1-sek-Pentyl-naphthalin | 3042-56-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 1-sek-Pentyl-naphthalin
• 英文别名: 1-pentan-3-ylnaphthalene
• CAS: 3042-56-6
• 化学式: C₁₅H₁₈
• 分子量: 198.308
• InChiKey: FAZYYSYNXQVQNY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.7
• 重原子数：
  15
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  乙烯 、 1-sek-Pentyl-naphthalin 生成 1-(2-Butyl)-5-(3-pentyl)-naphthalin
  参考文献：
  名称：

  Base-catalyzed reactions. XXXIII. Sodium- and potassium-catalyzed reactions of methylnaphthalenes with ethylene

  摘要：

  DOI：

  10.1021/jo01259a017
• 作为产物：
  描述：

  甲基萘 生成 1-sek-Pentyl-naphthalin
  参考文献：
  名称：

  Base-catalyzed reactions. XXXIII. Sodium- and potassium-catalyzed reactions of methylnaphthalenes with ethylene

  摘要：

  DOI：

  10.1021/jo01259a017

文献信息

• 757. Alkylation of the aromatic nucleus. Part XIV. Naphthalene
  作者：M. Z. A. Badr、W. J. Hickinbottom

  DOI：10.1039/jr9650004101

  日期：——
• Transition metal promoted reactions. 38. NiCl2(dppe)-catalyzed geminal dialkylation of dithioacetals and trimethylation of ortho thioesters
  作者：Yih Ling Tzeng、Ping Fan Yang、Nai Wen Mei、Tien Min Yuan、Chun Chi Yu、Tien Yau Luh

  DOI：10.1021/jo00018a016

  日期：1991.8

  NiCl2(dppe)-catalyzed cross-coupling of cinnamaldehyde dithioacetals gave the corresponding geminal dimethylation products in excellent yields. Allylic ortho thioesters afforded regioselectively the corresponding trimethylation products. The reaction may occur via an 18-electron pi-allyl intermediate, which undergoes facile reductive elimination to afford the geminal dimethylation product. Benzylic dithioacetals having an ortho amino group gave 2-isopropylanilines exclusively. The reaction of benzylic dithioacetals with EtMgBr under the same conditions yielded geminal diethylation products.
• Reactions of aromatic radical anions. III. Evidence for an alkyl radical-radical anion combination mechanism for alkylation of sodium naphthalenide with alkyl halides
  作者：G. Dann Sargent、Glenn A. Lux

  DOI：10.1021/ja01027a068

  日期：1968.12
• Base-catalyzed reactions. XXXIII. Sodium- and potassium-catalyzed reactions of methylnaphthalenes with ethylene
  作者：Bozidar Stipanovic、Herman Pines

  DOI：10.1021/jo01259a017

  日期：1969.7