copper;dimethoxy-sulfanylidene-sulfido-λ5-phosphane | 22281-50-1

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机二硫代磷酸及其衍生物
• 英文名称: copper;dimethoxy-sulfanylidene-sulfido-λ5-phosphane
• CAS: 22281-50-1
• 化学式: C₄H₁₂CuO₄P₂S₄
• 分子量: 377.894
• InChiKey: VGLRSDJWIRZUJJ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  3.4
• 重原子数：
  15
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  103
• 氢给体数：
  0
• 氢受体数：
  8

反应信息

• 作为反应物：
  描述：

  copper;dimethoxy-sulfanylidene-sulfido-λ5-phosphane 、 以 正庚烷 、 氯仿 为溶剂， 生成
  参考文献：
  名称：

  EPR, 1H, 31P ENDOR, and IR study of Cu(II) and Ni(II)(O,O-dimethyldithiophosphate)(N,N-dimethyldithiocarbamate) complexes

  摘要：

  Polycrystalline samples of Cu(Me(2)dtp)(Me(2)dtc) and Ni(Me(2)dtp)(Me(2)dtc) complexes are studied by means of EPR, ENDOR, and vibrational normal coordinate analysis. On the basis of EPR and ENDOR experimental results, the spin density distribution on H-1 and P-31 nuclei of the mixed ligand and parent copper dithiophosphate and dithiocarbamate complexes is compared. Comparison between vibrational spectra and normal coordinate analysis data on Ni(Me(2)dtp)(Me(2)dtc)(2) Ni(Me(2)dtp)(2) and Ni(Me(2)dtc)(2) enabled the conclusion that the structure of the NiS4 fragment in the mixed complex is retained close to that in the bis-chelate complexes.

  DOI：

  10.1016/0584-8539(94)00226-2
• 作为产物：
  描述：

  sodium O,O-dimethyl phosphorodithioate 、 copper(II) choride dihydrate 以 水 为溶剂， 生成 copper;dimethoxy-sulfanylidene-sulfido-λ5-phosphane
  参考文献：
  名称：

  溶质配位溶剂相互作用和温度对双（二硫代磷酸根）铜（II）的EPR和电子光谱的影响。

  摘要：

  在DMFA，DMSO和吡啶中，通过EPR和UV-VIS光谱研究了双（二取代的二硫代磷酸铜）铜（II）络合物CuII（R2-dtp）2的两个分子之间的自氧化还原反应。还评估了温度和溶液中二硫化物浓度的影响。EPR谱显示，当CuII（R2-dtp）2溶解在配位溶剂中时，其g值会增加，而与非配位溶剂中的相应值相比，铜的超细裂变会降低。在相同条件下，电子光谱在420 nm处的最大吸收观察到了变色移，这与配合物的配体-金属电荷转移（LMCT）跃迁相对应。结果解释为在CuII（R2-dtp）2与所用配位溶剂之间形成轴向或赤道加合物。另一方面，LMCT带的摩尔吸收率和EPR光谱的强度随着所用配位溶剂的性质，溶解后的时间和添加的二硫化物的量而强烈增加。两者还取决于远程配体取代基的大小和形状，并且它们以Me

  DOI：

  10.1016/s1386-1425(01)00707-7

文献信息

• [60]Fullerene metal complexes with large effective two-photon absorption cross-section
  作者：Fangfang Jian、Jing Wang、Hailian Xiao、Pusu Zhao、Pingping Sun、Lihua Huang

  DOI：10.1039/b926935e

  日期：——

  Fourteen novel complexes of fullerene C60 with metal dialkyldithiophosphate, [(RO)2PS2]2M}·2C60 (R = Me and Et; M = Mn, Fe, Co, Ni, Cu, Zn and Pd), can be obtained in high yield by the reaction of metal(II) dialkyldithiophosphate complexes with C60 fullerene. Their structures are determined by 1H, 13C, and 31P NMR spectroscopy, elemental analysis, FT-IR and UV-vis, and are supplied by single crystal X-ray data. The compound [(EtO)2PS2]2Pd}·2C60 was also studied by the HRTEM image and SAED patterns. Studies of the optical properties of the complexes of fullerene C60 with metal dialkyldithiophosphate show that these compounds all have very strong nonlinear optical absorption effects. The nonlinear absorption of fourteen complexes of fullerene C60 with metal dialkyldithiophosphate (in o-dichlorobenzene and in the solid state) was measured by the open-aperture Z-scan technique at a wavelength of 532 nm. DFT calculations are also used to discuss the stability of these complexes and to confirm the structural assignments.

  富勒烯 C60 与金属二烷基二硫代磷酸盐的 14 种新型配合物 [(RO)2PS2]2M}·2C60（R = Me 和 Et；M = Mn、Fe、Co、Ni、Cu、Zn 和 Pd）可以在高反应速率下获得。通过二烷基二硫代磷酸金属(II)配合物与C60富勒烯的反应产生的产量。它们的结构通过 1H、13C 和 31P NMR 光谱、元素分析、FT-IR 和 UV-vis 确定，并由单晶 X 射线数据提供。通过HRTEM图像和SAED图谱对化合物[(EtO)2PS2]2Pd}·2C60进行了研究。对富勒烯C60与二烷基二硫代磷酸金属盐配合物光学性质的研究表明，这些化合物均具有很强的非线性光学吸收效应。通过开孔 Z 扫描技术在 532 nm 波长下测量了富勒烯 C60 与金属二烷基二硫代磷酸盐（在邻二氯苯中和固态）的 14 种络合物的非线性吸收。 DFT 计算还用于讨论这些配合物的稳定性并确认结构分配。
• ——
  作者：KARAKOTOV S. D.、 VISHNYAKOV V. G.、 MINAKOV V. A.、 POMYKAEVA N. E.

  DOI：——

  日期：——
• Effect of solute-co-ordinating solvent interactions and temperature on the EPR and electronic spectra of bis(dithiophosphato)copper(II)
  作者：Nicola D Yordanov、Kalina Ranguelova

  DOI：10.1016/s1386-1425(01)00707-7

  日期：2002.4

  The self-redox reaction proceeding between two molecules of the complex bis(disubstituted-dithiophosphato)copper(II), CuII(R2-dtp)2, is studied by EPR and UV-VIS spectroscopy in DMFA, DMSO and pyridine. The effect of temperature and disulphide concentration in the solutions is also evaluated. The EPR spectra show that the g-values of CuII(R2-dtp)2 increase when it is dissolved in co-ordinating solvents

  在DMFA，DMSO和吡啶中，通过EPR和UV-VIS光谱研究了双（二取代的二硫代磷酸铜）铜（II）络合物CuII（R2-dtp）2的两个分子之间的自氧化还原反应。还评估了温度和溶液中二硫化物浓度的影响。EPR谱显示，当CuII（R2-dtp）2溶解在配位溶剂中时，其g值会增加，而与非配位溶剂中的相应值相比，铜的超细裂变会降低。在相同条件下，电子光谱在420 nm处的最大吸收观察到了变色移，这与配合物的配体-金属电荷转移（LMCT）跃迁相对应。结果解释为在CuII（R2-dtp）2与所用配位溶剂之间形成轴向或赤道加合物。另一方面，LMCT带的摩尔吸收率和EPR光谱的强度随着所用配位溶剂的性质，溶解后的时间和添加的二硫化物的量而强烈增加。两者还取决于远程配体取代基的大小和形状，并且它们以Me
• EPR, 1H, 31P ENDOR, and IR study of Cu(II) and Ni(II)(O,O-dimethyldithiophosphate)(N,N-dimethyldithiocarbamate) complexes
  作者：V. Iliev、V. Alexiev

  DOI：10.1016/0584-8539(94)00226-2

  日期：1995.6

  Polycrystalline samples of Cu(Me(2)dtp)(Me(2)dtc) and Ni(Me(2)dtp)(Me(2)dtc) complexes are studied by means of EPR, ENDOR, and vibrational normal coordinate analysis. On the basis of EPR and ENDOR experimental results, the spin density distribution on H-1 and P-31 nuclei of the mixed ligand and parent copper dithiophosphate and dithiocarbamate complexes is compared. Comparison between vibrational spectra and normal coordinate analysis data on Ni(Me(2)dtp)(Me(2)dtc)(2) Ni(Me(2)dtp)(2) and Ni(Me(2)dtc)(2) enabled the conclusion that the structure of the NiS4 fragment in the mixed complex is retained close to that in the bis-chelate complexes.