standard enthalpies of formation of crystalline Cs[ICl2] and Rb[ICl2] have been determined as –511.1 ± 4.1 and –491.4 ± 4.1 kJ mol–1 respectively, based on enthalpies of reaction with aqueous silver(I) nitrate. The results are discussed in relation to various thermodynamic parameters.
基于与
硝酸银(I)
水溶液反应的焓,晶体Cs [ICl 2 ]和Rb [ICl 2 ]的形成标准焓分别确定为–511.1±4.1和–491.4±4.1 kJ mol –1。讨论了有关各种热力学参数的结果。