双氟磺酰亚胺钾盐 | 14984-76-0

• 物质功能分类: 化学试剂 - 有机试剂 - 酰胺
• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 碱金属盐
• 中文名称: 双氟磺酰亚胺钾盐
• 英文名称: potassium bis(fluorosulfuryl)amide
• 英文别名: potassium bis(fluorosulfonyl)imide；potassium bis(fluorosulfonyl)amide；KFSI；bis(fluorosulfonyl)imide potassium salt；potassium di(fluorosulfonyl)imide；potassium bisfluorosulfonimide；K[bis(fluorosulfonyl)amide]；K[FSA]；potassium;bis(fluorosulfonyl)azanide
• CAS: 14984-76-0
• 化学式: F₂NO₄S₂*K
• mdl: MFCD17018950
• 分子量: 219.231
• InChiKey: MHEBVKPOSBNNAC-UHFFFAOYSA-N

物化性质

• 熔点：
  102℃

计算性质

• 辛醇/水分配系数(LogP)：
  -0.86
• 重原子数：
  10
• 可旋转键数：
  2
• 环数：
  0.0
• sp3杂化的碳原子比例：
  -2147483.648
• 拓扑面积：
  86
• 氢给体数：
  0
• 氢受体数：
  7

安全信息

• 危险等级：
  8
• 危险品运输编号：
  UN 1759
• 包装等级：
  II
• 危险类别：
  8
• 危险性防范说明：
  P260,P280,P303+P361+P353,P301+P330+P331,P304+P340+P310,P305+P351+P338+P310
• 危险性描述：
  H314
• 储存条件：
  储存条件：2-8°C，避光，并保存在氮气中。

SDS

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Section 1: Product Identification
Chemical Name: Potassium bis(fluorosulfonyl)imide, 99.5+%
CAS Registry Number: 14984-76-0
Formula: K[N(SO2F)2]
EINECS Number: none
Chemical Family: metal imide compound
Synonym: none

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Section 2: Composition and Information on Ingredients
Ingredient CAS Number Percent ACGIH (TWA) OSHA (PEL)
Title compound 14984-76-0 100% 2.5mg/m3 (as F) 2.5mg/m3 (as F)

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Section 3: Hazards Identification
Emergency Overview: Irritating to skin, eyes and respiratory tract. May be harmful if swallowed.
Primary Routes of Exposure: Ingestion, inhalation
Eye Contact: Causes slight to mild irritation of the eyes.
Skin Contact: Causes slight to mild irritation of the skin.
Inhalation: Irritating to the nose, mucous membranes and respiratory tract.
Ingestion: No information available on the physiological effects of ingestion. May be harmful if swallowed.
Acute Health Affects: Irritating to skin, eyes and respiratory tract.
No information on long-term chronic effects. Product contains fluorine which, under certain conditions of use,
Chronic Health Affects: decomposition or metabolism, may generate fluoride ion causing nausea, vomiting, labored breathing,
hypocalcaemia, deterioration of bone and tooth structure and kidney and liver damage.
NTP: No
IARC: No
OSHA: No

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SECTION 4: First Aid Measures
Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
Eye Exposure:
assistance in keeping their eye lids open. Get immediate medical attention.
Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
Skin Exposure:
irritation persists.
Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
Inhalation:
in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
Ingestion:
vomiting only if directed by medical personnel.

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SECTION 5: Fire Fighting Measures
Flash Point: no data
Autoignition Temperature: no data
Explosion Limits: no data
Extinguishing Medium: carbon dioxide, dry powder or foam
If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure
Special Fire Fighting Procedures:
self-contained breathing apparatus and full protective clothing.
Hazardous Combustion and If involved in a fire this material may emit irritating fumes.
Decomposion Products:
Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

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SECTION 6: Accidental Release Measures
Small spills can be mixed with vermiculite, sodium carbonate or other suitable non-combustible adsorbent and
Spill and Leak Procedures:
swept up.

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SECTION 7: Handling and Storage
Store in a tightly sealed container under an inert atmosphere of nitrogen or argon. Keep in a cool, dry,
Handling and Storage:
well-ventilated place.

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SECTION 8: Exposure Controls and Personal Protection
Eye Protection: Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection: Wear protective clothing and gloves.
Ventilation: Handle the material in an efficient fume hood.
If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
Respirator:
Protection Program to be in compliance with 29 CFR 1910.134.
Ventilation: Handle the material in an efficient fume hood.
Additional Protection: No additional protection required.

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SECTION 9: Physical and Chemical Properties
Color and Form: white pwdr
Molecular Weight: 219.23
Melting Point: no data
Boiling Point: no data
Vapor Pressure: no data
Specific Gravity: no data
Odor: none
Solubility in Water: insoluble

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SECTION 10: Stability and Reactivity
Stability: moisture sensitive
Hazardous Polymerization: no hazardous polymerization
Conditions to Avoid: prolonged exposure to moisture
Incompatibility: oxidizing agents and active metals
Decomposition Products: carbon monoxide, carbon dioxide, sulfur dioxide, fluorinated by-products and organic fumes.

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SECTION 11: Toxicological Information
RTECS Data: No information available in the RTECS files.
Carcinogenic Effects: no data
Mutagenic Effects: no data
Tetratogenic Effects: no data

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SECTION 12: Ecological Information
Ecological Information: No information available

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SECTION 13: Disposal Considerations
Disposal: Dispose of according to local, state and federal regulations.

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SECTION 14: Transportation
Shipping Name (CFR): Non-hazardous
Hazard Class (CFR): NA
Additional Hazard Class (CFR): NA
Packaging Group (CFR): NA
UN ID Number (CFR): NA
Shipping Name (IATA): Non-hazardous
Hazard Class (IATA): NA
Additional Hazard Class (IATA): NA
Packaging Group (IATA): NA
UN ID Number (IATA): NA

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SECTION 15: Regulatory Information
TSCA: Not listed in the TSCA inventory
SARA (Title 313): Not reportable under SARA 313
Second Ingredient: none

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SECTION 16 - ADDITIONAL INFORMATION
N/A

制备方法与用途

近年来，双氟磺酰亚胺钾在熔盐电池、硬涂膜、导电膜以及抗静电粘结剂上的应用引起了广泛关注。

制备方法 1. 双氯磺酰亚胺的制备

在1000mL反应瓶中，加入478.6g氯磺酸和2.1g NiCl₂，开启搅拌后，升温至105～115℃。随后滴加679.2g氯磺酰异氰酸酯。滴加完毕后，逐步升温至130～140℃，继续搅拌反应20小时。减压蒸馏收集到稳定馏分738g，收率83.9％。产品为白色固体，熔点约为36℃。

2. 双氟磺酰亚胺钾盐的制备

在500mL反应瓶中，加入220g乙酸乙酯和69.1g K₂CO₃，控温至20～30℃。搅拌下滴加90.6g HFSI(实施例2制备)。继续在20～30℃下搅拌反应4小时后，过滤滤液减压脱溶浓缩。当瓶内固含量超过50％时，向浓缩物中加入450g二氯甲烷，经过滤、干燥处理后得产品105.1g，收率95.9％。该产品为白色固体，熔点范围为98-100℃。

反应信息

• 作为反应物：
  描述：

  双氟磺酰亚胺钾盐 以 water, 1,3-dimethyl-1-propylpyrrolidinium bromide 、 水 为溶剂， 生成 1,3-dimethyl-1-propylpyrrolidinium bis(fluorosulfonyl)amide
  参考文献：
  名称：

  IONIC LIQUID AND POWER STORAGE DEVICE INCLUDING THE SAME

  摘要：

  一种具有高电化学稳定性和低熔点的离子液体。提供以下一般公式（G0）表示的离子液体。在一般公式（G0）中，R0到R5分别是具有1至20个碳原子的烷基基团、甲氧基、甲氧甲基基团、甲氧乙基基团和氢原子中的任意一种，而A-是一价亚胺基阴离子、一价甲基基阴离子、全氟烷基磺酸阴离子、四氟硼酸盐或六氟磷酸盐。

  公开号：

  US20120308882A1
• 作为产物：
  描述：

  bis(fluorosulfonyl)imide ammonium salt 在 potassium hydroxide 作用下， 以 乙酸丁酯 、 水 为溶剂， 37.0 ℃ 、8.67 kPa 条件下， 反应 1.0h， 以1.93 g的产率得到双氟磺酰亚胺钾盐
  参考文献：
  名称：

  PRODUCTION PROCESS FOR FLUOROSULFONYLIMIDE AMMONIUM SALT

  摘要：

  通过将化合物[I]，如N,N-二(氯磺酰)亚胺和NH4F (HF)p反应，可以得到类似氨基N,N-二(氟磺酰)亚胺的化合物[II]。通过将得到的化合物[II]与碱金属化合物等反应，可以得到类似N,N-二(氟磺酰)亚胺碱金属盐的化合物[IV]。

  公开号：

  US20130331609A1
• 作为试剂：
  描述：

  四丙基溴化铵 在 双氟磺酰亚胺钾盐 作用下， 以 水 为溶剂， 生成 bis(fluorosulfonyl)imide tetrapropylammonium salt
  参考文献：
  名称：

  Method for producing bis(fluorosulfonyl)imide salt, method for producing fluorosulfate, and method for producing bis(fluorosulfonyl)imide onium salt

  摘要：

  根据本发明的生产双(氟磺酰)亚胺盐的方法，生产氟磺酸盐的方法以及生产双(氟磺酰)亚胺酸盐的方法，首先，通过将含有双(氟磺酰)亚胺和氟磺酸的混合液溶解在水中制备出一种水溶液。然后，用碱性化合物对这种水溶液进行中和，产生双(氟磺酰)亚胺盐和氟磺酸盐。在这些方法中，可以安全、容易地获得双(氟磺酰)亚胺盐、氟磺酸盐和双(氟磺酰)亚胺酸盐。

  公开号：

  US09156692B2

文献信息

• Silylated quaternary ammonium salts – ionic liquids with hydrophobic cations
  作者：Matjaž Koželj、Abdelbast Guerfi、Karim Zaghib

  DOI：10.1039/c4ta02675f

  日期：——

  class of ionic liquids was obtained by a combination of bis(perfluoroalkylsulfonyl)amide anions and O-silylated choline like cations. The protection of the hydrophilic hydroxyl group of hydroxyalkyl substituted quaternary ammonium salts with a trialkylsilyl group changes cations' properties from hydrophilic to hydrophobic; both constituents (cations and anions) of resulting ionic liquids have a hydrophobic

  通过双（全氟烷基磺酰基）酰胺阴离子和O-甲硅烷基化的胆碱样阳离子的组合获得另一类离子液体。具有三烷基甲硅烷基的羟烷基取代的季铵盐的亲水羟基的保护将阳离子的性质从亲水变为疏水。所得离子液体的两种成分（阳离子和阴离子）均具有疏水性。研究了它们的基本物理和化学性质。离子液体的中等粘度和电导率遵循它们对温度的依赖性的Vogel-Tammann-Fulcher模型。所有离子液体均显示出与CV测量所预期的相似的电化学稳定性。相对于Li / Li ，大多数化合物的阴极稳定性低于0 V+，并且与Li / Li +相比，阳极分解通常会在超过5 V的条件下开始。这些性质表明，这些离子液体具有制备高压锂电池电解液的潜力。
• IONIC COMPOUNDS HAVING A SILYLOXY GROUP
  申请人：HYDRO-QUÉBEC

  公开号：US20150093655A1

  公开（公告）日：2015-04-02

  There is provided an ionic compound having attached thereto a silyloxy group. There is also provided methods of making this ionic compound as well as electrolytes, electrochemical cells and capacitors comprising this ionic compound.

  提供了一种具有硅氧基团的离子化合物。还提供了制备该离子化合物的方法，以及包含该离子化合物的电解质、电化学电池和电容器。
• 一种磺酰亚胺类金属盐、其制备方法及应用
  申请人：中国科学院上海有机化学研究所

  公开号：CN113321669B

  公开（公告）日：2023-03-24

  本发明公开了一种磺酰亚胺类金属盐、其制备方法及应用。本发明提供了一种式I或式II的磺酰亚胺类金属盐；其中，所述的式I的磺酰亚胺类金属盐为如式I‑1所示的磺酰亚胺类金属盐和/或如式I‑2所示的磺酰亚胺类金属盐；所述的式II的磺酰亚胺类金属盐为如式II‑1所示的磺酰亚胺类金属盐和/或如式II‑2所示的磺酰亚胺类金属盐。本发明的磺酰亚胺类金属盐，其制备方法，具有反应条件温和，产率高，后处理简单等优点；其作为催化剂具有较好的催化效果。
• [DE] VERFAHREN ZUR HERSTELLUNG VON GUANIDINIUM-SALZEN<br/>[EN] METHOD FOR PRODUCING GUANIDINIUM SALTS<br/>[FR] PROCEDE DE PRODUCTION DE SELS DE GUANIDINIUM
  申请人：MERCK PATENT GMBH

  公开号：WO2005075413A1

  公开（公告）日：2005-08-18

  Die vorliegende Erfindung betrifft ein zweistufiges Verfahren zur Herstellung von Guanidinium-Salzen der Formel (1), wobei die Substituenten R eine in Anspruch 1 angegebene Bedeutung haben und A- ein Sulfonat, Alkyl- oder Aryl-Sulfat, Hydrogensulfat, Imid, Methanid, Carboxylat, Phosphat, Phosphinat, Phosphonat, Borat, Thiocyanat, Perchlorat, Fluorsilikat oder Nitrat ist, sowie Zwischenverbindungen aus diesem Verfahren.

  This invention relates to a two-step process for the production of guanidinium salts of formula (1), wherein the substituents R have the meaning as defined in claim 1 and A- is a sulfonate, alkyl or aryl sulfate, hydrogen sulfate, imide, methanide, carboxylate, phosphate, phosphinate, phosphonate, borate, thiocyanate, perchlorate, fluorosilicate, or nitrate, as well as intermediates from this process.
• SULFAMIC ACID DERIVATIVES AND PROCESSES FOR THEIR PREPARATION
  申请人：HYDRO-QUÉBEC

  公开号：US20200181071A1

  公开（公告）日：2020-06-11

  Here are described processes for the preparation of sulfamic acid derivatives, for instance, halogenated derivatives and their metallic or organic salts. The present document also describes the sulfamic acid derivatives thus produced and to their uses, for instance, in electrolyte compositions for electrochemical applications.

  这里描述了制备磺酰胺酸衍生物的过程，例如卤代衍生物及其金属或有机盐。本文件还描述了因此制得的磺酰胺酸衍生物及其用途，例如在电化学应用的电解质组成中的用途。