11-(4-methoxyphenyl)benzofuro[3,2-b]carbazole | 1015076-91-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并呋喃
• 英文名称: 11-(4-methoxyphenyl)benzofuro[3,2-b]carbazole
• 英文别名: 11-(4-Methoxyphenyl)-[1]benzofuro[3,2-b]carbazole
• CAS: 1015076-91-1
• 化学式: C₂₅H₁₇NO₂
• 分子量: 363.415
• InChiKey: WCYLYUBBYKNMOV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.7
• 重原子数：
  28
• 可旋转键数：
  2
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.04
• 拓扑面积：
  27.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  11-(4-methoxyphenyl)benzofuro[3,2-b]carbazole 在 三溴化硼 作用下， 以 二氯甲烷 为溶剂， 反应 6.0h， 生成 11-(4-hydroxyphenyl)benzofuro[3,2-b]carbazole
  参考文献：
  名称：

  Synthesis, Structures, and Properties of Unsymmetrical Heteroacenes Containing Both Pyrrole and Furan Rings

  摘要：

  Unsymmetrical heteroacenes, 11-phenylbenzofuro[3;2-b]carbazole (Ph-BFC) and its alkoxylated derivatives, were readily synthesized by palladium-catalyzed double N-arylation of arylamines. They characteristically form antiparallel cofacial pi-stacking arrangements, which may result from their unsymmetrical structures. Their physical properties show their potential for application as active layers in organic field-effect transistors.

  DOI：

  10.1021/ol703110g
• 作为产物：
  描述：

  2-(trifluoromethansulfonyloxy)-3-[2-(trifluoromethansulfonyloxy)phenyl]-dibenzofuran 、 甲氧苯胺 在 potassium phosphate 、 bis(dibenzylideneacetone)-palladium⁽⁰⁾ 、 2-二环己基磷-2',6'-二异丙氧基-1,1'-联苯 作用下， 以 甲苯 为溶剂， 反应 72.0h， 以72%的产率得到11-(4-methoxyphenyl)benzofuro[3,2-b]carbazole
  参考文献：
  名称：

  Synthesis, Structures, and Properties of Unsymmetrical Heteroacenes Containing Both Pyrrole and Furan Rings

  摘要：

  Unsymmetrical heteroacenes, 11-phenylbenzofuro[3;2-b]carbazole (Ph-BFC) and its alkoxylated derivatives, were readily synthesized by palladium-catalyzed double N-arylation of arylamines. They characteristically form antiparallel cofacial pi-stacking arrangements, which may result from their unsymmetrical structures. Their physical properties show their potential for application as active layers in organic field-effect transistors.

  DOI：

  10.1021/ol703110g