1,4-二氮杂双环[2.2.2]辛-2-基甲基乙酸酯 | 120340-35-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二嗪烷类
• 中文名称: 1,4-二氮杂双环[2.2.2]辛-2-基甲基乙酸酯
• 英文名称: 2-acetoxymethyl-1,4-diazabicyclo<2.2.2>octane
• 英文别名: (1,4-Diazabicyclo[2.2.2]octan-2-yl)methyl acetate；1,4-diazabicyclo[2.2.2]octan-2-ylmethyl acetate
• CAS: 120340-35-4
• 化学式: C₉H₁₆N₂O₂
• 分子量: 184.238
• InChiKey: RTIGOAJWDGQRBX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.2
• 重原子数：
  13
• 可旋转键数：
  3
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.89
• 拓扑面积：
  32.8
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  甲基1,4-二氮杂双环[2.2.2]辛烷-2-羧酸酯 在 lithium aluminium tetrahydride 作用下， 以 四氢呋喃 为溶剂， 反应 65.5h， 生成 1,4-二氮杂双环[2.2.2]辛-2-基甲基乙酸酯
  参考文献：
  名称：

  二氮杂双环烷烃在节点位置具有氮原子。5. 2-羟甲基-1,4-二氮杂双环[2.2.2]辛烷的合成及一些反应

  摘要：

  DOI：

  10.1007/bf00496614

文献信息

• VERFAHREN ZUR HERSTELLUNG VON TEDA-DERIVATEN
  申请人：BASF SE

  公开号：EP2197882A2

  公开（公告）日：2010-06-23
• METHOD FOR PRODUCING TEDA DERIVATIVES
  申请人：Cauwenberge Gunther Van

  公开号：US20100204438A1

  公开（公告）日：2010-08-12

  The present invention relates to a process for preparing triethylenediamine (TEDA) derivatives, comprising the following steps: a) reacting a dihydropyrazine with an olefin, b) if appropriate hydrogenating after step a). The present invention further also relates to novel TEDA derivatives as such and to their use as incorporable polyurethane catalysts.
• METHOD OF PRODUCING AMMONIUM SALT COMPOUND, METHOD OF PRODUCING COMPOUND, AND COMPOUND, POLYMERIC COMPOUND, ACID GENERATOR, RESIST COMPOSITION AND METHOD OF FORMING RESIST PATTERN
  申请人：c/o Tokyo Ohka Kogyo Co., Ltd.

  公开号：US20140017617A1

  公开（公告）日：2014-01-16

  A method of producing an ammonium salt compound, including reacting a first ammonium salt compound containing a first ammonium cation which is a primary, secondary or tertiary ammonium cation with a nitrogen-containing compound having a lone pair to obtain a second ammonium salt compound which contains a conjugated acid of the nitrogen-containing compound, the conjugated acid of the nitrogen-containing compound having a larger pKa than the pKa of the first ammonium cation; and a method of producing a compound, including a step of salt exchange between the ammonium salt compound obtained by the aforementioned production method and a sulfonium cation or iodonium cation which has a higher hydrophobicity than the hydrophobicity of the conjugated acid of the nitrogen-containing compound.
• US9075304B2
  申请人：——

  公开号：US9075304B2

  公开（公告）日：2015-07-07
• [DE] VERFAHREN ZUR HERSTELLUNG VON TEDA-DERIVATEN<br/>[EN] METHOD FOR PRODUCING TEDA DERIVATIVES<br/>[FR] PROCÉDÉ DE PRODUCTION DE DÉRIVÉS TEDA
  申请人：BASF SE

  公开号：WO2009030649A2

  公开（公告）日：2009-03-12

  Die vorliegende Erfindung betrifft ein Verfahren zur Herstellung von Triethylendiamin- (TEDA)-Derivaten umfassend die folgenden Schritte: a) Reaktion eines Dihydropyrazins mit einem Olefin, b) gegebenenfalls eine Hydrierung in Anschluss an Schritt a). Weiterhin betrifft die vorliegende Erfindung auch neue TEDA-Derivate als solche sowie deren Verwendung als einbaubare Polyurethan-Katalysatoren.