 to 6 carbon atoms, a substituted or unsubstituted phenyl group, and a substituted or unsubstituted biphenyl group; and R 2 represents any of an alkyl group having 1 to 6 carbon atoms, a substituted or unsubstituted phenyl group, and a substituted or unsubstituted biphenyl group. In addition, l, m, and n are each independently 0 or 1.

  为了提供具有高发光效率的发光元件，并提供低功耗、低电压驱动的发光装置和电子装置，提供了由通式（1）表示的咔唑衍生物。在该式中，α1、α2、α3和α4各代表具有小于或等于13个碳原子的芳烃基；Ar1和Ar2各代表具有小于或等于13个碳原子的芳基；R1代表氢原子、具有1至6个碳原子的烷基、取代或未取代的苯基和取代或未取代的联苯基中的任意一种；R2代表具有1至6个碳原子的烷基、取代或未取代的苯基和取代或未取代的联苯基中的任意一种。此外，l、m和n各自独立地为0或1。