[Cu(2-[2'-carboxyphenylazo]-5,5-dimethyl-1,3-cyclohexanedione(-1H))(2-aminopyridine)2(NO3)]*CH3OH | 841233-29-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二嗪烷类
• 英文名称: [Cu(2-[2'-carboxyphenylazo]-5,5-dimethyl-1,3-cyclohexanedione(-1H))(2-aminopyridine)2(NO3)]*CH3OH
• CAS: 841233-29-2
• 化学式: CH₄O*C₂₅H₂₇CuN₇O₇
• 分子量: 633.12
• InChiKey: COLDHDFIIZPQFF-YDTRVRFHSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Cu(2-[2'-carboxyphenylazo]-5,5-dimethyl-1,3-cyclohexanedione(-1H))(2-aminopyridine)2(NO3)]*CH3OH 以 neat (no solvent) 为溶剂， 生成 [Cu(2-[2'-carboxyphenylazo]-5,5-dimethyl-1,3-cyclohexanedione(-1H))(2-aminopyridine)2(NO3)]
  参考文献：
  名称：

  Azo Complexes of Cu(II), Co(II), Ni(II), Cd(II), Th(IV), and UO₂(VI) Ions. Mixed‐Ligand Complexes, Pyrolysis Products and Biological Activity

  摘要：

  The reactions of azo ligand, 2-[2'-carboxyphenylazo]-5,5-dimethyl-1,3-cyclohexane-dione, (H2L), with the metal ion Cd(II), Cu(II), Ni(II), Co(II), Th(IV), or UO2(VI) in the presence of LiOH as a deprotonating agent, yielded binary mononuclear complexes. The binary Cu(II) complex reacts with the ligands 1,10-phenanthroline or 2-aminopyridine to form mixed-ligand complexes. All the binary complexes of Cd(II), Cu(II), And Ni(II) have octahedral configurations, while the Co(II) complex is square-planar. The binary complexes of Th(IV) and UO2(VI) have distorted dodecahedral geometries. The mixed-ligand complexes have octahedral configurations. Thermal studies on these complexes showed the possibility of obtaining new complexes pyrolytically, where the complexes decompose through several isolable as well as nonisolable intermediates during heating. The structures of all complexes and the corresponding thermal products were elucidated by elemental analyses, conductance, IR and electronic absorption spectra, magnetic moments, H-1 NMR and TG-DSC measurements as well as by mass spectroscopy. The ligand and some of the complexes were found to activate the enzyme pectinlyase.

  DOI：

  10.1081/sim-200026204
• 作为产物：
  描述：

  甲醇 、 2-氨基吡啶 、 copper(II) nitrate trihydrate 、 2-[2'-carboxyphenylazo]-5,5-dimethyl-1,3-cyclohexanedione 在 LiOH*H₂O 作用下， 以 甲醇 、 水 为溶剂， 以59%的产率得到[Cu(2-[2'-carboxyphenylazo]-5,5-dimethyl-1,3-cyclohexanedione(-1H))(2-aminopyridine)2(NO3)]*CH3OH
  参考文献：
  名称：

  Azo Complexes of Cu(II), Co(II), Ni(II), Cd(II), Th(IV), and UO₂(VI) Ions. Mixed‐Ligand Complexes, Pyrolysis Products and Biological Activity

  摘要：

  The reactions of azo ligand, 2-[2'-carboxyphenylazo]-5,5-dimethyl-1,3-cyclohexane-dione, (H2L), with the metal ion Cd(II), Cu(II), Ni(II), Co(II), Th(IV), or UO2(VI) in the presence of LiOH as a deprotonating agent, yielded binary mononuclear complexes. The binary Cu(II) complex reacts with the ligands 1,10-phenanthroline or 2-aminopyridine to form mixed-ligand complexes. All the binary complexes of Cd(II), Cu(II), And Ni(II) have octahedral configurations, while the Co(II) complex is square-planar. The binary complexes of Th(IV) and UO2(VI) have distorted dodecahedral geometries. The mixed-ligand complexes have octahedral configurations. Thermal studies on these complexes showed the possibility of obtaining new complexes pyrolytically, where the complexes decompose through several isolable as well as nonisolable intermediates during heating. The structures of all complexes and the corresponding thermal products were elucidated by elemental analyses, conductance, IR and electronic absorption spectra, magnetic moments, H-1 NMR and TG-DSC measurements as well as by mass spectroscopy. The ligand and some of the complexes were found to activate the enzyme pectinlyase.

  DOI：

  10.1081/sim-200026204