(OC-6-11)六氟代锑酸(1-)钠

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 碱金属盐
• 中文名称: (OC-6-11)六氟代锑酸(1-)钠
• 中文别名: 六氟锑(V)酸钠；六氟锑酸钠；六氟代锑酸钠
• 英文名称: sodium;antimony(5+);hexafluoride
• 化学式: F6NaSb
• 分子量: 258.74
• InChiKey: HKLMYZVMEYYVBS-UHFFFAOYSA-H

计算性质

• 辛醇/水分配系数(LogP)：
  -21.35
• 重原子数：
  8
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  Dibenzylsulfonium tetrafluoroborate 、 (OC-6-11)六氟代锑酸(1-)钠 在 氮气 、 silica gel 、 甲醇 、 水 作用下， 以 二氯甲烷 为溶剂， 反应 20.0h， 以163.9 g (95% of theory) of dibenzylphenylsulfonium hexafluoroantimonate are obtained as white crystals of melting point 105°-109° C.的产率得到dibenzylphenylsulfonium hexafluoroantimonate
  参考文献：
  名称：

  Thermosetting mixtures utilizing araliphatic sulfonium salts

  摘要：

  含有(a)平均分子中含有多于一个1,2-环氧基团的环氧树脂，(b)二元或多元异氰酸酯化合物和(c)式I至IV的磺酸盐混合物：##STR1## 其中A是C.sub.1-C.sub.12烷基，C.sub.3-C.sub.8环烷基，C.sub.4-C.sub.10环烷基烷基或苯，未取代或取代于C.sub.1-C.sub.8烷基，C.sub.1-C.sub.4烷氧基，卤素，硝基，苯基，苯氧基，烷氧基中烷氧基中含有1-4个碳原子或含有1-12个碳原子的丙烯酰基中的一种或多种取代基；Ar，Ar.sub.1和Ar.sub.2各自独立地是未取代或取代于C.sub.1-C.sub.8烷基，C.sub.1-C.sub.4烷氧基，卤素，硝基，苯基，苯氧基，烷氧基中烷氧基中含有1-4个碳原子和含有1-12个碳原子的酰基中的一种或多种取代基的苯基，或是未取代或取代于C.sub.1-C.sub.8烷基，C.sub.1-C.sub.4烷氧基，卤素，硝基，苯基，苯氧基，烷氧基中烷氧基中含有1-4个碳原子和含有1-12个碳原子的酰基中的一种或多种取代基的萘基；芳撑基在每种情况下是未取代或取代于C.sub.1-C.sub.8烷基，C.sub.1-C.sub.4烷氧基，卤素，硝基，苯基，苯氧基，烷氧基中烷氧基中含有1-4个碳原子和含有1-12个碳原子的酰基中的一种或多种取代基的苯撑基，或是未取代或取代于C.sub.1-C.sub.8烷基，C.sub.1-C.sub.4烷氧基，卤素，硝基，苯基，苯氧基，烷氧基中烷氧基中含有1-4个碳原子和含有1-12个碳原子的酰基中的一种或多种取代基的萘撑基，Q.sup..crclbar.是SbF.sub.6.sup..crclbar.，AsF.sub.6.sup..crclbar.或SbF.sub.5 OH.sup..crclbar.的磺酸盐，热固化后可形成高交联密度和高耐热性的模塑材料。

  公开号：

  US05149767A1
• 作为产物：
  描述：

  sodium fluoride 、 三氟化锑 生成 (OC-6-11)六氟代锑酸(1-)钠
  参考文献：
  名称：

  MOTIDA, JOSIXARU;TATEHNO, JOSIO;KAVADZAVA, JOSIO;KAVAMURA, KADZUO

  摘要：

  DOI：

文献信息

• Non-toxic aryl onium salts, UV curable coating compositions and food
  申请人：General Electric Company

  公开号：US04981881A1

  公开（公告）日：1991-01-01

  A method is provided for coating a substrate with a non-toxic irradiation curable epoxy resin composition. There is used an alkoxy-substituted aryl onium salt, in combination with a non-toxic oxirane-containing organic or silicone resin.

  提供了一种用无毒辐射固化环氧树脂组合物涂覆基底的方法。使用了烷氧基取代的芳基烯鎓盐，结合无毒环氧基含有机或有机硅树脂。
• Araliphatic sulfonium and their use
  申请人：Ciba-Geigy Corporation

  公开号：US05247113A1

  公开（公告）日：1993-09-21

  Sulfonium salts of the formulae I to IV ##STR1## in which A is C.sub.1 -C.sub.12 alkyl, C.sub.3 -C.sub.8 cycloalkyl, C.sub.4 -C.sub.10 cycloalkylalkyl, phenyl which is unsubstituted or mono- or polysubstituted by C.sub.1 -C.sub.8 alkyl, C.sub.1 -C.sub.4 alkoxy, halogen, nitro, phenyl, phenoxy, alkoxycarbonyl having 1-4 C atoms in the alkoxy radical or acyl having 1-12 C atoms, Ar, Ar.sup.1 and Ar.sup.2, independently of one another, are each unsubstituted or mono- or polysubstituted phenyl, or naphthyl which is unsubstituted or mono- or polysubstituted each arylene is an unsubstituted or mono- or polysubstituted phenylene or unsubstituted or mono- or polysubstituted naphthylene and Q.sup..crclbar. is SbF.sub.6.sup.-, AsF.sub.6.sup.- or SbF.sub.5 OH.sup.- are valuable curing agents and curing accelerators in the heat-curing of cationically polymerizable compounds, preferably epoxy resins.

  式I至IV的磺鎵鹽 ##STR1## 其中A为C.sub.1-C.sub.12烷基，C.sub.3-C.sub.8环烷基，C.sub.4-C.sub.10环烷基烷基，苯基，未取代或经C.sub.1-C.sub.8烷基，C.sub.1-C.sub.4烷氧基，卤素，硝基，苯基，苯氧基，具有1-4个C原子的烷氧基基团或具有1-12个C原子的酰基取代的苯基；Ar，Ar.sup.1和Ar.sup.2，彼此独立，均为未取代或经C.sub.1-C.sub.8烷基，C.sub.1-C.sub.4烷氧基，卤素，硝基，苯基，苯氧基，具有1-4个C原子的烷氧基基团或具有1-12个C原子的酰基取代的苯基，或未取代或经单或多取代的萘基；每个芳基均为未取代或经单或多取代的苯基或未取代或经单或多取代的萘基，Q.sup..crclbar.为SbF.sub.6.sup.-，AsF.sub.6.sup.-或SbF.sub.5 OH.sup.-是有价值的固化剂和固化促进剂，在阳离子聚合化合物的热固化中，优选用于环氧树脂。
• Araliphatic sulfonium salts and their use
  申请人：Ciba-Geigy Corporation

  公开号：US05013814A1

  公开（公告）日：1991-05-07

  Sulfonium salts of the formulae I to IV ##STR1## in which A is C.sub.1 -C.sub.12 alkyl, C.sub.3 -C.sub.8 cycloalkyl, C.sub.4 -C.sub.10 cycloalkylalkyl, phenyl which is unsubstituted or mono- or polysubstituted by C.sub.1 -C.sub.8 alkyl, C.sub.1 -C.sub.4 alkoxy, halogen, nitro, phenyl, phenoxy, alkoxycarbonyl having 1-4 C atoms in the alkoxy radical or acyl having 1-12 C atoms, Ar, Ar.sup.1 and Ar.sup.2, independently of one another, are each unsubstituted or mono- or polysubstituted phenyl, or naphthyl which is unsubstituted or mono- or polysubstituted each arylene is an unsubstituted or mono- or polysubstituted phenylene or unsubstituted or mono- or polysubstituted naphthylene and Q.sup..crclbar. is SbF.sub.6 --, AsF.sub.6 -- or SbF.sub.5 OH-- are valuable curing agents and curing accelerators in the heat-curing of cationically polymerizable compounds, preferably epoxy resins.

  公式I至IV的磺鎵鹽##STR1##其中A是C.sub.1-C.sub.12烷基，C.sub.3-C.sub.8环烷基，C.sub.4-C.sub.10环烷基烷基，苯基，其未经取代或经C.sub.1-C.sub.8烷基，C.sub.1-C.sub.4烷氧基，卤素，硝基，苯基，苯氧基，烷氧羰基在烷氧基基团中具有1-4个C原子或酰基在1-12个C原子中，Ar，Ar.sup.1和Ar.sup.2，独立于彼此，均为未经取代或经C.sub.1-C.sub.8烷基，C.sub.1-C.sub.4烷氧基，卤素，硝基，苯基，苯氧基，烷氧羰基在烷氧基基团中具有1-4个C原子或酰基在1-12个C原子中的苯基，或未经取代或经C.sub.1-C.sub.8烷基，C.sub.1-C.sub.4烷氧基，卤素，硝基，苯基，苯氧基，烷氧羰基在烷氧基基团中具有1-4个C原子或酰基在1-12个C原子中的萘基，且每个芳基均未经取代或经C.sub.1-C.sub.8烷基，C.sub.1-C.sub.4烷氧基，卤素，硝基，苯基，苯氧基，烷氧羰基在烷氧基基团中具有1-4个C原子或酰基在1-12个C原子中，Q.sup..crclbar.是SbF.sub.6--，AsF.sub.6--或SbF.sub.5OH--在阳离子聚合化合物的热固化中是有价值的固化剂和固化加速剂，优选为环氧树脂。
• Heat-latent, cationic polymerization initiator and resin compositions
  申请人：Nippon Paint Co., Ltd.

  公开号：US05070161A1

  公开（公告）日：1991-12-03

  Benzyl pyridinium or ammonium salts of a non-nucleophilic anion are useful as a cationic polymerization initiator having a heat latency. A variety of resinous compositions containing this initiator is also disclosed.

  苄基吡啶或铵盐与非亲核阴离子结合后，可用作具有热潜伏期的阳离子聚合引发剂。本发明还揭示了包含该引发剂的各种树脂组合物。
• Materials, methods, and uses for photochemical generation of acids and/or radical species
  申请人：Marder Seth

  公开号：US20050173683A1

  公开（公告）日：2005-08-11

  The present invention provides compounds and compositions, which include: at least one chromophore having strong simultaneous two-photon or multi-photon absorptivity; at least one acid- or radical-generator in close proximity to the chromophore; such that the single- or multi-photon excitation of the chromophore results in the generation of an acid and/or redical that is capable of activating chemistry; and such that compositions of matter based on the componds and compositions of the invention can be photo-patterned by one- or multiphoton excitation.

  本发明提供了化合物和组合物，其中包括：至少一种具有强烈的同时双光子或多光子吸收性的色团；至少一个与色团相邻的酸或自由基发生剂；这样，色团的单光子或多光子激发会产生能够激活化学反应的酸和/或自由基；并且基于该发明的化合物和组合物的物质组成可以通过单光子或多光子激发进行光图案化。