钯(II)二乙基二硫代磷酸酯 | 21312-72-1

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机二硫代磷酸及其衍生物
• 中文名称: 钯(II)二乙基二硫代磷酸酯
• 英文名称: Pd(II) diethyldithiophosphate
• 英文别名: Diethoxy-sulfanylidene-sulfido-lambda5-phosphane;palladium(2+)；diethoxy-sulfanylidene-sulfido-λ5-phosphane;palladium(2+)
• CAS: 21312-72-1
• 化学式: C₈H₂₀O₄P₂PdS₄
• 分子量: 476.876
• InChiKey: LKOCTORPHGOIGF-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  3.66
• 重原子数：
  19
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  103
• 氢给体数：
  0
• 氢受体数：
  8

反应信息

• 作为反应物：
  描述：

  钯(II)二乙基二硫代磷酸酯 在 三苯基膦 作用下， 以 二氯甲烷 为溶剂， 以65%的产率得到
  参考文献：
  名称：

  O,O-Alkylene dithiophosphates of palladium(II) and their adducts with triphenylphosphine

  摘要：

  DOI：

  10.1016/s0020-1693(00)86279-9
• 作为产物：
  描述：

  sodium O,O-diethyl phosphorodithioate 、 palladium dichloride 在 potassium chloride 作用下， 以81%的产率得到钯(II)二乙基二硫代磷酸酯
  参考文献：
  名称：

  O,O-Alkylene dithiophosphates of palladium(II) and their adducts with triphenylphosphine

  摘要：

  DOI：

  10.1016/s0020-1693(00)86279-9

文献信息

• [60]Fullerene metal complexes with large effective two-photon absorption cross-section
  作者：Fangfang Jian、Jing Wang、Hailian Xiao、Pusu Zhao、Pingping Sun、Lihua Huang

  DOI：10.1039/b926935e

  日期：——

  Fourteen novel complexes of fullerene C60 with metal dialkyldithiophosphate, [(RO)2PS2]2M}·2C60 (R = Me and Et; M = Mn, Fe, Co, Ni, Cu, Zn and Pd), can be obtained in high yield by the reaction of metal(II) dialkyldithiophosphate complexes with C60 fullerene. Their structures are determined by 1H, 13C, and 31P NMR spectroscopy, elemental analysis, FT-IR and UV-vis, and are supplied by single crystal X-ray data. The compound [(EtO)2PS2]2Pd}·2C60 was also studied by the HRTEM image and SAED patterns. Studies of the optical properties of the complexes of fullerene C60 with metal dialkyldithiophosphate show that these compounds all have very strong nonlinear optical absorption effects. The nonlinear absorption of fourteen complexes of fullerene C60 with metal dialkyldithiophosphate (in o-dichlorobenzene and in the solid state) was measured by the open-aperture Z-scan technique at a wavelength of 532 nm. DFT calculations are also used to discuss the stability of these complexes and to confirm the structural assignments.

  富勒烯 C60 与金属二烷基二硫代磷酸盐的 14 种新型配合物 [(RO)2PS2]2M}·2C60（R = Me 和 Et；M = Mn、Fe、Co、Ni、Cu、Zn 和 Pd）可以在高反应速率下获得。通过二烷基二硫代磷酸金属(II)配合物与C60富勒烯的反应产生的产量。它们的结构通过 1H、13C 和 31P NMR 光谱、元素分析、FT-IR 和 UV-vis 确定，并由单晶 X 射线数据提供。通过HRTEM图像和SAED图谱对化合物[(EtO)2PS2]2Pd}·2C60进行了研究。对富勒烯C60与二烷基二硫代磷酸金属盐配合物光学性质的研究表明，这些化合物均具有很强的非线性光学吸收效应。通过开孔 Z 扫描技术在 532 nm 波长下测量了富勒烯 C60 与金属二烷基二硫代磷酸盐（在邻二氯苯中和固态）的 14 种络合物的非线性吸收。 DFT 计算还用于讨论这些配合物的稳定性并确认结构分配。
• Synthesis and characterization of monomeric palladium(II) pyridine-2-chalcogenolate complexes
  作者：Sanjay Narayan、Vimal K. Jain、K. Panneerselvam、Tian Huey Lu、Shu-Fang Tung

  DOI：10.1016/s0277-5387(98)00426-4

  日期：1999.3

  Mononuclear palladium(II) complexes of the type [Pd(Epy)((SS)-S-boolean AND)(PPh3)] [E = S or Se; (SS)-S-boolean AND = S2CNEt2, S2P(OR)(2) (R = Et, Pr-n, Pr-i)] have been prepared. All the complexes have been characterized by elemental analysis and NMR (H-1, P-31H-1}, Se-77H-1}) spectral data. The NMR data indicate that there are two species in solution, i.e. one with chelating (SS)-S-boolean AND ligand predominates (similar to 95%) while the other with chelating Epy and monodentate (SS)-S-boolean AND existing in similar to 5% concentration. The X-ray crystal structure of [Pd(Spy)S2P(OPri)(2)}(PPh3)] has been determined. The square planar palladium atom is coordinated to asymmetrically chelated ((PrO)-O-i)(2)PS2- ligand, PPh3 and pyS(-) groups. (C) 1999 Elsevier Science Ltd. All rights reserved.