N-(5-羟基-1-萘基)甲烷磺酰胺 | 54179-49-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 中文名称: N-(5-羟基-1-萘基)甲烷磺酰胺
• 英文名称: N-(5-Hydroxy-1-naphthyl)methansulfonamid
• 英文别名: 5-(N-methanesulphonyl)-amino-1-naphthol；5-methanesulfonylamino-1-naphthol；5-methylsulfonamido-1-naphthol；Methanesulfonamide, N-(5-hydroxy-1-naphthalenyl)-；N-(5-hydroxynaphthalen-1-yl)methanesulfonamide
• CAS: 54179-49-6
• 化学式: C₁₁H₁₁NO₃S
• mdl: MFCD18970961
• 分子量: 237.279
• InChiKey: YKCHZHCCPAEVIN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.1
• 重原子数：
  16
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.09
• 拓扑面积：
  74.8
• 氢给体数：
  2
• 氢受体数：
  4

安全信息

• 海关编码：
  2935009090

反应信息

• 作为反应物：
  描述：

  N-(5-羟基-1-萘基)甲烷磺酰胺 生成 2-Nitroso-5-methanesulfonylamino-1-naphthol
  参考文献：
  名称：

  TSUKASEH, MASAAKI;SATO, KODZO

  摘要：

  DOI：
• 作为产物：
  描述：

  1-氨基-5-萘酚 、 甲基磺酰氯 在 吡啶 作用下， 以36 %的产率得到N-(5-羟基-1-萘基)甲烷磺酰胺
  参考文献：
  名称：

  卤代炔双亲核加成和 C−H 环化制备杂 π 共轭化合物

  摘要：

  当混合物含有 1-halo-1-alkyne、双亲核试剂和碱（Cs2CO3 或 K3PO< sub>4)在DMF中加热，发生二亲核试剂与乙炔的区域和立体选择性亲核加成。该反应产生了 (Z,Z)-双(卤代烯烃)，随后通过 Pd 催化环化C-H键活化，导致形成含双氧或双氮的杂π共轭化合物。 N-(5-羟基萘-1-基)甲磺酰胺先用 2-苯基-1-氯乙炔处理，然后用 1-氯-1-十六炔处理。经过这些反应，Pd催化的双C-H环化反应生成1H-2-苯基-7-十四烷基苯并呋喃[7,6-]吲哚。值得注意的是，该化合物在 86 °C 时转变为扇形结构，并转变为以层状结构为特征的近晶 A 相。

  DOI：

  10.1002/adsc.202301510

文献信息

• Magenta image-providing phenylazo-naphthyl dyes
  申请人：Eastman Kodak Company

  公开号：US03932381A1

  公开（公告）日：1976-01-13

  Magenta image dye-providing compound having formulas as follows: ##SPC1## Wherein: Car represents a carrier moiety which, as a function of oxidation under alkaline conditions, releases a diffusible dye from said compound; m and q each represent an integer having a value of 0 or 1; X represents a bivalent linking group; R represents hydrogen or alkyl; J represents a bivalent radical selected from sulfonyl or carbonyl; Q represents hydrogen, hydroxy or an acylamino radical; G represents hydroxy, a salt thereof, or a hydrolyzable acyloxy group; r represents an integer having a value of 1 or 2; Z represents cyano, trifluoromethyl, a carboxy, a carboxylic acid ester, nitro in the 2- or 3- position relative to the azo radical, fluorosulfonyl, sulfo, halogen, an alkylsulfonyl radical; a phenylsulfonyl radical, alkylcarbonyl, a sulfamoyl radical; a carbamoyl radical, and, in formulas I or II when r is 1, Z may represent a radical having the formula Car-[X--(NR--J).sub.q ].sub.m -- wherein Car, X, J, R, q and m are as described previously; R.sup.1 represents hydrogen, an alkyl radical, an alkoxy radical or a halogen atom; E is in the 5-, 6- or 7- position relative to G and represents hydrogen, carboxy, a carboxylic acid ester, sulfo, a sulfamoyl radical, a carbamoyl radical, alkylsulfonyl radical or a phenylsulfonyl radical; Z.sup.1 represents hydrogen or Z; with the proviso that there be no more than one sulfo radical and no more than one carboxy radical present in said compound.

  蓝紫色图像染料提供化合物的化学式如下：其中：Car代表一个载体基团，根据碱性条件下的氧化作用，从该化合物中释放出可扩散的染料；m和q分别代表取值为0或1的整数；X代表双价连接基团；R代表氢或烷基；J代表从磺酰基或羰基中选择的双价基团；Q代表氢、羟基或酰胺基团；G代表羟基、其盐，或可水解的酰氧基团；r代表取值为1或2的整数；Z代表氰基、三氟甲基、一个羧基、一个羧酸酯、在与偶氮基团相对的2-或3-位上的硝基、氟磺酰基、磺酰基、卤素、一个烷基磺酰基团、苯基磺酰基团、烷基羰基、磺胺基、氨基基团；以及在化学式I或II中，当r为1时，Z可以表示具有化学式Car-[X--(NR--J).sub.q ].sub.m --的基团，其中Car、X、J、R、q和m如前所述；R.sup.1代表氢、烷基基团、烷氧基团或卤素原子；E位于与G相对的5-、6-或7-位上，表示氢、羧基、羧酸酯、磺酰基、磺胺基、羰基基团、烷基磺酰基团或苯基磺酰基团；Z.sup.1代表氢或Z；但前提是该化合物中不得有超过一个磺酰基团和一个羧基团。
• Positive-working immobile intramolecular nucleophilic displacement
  申请人：Eastman Kodak Company

  公开号：US04278598A1

  公开（公告）日：1981-07-14

  Novel photographic dye release compounds have the structure: ##STR1## wherein R.sup.1 is an aromatic group containing 5-7 members in the ring to which Nu and E are attached; R.sup.2 and R.sup.3 are bivalent organic groups containing from 1-3 atoms in the bivalent linkage which are alkylene, oxyalkylene or thiaalkylene; Nu is a nucleophilic group which is a hydrazine, an hydroxyamino, an hydroxy, a sulfonamido, a primary amino or alkali-labile precursors for said nucleophilic groups; E is an electrophilic group which is a carbonyl or a sulfonyl; Q is a bivalent group providing a mono atom linkage between E and X.sub.2 and is amino providing a mono atom nitrogen linkage, an oxygen atom, a sulfur atom or a selenium atom, provided that Nu and E are positioned on a ring of said aromatic group to provide for intramolecular formation of a 5- to 7-membered ring between Nu and E displacing Q--X.sub.2 from E; one of X.sup.1 or Q--X.sub.2 is a ballasting group containing at least 8 carbon atoms, which ballasting group is of a size sufficient to render said compound immobile in an alkaline solution-permeable layer of a photographic element; one of X.sup.1 or Q--X.sub.2 is an azo dye, an azomethine dye; an anthraquinone dye, an alizarin dye, a merocyanine dye, a quinoline dye or a cyanine dye; and n and m are integers of 1 or 2.

  新型的光敏染料释放化合物具有以下结构：##STR1## 其中R.sup.1是一个芳香族基团，包含5-7个成员，连接Nu和E的环上；R.sup.2和R.sup.3是双价的有机基团，含有1-3个原子的双键连接，可以是烷基，氧烷基或硫代烷基；Nu是一个亲核基团，可以是肼，羟基氨基，羟基，磺酰胺基，一级氨基或碱性易裂解的上述亲核基团的前体；E是一个电荷亲和基团，可以是羰基或磺酰基；Q是一个双价基团，提供E和X.sub.2之间的单原子键连接，并且可以是氨基提供单原子氮键连接，氧原子，硫原子或硒原子，前提是Nu和E位于所述芳香族基团的环上，以便在Nu和E之间形成5-到7-成员环，将Q-X.sub.2从E中取代；X.sup.1或Q-X.sub.2中的一个是含有至少8个碳原子的平衡基团，该平衡基团的大小足以使该化合物在光敏元素的碱性溶液渗透层中不动；X.sup.1或Q-X.sub.2中的一个是偶氮染料，偶氮亚甲基染料；蒽醌染料，茜素染料，美洛色染料，喹啉染料或青烷染料；n和m是1或2的整数。
• Betaine-type cyan monoazo dyes for dying and printing fibrous materials
  申请人：Fuji Photo Film Co., Ltd.

  公开号：US04956456A1

  公开（公告）日：1990-09-11

  The present invention is directed towards a betaine-type monoazo dye for dying and printing fibrous materials, represented by formula (I): Dye--X--Y (I) wherein Dye represents a cyan dye anion represented by formula (II); X represents a bond or linking group; Y represents quaternary ammonium; and Dye and X are bonded to each other via A, B.sup.1, B.sup.2, B.sup.3, B.sup.4 or B.sup.5 in formula (II): ##STR1## wherein B.sup.1, B.sup.2, B.sup.3, B.sup.4 and B.sup.5 are the same or different, and each represents a member selected from the group consisting of a bond, hydrogen, alkyl, halogen, --OR.sup.4, --CO.sub.2 R.sup.4, ##STR2## wherein R.sup.4 and R.sup.5 are the same or different and each represents a member selected from the group consisting of hydrogen, alkyl and aryl, or R.sup.4 and R.sup.5 are taken together to form 5- or 6-membered heterocyclic ring containing oxygen, nitrogen, sulfur or combinations thereof as heteroatoms; A represents a member selected from the group consisting of hydrogen, alkyl, aryl, cycloalkyl, a 5- or 6-membered heterocyclic ring containing oxygen, nitrogen, sulfur or combinations thereof as heteroatoms and ##STR3## wherein A.sup.2 and A.sup.3 have the same meaning as A, or A.sup.2 and A.sup.3 are bonded to each other to form a 5- or 6-membered heterocyclic ring containing oxygen, nitrogen, sulfur or combinations thereof as heteroatoms; E represents a member selected from the group consisting of hydrogen, halogen, cyano, hydroxyl, carboxyl, alkyl, aryl, a 5- or 6-membered heterocyclic ring containing oxygen, nitrogen, sulfur or combinations thereof as heteroatoms, alkoxy, aryloxy, alkylthio, arylthio, carbacylamino, sulfonylamino, carbamoyl, amino, alkylsulfonyl and phenylsulfonyl; G represents a member selected from the group consisting of cyano, alkylsulfonyl and phenylsulfonyl; J represents a member selected from the group consisting of hydrogen, halogen, cyano, alkylsulfonyl and phenylsulfonyl; and R.sup.1 represents a member selected from the group consisting of hydrogen and alkyl.

  本发明涉及一种用于染色和印刷纤维材料的甜菜碱型单偶氮染料，其表示为公式(I)：Dye--X--Y(I)，其中Dye表示公式(II)所表示的青色染料阴离子；X表示一个化学键或连接基团；Y表示季铵基团；而Dye和X通过公式(II)中的A、B.sup.1、B.sup.2、B.sup.3、B.sup.4或B.sup.5相互连接： ##STR1## 其中B.sup.1、B.sup.2、B.sup.3、B.sup.4和B.sup.5相同或不同，每个表示从羟基、氢、烷基、卤素、--OR.sup.4、--CO.sub.2R.sup.4、##STR2## 中选择的一种成员，其中R.sup.4和R.sup.5相同或不同，每个表示从氢、烷基和芳基中选择的一种成员，或R.sup.4和R.sup.5结合在一起形成含有氧、氮、硫或其组合的5-或6-成员杂环环；A表示从氢、烷基、芳基、环烷基、含氧、氮、硫或其组合的5-或6-成员杂环环和##STR3## 中选择的一种成员，其中A.sup.2和A.sup.3与A具有相同的含义，或A.sup.2和A.sup.3通过形成含有氧、氮、硫或其组合的5-或6-成员杂环环相互连接；E表示从氢、卤素、氰基、羟基、羧基、烷基、芳基、含氧、氮、硫或其组合的5-或6-成员杂环环、烷氧基、芳氧基、烷硫基、芳硫基、碳酰胺基、磺酰胺基、氨基、烷基磺酰基和苯基磺酰基中选择的一种成员；G表示从氰基、烷基磺酰基和苯基磺酰基中选择的一种成员；J表示从氢、卤素、氰基、烷基磺酰基和苯基磺酰基中选择的一种成员；而R.sup.1表示从氢和烷基中选择的一种成员。
• Color light-sensitive material
  申请人：FUJI PHOTO FILM CO., LTD.

  公开号：EP0143310A2

  公开（公告）日：1985-06-05

  A color light-sensitive material is described, comprising a support and at least one light-sensitive silver salt layer on the support, wherein the layer contains a dye-providing compound represented by the general formula (I): wherein all the symbols are as defined in the appended claims. This dye-providing compound provides a color image which is sharp and further is superior in light fastness.

  本发明描述了一种彩色光敏材料，它包括一个支撑体和至少一个位于支撑体上的光敏银盐层，其中银盐层含有一种由通式（I）表示的染料提供化合物：其中所有符号如所附权利要求中所定义。 这种染料提供化合物可提供清晰的彩色图像，而且耐光性更优。
• Hair dye composition comprising an azo dye containing a dissociative proton, method and use
  申请人：Kao Corporation

  公开号：EP1398020A1

  公开（公告）日：2004-03-17

  The present invention is directed to a hair dyeing composition comprising a dissociative azo dye of the following general formula (I)         A-N=N-B     (1)    wherein A represents a phenyl or naphthyl group, wherein these groups may be substituted, wherein these phenyl or naphthyl groups do not contain sulfo or carboxyl groups or quaternary ammonium groups; and B represents an aromatic group required for the compound represented by the general formula (I) to form a dissociative azo dye which is free from anionic sulfo or carboxyl groups and quaternary ammonium groups. Additionally, the present invention describes a method of dyeing human or animal hair by using such a dye and the use of this direct azo dye for dyeing human or animal hair. The use of this direct azo dye can impart the hair with an extremely vivid color and has a less color fade over the time.

  本发明涉及一种染发组合物，该组合物包含以下通式 (I) 的离解型偶氮染料 A-N=N-B (1) 其中 A 代表苯基或萘基，这些基团可以被取代，其中这些苯基或萘基不含有硫基或羧基或季铵基；B 代表芳香基团，这些芳香基团是通式(I)所代表的化合物形成不含阴离子硫基或羧基及季铵基的离解型偶氮染料所必需的。此外，本发明还介绍了使用这种染料染人或动物毛发的方法，以及使用这种直接偶氮染料染人或动物毛发的方法。使用这种直接偶氮染料可以赋予头发极其鲜艳的颜色，并且随着时间的推移褪色较少。