1,4,8,11-tetraoxacyclotetradecyl[2,3:9,10]bis-dipyrido[3,2-a:2'3'-c]phenazine | 1170773-84-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 菲咯啉
• 英文名称: 1,4,8,11-tetraoxacyclotetradecyl[2,3:9,10]bis-dipyrido[3,2-a:2'3'-c]phenazine
• 英文别名: 2,6,29,33-Tetraoxa-10,16,19,25,37,43,46,52-octazaundecacyclo[32.20.0.07,28.09,26.011,24.012,17.018,23.036,53.038,51.039,44.045,50]tetrapentaconta-1(34),7(28),8,10,12(17),13,15,18(23),19,21,24,26,35,37,39(44),40,42,45(50),46,48,51,53-docosaene
• CAS: 1170773-84-8
• 化学式: C₄₂H₂₈N₈O₄
• 分子量: 708.736
• InChiKey: JGLSOWTYCACHIY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.5
• 重原子数：
  54
• 可旋转键数：
  0
• 环数：
  11.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  140
• 氢给体数：
  0
• 氢受体数：
  12

反应信息

• 作为反应物：
  描述：

  顺-双(2,2-二吡啶)二氯化钌(II) 水合物 、 1,4,8,11-tetraoxacyclotetradecyl[2,3:9,10]bis-dipyrido[3,2-a:2'3'-c]phenazine 、 hexafluorophosphate anion 以 乙二醇 为溶剂， 以75.6%的产率得到(1,4,8,11-tetraoxacyclotetradecyl[2,3:9,10]bis-dipyrido[3,2-a:2'3'-c]phenazine)di(bis(2,2'-bipyridine)ruthenium(II)) hexafluorophosphate
  参考文献：
  名称：

  A new family of dinuclear Ru(II) polypyridyl complexes containing dibenzo-14-crown-4

  摘要：

  Three bis(bidentate) ligands cis-di(4,5-diazafluoren-9-ylimino)dibenzo-14-crown-4 (BL1), trans-di(4,5-diazafluoren-9-ylimino)dibenzo-14-crown-4 (BL2), and 1,4,8,11-tetraoxacyclotetradecyl[2,3:9,10]bis-dipyrido[3,2-a:2'3'-c]phenazine (BL3), and corresponding bimetallic Ru(II) complexes [(bpy)(2)RuBL1-3Ru(bpy)(2)](PF6)(4) (Ru-BL1-3) have been synthesized. Cyclic voltammetry of these complexes are consistent with one Ru(II)-centered reversible oxidation and three ligand-centered reductions. These complexes show metal-to-ligand charge transfer absorption at 445-454 nm and emission at 575592 nm. (c) 2008 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2008.05.003