1,2-bis(5'-(dimesitylboryl)-2'-methylthien-3'-yl)pentene | 911289-22-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 噻吩类
• 英文名称: 1,2-bis(5'-(dimesitylboryl)-2'-methylthien-3'-yl)pentene
• 英文别名: [4-[2-[5-Bis(2,4,6-trimethylphenyl)boranyl-2-methylthiophen-3-yl]cyclopenten-1-yl]-5-methylthiophen-2-yl]-bis(2,4,6-trimethylphenyl)borane；[4-[2-[5-bis(2,4,6-trimethylphenyl)boranyl-2-methylthiophen-3-yl]cyclopenten-1-yl]-5-methylthiophen-2-yl]-bis(2,4,6-trimethylphenyl)borane
• CAS: 911289-22-0
• 化学式: C₅₁H₅₈B₂S₂
• 分子量: 756.776
• InChiKey: ZSLJGGJSOFTJOW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  10.25
• 重原子数：
  55
• 可旋转键数：
  8
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  56.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1,2-bis(5'-(dimesitylboryl)-2'-methylthien-3'-yl)pentene 以 四氢呋喃 为溶剂， 生成 2,8-Bis-[bis-(2,4,6-trimethyl-phenyl)-boranyl]-9a,9b-dimethyl-5,6,9a,9b-tetrahydro-4H-1,9-dithia-trindene
  参考文献：
  名称：

  Modulation of the Photochromic Property in an Organoboron-Based Diarylethene by a Fluoride Ion

  摘要：

  Organoboron-based diarylethene was successfully synthesized and exhibited photochromic property. Furthermore, its photochromic property can be modulated by a fluoride ion. The absorption maximum of the photostationary state shifted from 655 to 490 nm upon addition of a fluoride ion. The modulation mechanism is attributed to the special Lewis acid-base interaction between a trivalent boron atom and a fluoride ion.

  DOI：

  10.1021/ol061370g
• 作为产物：
  描述：

  2,8-Bis-[bis-(2,4,6-trimethyl-phenyl)-boranyl]-9a,9b-dimethyl-5,6,9a,9b-tetrahydro-4H-1,9-dithia-trindene 以 四氢呋喃 为溶剂， 生成 1,2-bis(5'-(dimesitylboryl)-2'-methylthien-3'-yl)pentene
  参考文献：
  名称：

  Modulation of the Photochromic Property in an Organoboron-Based Diarylethene by a Fluoride Ion

  摘要：

  Organoboron-based diarylethene was successfully synthesized and exhibited photochromic property. Furthermore, its photochromic property can be modulated by a fluoride ion. The absorption maximum of the photostationary state shifted from 655 to 490 nm upon addition of a fluoride ion. The modulation mechanism is attributed to the special Lewis acid-base interaction between a trivalent boron atom and a fluoride ion.

  DOI：

  10.1021/ol061370g

文献信息

• 상전이 광 이성질체 화합물, 발광다이오드 표시장치 및 그 제조 방법
  申请人：LG Display Co.,Ltd. 엘지디스플레이 주식회사(119981018655) Corp. No ▼ 110111-0393134

  公开号：KR20180045361A

  公开（公告）日：2018-05-04

  본 발명은 상전이 광 이성질체 화합물을 제공하며, 상전이 광 이성질체층에 선택적 광 조사 공정을 진행한 후 도전성 물질을 증착함으로써, 마스크 공정 없이 금속 패턴의 형성이 가능하다. 따라서, 마스크 공정 없이 발광다이오드의 제 2 전극의 일부에 보조 전극을 형성할 수 있으며, 이에 의한 제 2 전극의 전압 강하에 의한 발광다이오드 표시장치의 표시 품질 저하 문제를 방지할 수 있다.

  本发明提供了一种转变光性质的化合物，并且通过在转变光性质层上进行选择性光照处理后，通过沉积挑战性物质，可以在无掩模工艺的情况下形成金属图案。因此，可以在无掩模工艺的情况下，在发光二极管的第二电极的一部分形成辅助电极，并且可以避免由第二电极的电压降低引起的发光二极管显示器的显示质量下降问题。
• Modulation of the Photochromic Property in an Organoboron-Based Diarylethene by a Fluoride Ion
  作者：Zhiguo Zhou、Shuzhang Xiao、Jia Xu、Zhiqiang Liu、Mei Shi、Fuyou Li、Tao Yi、Chunhui Huang

  DOI：10.1021/ol061370g

  日期：2006.8.1

  Organoboron-based diarylethene was successfully synthesized and exhibited photochromic property. Furthermore, its photochromic property can be modulated by a fluoride ion. The absorption maximum of the photostationary state shifted from 655 to 490 nm upon addition of a fluoride ion. The modulation mechanism is attributed to the special Lewis acid-base interaction between a trivalent boron atom and a fluoride ion.